1,6-己二醇 反应生成 1,6-二溴己烷 参考文献:Cyclic Acetylenes. Xii. The Syntheses Ofo,P'-Bridged Cyclic Tolans By The Fritsch-Buttenberg-Wiechell Rearrangement 标题:Cyclic Acetylenes. Xii. The Syntheses Ofo,P'-Bridged Cyclic Tolans By The Fritsch-Buttenberg-Wiechell Rearrangement 摘要:通过fritsch-Buttenberg-Wiechell重排反应,合成了o,P'-二羟基二苯乙炔的多甲撑醚衍生物(Viin,N=7,8,9,10,11和12).研究了viin的电子光谱,红外光谱和核磁共振谱.观测到随着环张力的增加,出现了减色效应,与应变p,P'-桥联环托兰的长波带红移相反,Viin的电子光谱中长波带出现了高色散位移. DOI:10.1246/bcsj.44.177
专利号:US-10865116-B2 优先权日:2017-03-24 标 题:Process for the synthesis of IZM-2 zeolite in the presence of a template, 1,6-bis(methylpiperidinium)hexane dihydroxide 发明人:MARTINEZ FRANCO RAQUEL; BATS NICOLAS 权利人:IFP ENERGIES NOW 摘要:A novel process is described for the preparation of a microporous crystalline solid, known as IZM-2 microporous solid or IZM-2 zeolite. This novel process consists of carrying out the synthesis of IZM-2 zeolite by conversion/transformation of a zeolite with structure type FAU in a fluorinated medium under hydrothermal conditions. In particular, said novel process consists of carrying out the synthesis of an IZM-2 zeolite in a fluorinated medium starting from a zeolite with structure type FAU used as the source of silicon and aluminium and a specific organic molecule or template comprising two quaternary ammonium functions, namely 1,6-bis(methylpiperidinium)hexane dihydroxide.
专利号:US-10364220-B2 优先权日:2012-12-21 标题:Synthesis of succinimides and quaternary ammonium ions for use in making molecular sieves 发明人:SCHMITT KIRK D; ZUSHMA STEPHEN; BURTON ALLEN W 权利人:EXXONMOBIL CHEMICAL PATENTS INC 摘要:The present invention relates to the synthesis of succinimides, in particular to a method for the synthesis of a succinimide compound, comprising the step of reacting an alkyne, with carbon monoxide and ammonia or an amine, in the presence of an iron catalyst, wherein the reaction is carried out in an amine liquid phase and/or in the absence of an ether solvent. The succinimides may be reduced to quaternary ammonium cations which may be used as structure directing agents in the synthesis of molecular sieves.
专利号:WO-9805658-A1 优先权日:1996-08-07 标 题 :Synthesis of 2-(2-furoyl)-4(5)-(2-furanyl)-1h-imidazole and analogs thereof 发明人:RHO TAIKYUN; LANKIN MICHAEL E; SHIH DAVID H; LANKIN CLAIRE M 权利人:ALTEON INC 摘要:The present invention relates to a practical and facile synthesis of 2-(2-furoyl)-4(5)-(2-furanyl)-1H-imidazole (FFI) and analogs thereof. The synthesis utilizes a novel hydrazinium salt as an intermediate reaction product which facilitates the isolation of purified product in high yields.
专利号:US-10875778-B2 优先权日:2017-03-24 标 题 :Process for the synthesis of IZM-2 zeolite in the presence of a template, 1,6-bis(methylpiperidinium)hexane dibromide 发明人:MARTINEZ FRANCO RAQUEL; BATS NICOLAS 权利人:IFP ENERGIES NOW 摘要:A novel process is described for the preparation of a microporous crystalline solid, known as IZM-2 microporous solid or IZM-2 zeolite. This novel process consists of carrying out the synthesis of IZM-2 zeolite by conversion/transformation of a zeolite with structure type FAU under hydrothermal conditions. In particular, said novel process consists of carrying out the synthesis of an IZM-2 zeolite starting from a zeolite with structure type FAU used as the source of silicon and aluminium and a specific organic molecule or template comprising two quaternary ammonium functions, namely 1,6-bis(methylpiperidinium)hexane dibromide.
专利号:US-11851338-B2 优先权日:2019-04-19 标 题:Method for fast synthesis of an AFX-structure zeolite with a FAUjasite source 发明人:MARTINEZ FRANCO RAQUEL; HARBUZARU BOGDAN; LLIDO ERIC; BERTHOUT DAVID 权利人:IFP ENERGIES NOW 摘要:The present invention relates to a process for the rapid synthesis of an AFX-structure zeolite comprising at least:n i) mixing, in an aqueous medium, a FAU-structure zeolite having an SiO 2 (FAU) /Al 2 O 3 (FAU) molar ratio of between 2.00 and 100, a nitrogen-containing organic compound R, at least one source of at least one alkali and/or alkaline-earth metal M of valence n,n with the following molar composition: (SiO 2 (FAU) )/(Al 2 O 3 (FAU) ) between 2.00 and 100, H 2 O/(SiO 2 (FAU) ) between 1 and 100, R/(SiO 2 (FAU) ) between 0.01 and 0.6, M 2/n O/(SiO 2(FAU) ) between 0.005 and 0.45, wherein SiO 2 (FAU) denotes the amount of SiO 2 provided by the FAU zeolite and Al 2 O 3 (FAU) denotes the amount of Al 2 O 3 provided by the FAU zeolite, until a homogeneous precursor gel is obtained; n ii) hydrothermally treating said precursor gel obtained at the end of step i) under autogenous pressure at a temperature of between 120° C. and 250° C., for 4 to 12 hours.
专利号:US-5856511-A 优先权日:1996-08-07 标题 :Synthesis of 2-(2-furoyl)-4(5)-(2-furanyl)-1H-imidazole and analogs thereof 发明人:RHO TAIKYUN; LANKIN MICHAEL E; SHIH DAVID H; LANKIN CLAIRE M 权利人:ALTEON INC 摘要:The present invention relates to a practical and facile synthesis of 2-(2-furoyl)-4(5)-(2-furanyl)-1H-imidazole (FFI) and analogs thereof. The synthesis utilized a novel hydrazinium salt as an intermediate reaction product which facilitates the isolation of purified product in high yields.
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