CAS: 918655-03-5; (4-(Naphthalen-2-yl)Phenyl)Boronic Acid

• 英文名称(4-(Naphthalen-2-yl)Phenyl)Boronic Acid
• 中文名称4-(2-萘基)苯硼酸
• IUPAC名称(4-(naphthalen-2-yl)phenyl)boronic acid
• CAS编号918655-03-5
• MFCD编号:MFCD09260454
• EINECS号:805-884-9
• 分子式:C16H13BO2
• 分子量:248.08
• 产品CID: 1956890
• 产品分类化学试剂 → 有机试剂 → 多环化合物

• 相似结构搜索
• InChIKey: ICQAKBYFBIWELX-UHFFFAOYSA-N
• InChI=1S/C16H13BO2/c18-17(19)16-9-7-13(8-10-16)15-6-5-12-3-1-2-4-14(12)11-15/h1-11,18-19H…
• 计算化学: 氢键受体数2.0氢键供体数2.0可旋转键数2.0

物理性质

• 沸点463.0±48.0 °C(预测)
• 闪点463 ºCat 760 mmHg
• 密度1.23±0.1 g/cm3(预测)
• pKa:8.58±0.16(预测)
• PSA:40.46
• LogP:2.1866
• 折射率1.676
• 外观形态白色至几乎白色粉末至晶体
• 储存条件在惰性气体(氮气或氩气)下 2-8°C
• 产品应用该化合物用作生物医学应用(包括水凝胶,传感器和癌症治疗)中多氢氧化合物的识别剂.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Warning(警告)
• 危险描述H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P261-P280a-P304+P340-P305+P351+P338-P405-P501a

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 4-(Naphthalen-2-yl)Phenylboronic Acid 主要起始原料 2-Bromonaphthalene And 1,4-Phenylenebisboronic Acid
• 1537876-29-1 + 32316-92-0 = 918655-03-5
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: (Triphenylphosphine)Palladium Solvents: Ethanol,Water; 5 H,50 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 2 - 3
  标题:Preparation Of Stable Ate Complexes Composed Of Scyllo-Inositol Or 1,3,5-Cis-Cyclohexanetriol And Organoboronic Acids,Their Use As Reagents For Organic Synthesis,And Method For Organic Synthesis Using The Complexes
  参考文献:Japan]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 1 H,-78 °C1.2 Reagents: Trimethyl Borate; -78 °C; 2 H,-78 °C1.3 Reagents: Hydrochloric Acid Solvents: Water
  标题:Novel Organic Electroluminescent Compounds,Layers And Organic Electroluminescent Device Using The Same
  参考文献:United States]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 2 H,-78 °C1.2 Reagents: Trimethyl Borate; 19 H,-78 °C -> Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; 1 H
  标题:Organometallic Complex,Light-Emitting Element,Light-Emitting Device,Electronic Device,And Lighting Device
  参考文献:United States]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 2 H,-78 °C1.2 Reagents: Trimethyl Borate Solvents: Tetrahydrofuran; -78 °C; 1 H,-78 °C; -78 °C -> Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Cooled; Rt; 1 H,Rt
  标题:Preparation Of N-Aryl-N-[(Dibenzofuranyl)Phenyl]-9,9-Diphenylfluoren-4-Amine Compounds For Organic Electroluminescent Element,Organic Electroluminescent Element,And Electronic Device
  参考文献:World Intellectual Property Organization]
  
  = 918655-03-5 [标题:Reaction Conditions
  标题:Preparation Of Benzofuran Heterocyclic Organic Compounds,Composition And Its Application In Organic Electronic Device
  参考文献:China]
  
  = 918655-03-5 [标题:Reaction Conditions
  标题:Asymmetric Trivalent Anthracene And Organic Electroluminescent Devices Containing Asymmetric Trivalent Anthracene
  参考文献:Taiwan]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -78 °C; 2 H,-78 °C1.2 Reagents: Trimethyl Borate; 30 Min,-78 °C; Overnight,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Acidified,Rt
  标题:Preparation Of Anthracene Derivatives For High Efficiency And Long Lifetime Organic Light-Emitting Diode
  参考文献:World Intellectual Property Organization]
  
  4612-26-4 + 580-13-2 = 918655-03-5
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran,Water; 2 H,80 °C
  标题:Condensed Heterocyclic Compounds And Organic Light-Emitting Device Including The Same
  参考文献:United States]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Water; -78 °C; 2 H,-78 °C1.2 Reagents: Trimethyl Borate; -78 °C; -78 °C -> Rt; 12 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Neutralized,Rt
  标题:Preparation Of Anthracene Compounds As Organic Electroluminescent Device Materials
  参考文献:Korea]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; 1 H,-78 °C1.2 Reagents: Trimethyl Borate; -78 °C; 2 H,-78 °C1.3 Reagents: Hydrochloric Acid Solvents: Water
  标题:Substituted 9H-Carbazole Compounds As Organic Light-Emitting Compounds For An Organic Electroluminescent Device
  参考文献:Korea]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 1 H,-78 °C1.2 Reagents: Trimethyl Borate; -78 °C; 2 H,-78 °C1.3 Reagents: Hydrochloric Acid Solvents: Water
  标题:Novel Organic Electroluminescent Compounds And Organic Electroluminescent Device Using The Same
  参考文献:World Intellectual Property Organization]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 1 H,-78 °C1.2 Reagents: Trimethyl Borate; 2 H,-78 °C1.3 Reagents: Ammonium Chloride Solvents: Water
  标题:Novel Aromatic Compounds For Organic Electronic Material And Organic Electroluminescent Device
  参考文献:Korea]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 2 H,-10 °C -> 0 °C; 0 °C -> -78 °C1.2 Reagents: Triisopropyl Borate; -78 °C; 17 H,Rt
  标题:Chrysene Derivatives For Organic Electroluminescence Materials And Devices
  参考文献:World Intellectual Property Organization]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 30 Min,-60 °C; 30 Min,-60 °C1.2 Reagents: Triisopropyl Borate; -60 °C; Overnight1.3 Reagents: Water
  标题:Light Emitting Elements That Emit Near-Ir Light And Exhibit High Efficiency And Long Lifespan,Light Emitting Devices,Authentication Devices,And Electronic Devices
  参考文献:United States]
  
  22082-99-1 = 918655-03-5
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 30 Min,-60 °C; 30 Min,-60 °C1.2 Reagents: Triisopropyl Borate; -60 °C; Overnight,-60 °C -> Rt1.3 Reagents: Water
  标题:Preparation Of Thiadiazole,Anthracene,And Tetracene Derivatives For Light-Emitting Devices
  参考文献:China

海关参考信息

• 2902200000-苯
  2902902000-精萘
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管