专利号:US-2023348657-A1 优先权日:2020-07-23 标题 :Synthesis of linear polyoxazolidinones using uretdiones as diisocyanate component 发明人:QUELL AGGELIKI; THOMAS HANS-JOSEF; ELING BEREND 权利人:BASF SE 摘要:A process for preparing a thermoplastic polymer involves reacting at least components (a) to (b), in the presence of a catalyst composition (c). Component (a) is an isocyanate composition containing at least one uretdione diisocyanate (a-i), and component (b) is an epoxide composition containing at least one diepoxide (b-i). The catalyst composition (c) contains at least one ionic liquid (c-i), preferably selected from 1-ethyl-3-methyl imidazolium bromide, 1-benzyl-3-methyl imidazolium chloride. 1-butyl-1-methylpiperidinium chloride, 1-ethyl-2,3-dimethylimidazolium bromide, 1-(2-hydroxyethyl)-3-methyl imidazolium chloride, butyl-1-methylpiperidinium acetate, or mixtures of two or more thereof. A thermoplastic polymer obtained or obtainable from the process is useful for the preparation of a fibre or a molded article or as a modifier for another thermoplastic material.
专利号:US-4708754-A 优先权日:1987-02-02 标 题 :Method of generating crosslinking sites on the surface of ammonium perchlorate in solid interceptor propellants 发明人:SAYLES DAVID C 权利人:US ARMY 摘要:A method of generating reactive crosslinking sites on the surface of the onium perchlorate particles contained in a Catocene-catalyzed, high-burning rate solid propellant composition by a processing agent which also results in a major improvement in the processibility thereof. The fluid state of the propellant is retained during mixing as a result of interaction between the processing agent prepared prior to incorporating it or when the processing agent is prepared in situ during the propellant mix cycle. There are two alternates available toward improving the processibility of Catocene-catalyzed, high-burning rate propellants. These are: a. The synthesis of a condensation product (processing agent) by the interaction at room temperature of 1,3,5,7,9-pentaazanonane, acrylonitrile, oxiranylmethanol and octadecyl isocyanate in predetermined ratios; or b. Incrementally adding the octadecyl isocyanate to the propellant mix which incorporates the glycidol reaction product of cyanoethyl-substituted tetraethylenepentamine (Tepanol). A major improvement in processing can be effected as a result of the additions of octadecyl isocyanate in 1,2, or 3 increments to the Tepanol-containing mix.
专利号:US-10385167-B2 优先权日:2015-02-13 标题:Process for the synthesis of polyoxazolidinone compounds with high stability 发明人:MÜLLER THOMAS ERNST; Gürtler Christoph; BASU SUSMIT; RANGHEARD CLAUDINE; RIVILLO DAVID; LEITNER WALTER; Köhler Burkhard 权利人:COVESTRO DEUTSCHLAND AG 摘要:The present invention relates to polyoxazolidinone compounds, a method for the production of polyoxazolidinone compounds, comprising the step of reacting a biscarbamate compound with a bisepoxide compound in the presence of a mono-carbamate, a mono-isocyanate and/or a mono-epoxide compound as chain regulator and a suitable base having a pK b value of ≤9 as catalyst. The invention further relates to the use of polyoxazolidinone compounds with high thermal stability.
专利号:US-11326018-B2 优先权日:2016-08-19 标 题:Process for the synthesis of polyoxazolidinone compounds 发明人:WEBER ANNA; RANGHEARD CLAUDINE; KESSLER MICHAEL; LEITNER WALTER; Gürtler Christoph; KOOPMANS CARSTEN; MÜLLER THOMAS ERNST 权利人:COVESTRO DEUTSCHLAND AG 摘要:A method for the production of polyoxazolidinone compounds, comprising the step of reacting an isocyanate compound (A) with an epoxide compound (B) in the presence of a catalyst (C), wherein the isocyanate compound (A) comprises a isocyanate compound (A 1 ) wherein the a isocyanate compound (A1) comprising at least two isocyanate groups (I 1 ≥2), preferred two isocyanate groups (I 1 =2), wherein the epoxide compound (B) comprises a epoxide compound (B 1 ) and an epoxide compound (B 2 ), wherein the epoxide compound (B 2 ) is different from the epoxide compound (B 1 ) wherein the epoxide compound (B 1 ) comprising at least two terminal epoxide groups (F1≥2), preferred two terminal epoxide groups (F 1 =2), linked together by a linking group (L1) and the epoxide compound (B 2 ) comprising at least two terminal epoxide groups (F 2 ≥2)), preferred two terminal epoxide groups (F 2 =2), linked together by a linking group (L 2 ), wherein the linking group (L 2 ) comprises acyclic and covalent bonds to each other free of conjugated multiple bonds within the main chain, wherein the epoxide compound (B 2 ) is present in the epoxide compounds B 1 and B 2 , in an amount of ≥0.01 mol-% to <10 mol-%, preferred 1-9 mol-% more preferred 3-8 mol-% based on the molar ratio the terminal epoxide groups in the epoxide compound (B 1 ) and of the sum of the terminal epoxide groups in the epoxide compound (B 1 ) and terminal epoxide groups in the epoxide compound (B 2 ).
专利号:US-8173742-B2 优先权日:2003-12-24 标题:Synthesis of biurets and isocyanates with alkoxysilane functions, formulations containing same and use thereof 发明人:BERNARD JEAN-MARIE; SCHWARZ JOHANNES; REVELANT DENIS 权利人:BERNARD JEAN-MARIE; SCHWARZ JOHANNES; REVELANT DENIS; PERSTORP FRANCE 摘要:The invention relates to a composition and a method of preparing one such composition and an isocyanatoalkoxysilane; the polyisocyanate composition contains at least two different oligomeric compounds comprising at least three units and at most five units selected from aminoalkylsilane units and diamine units and at least one function selected from isocyanate functions and from those derived therefrom, the aforementioned compounds having at least two aminoalkylsilane units and another compound having at least two diamine units; the invention is suitable for coatings.
专利号:US-2005192265-A1 优先权日:2003-03-20 标 题:Cycloalkyl, lactam, lactone and related compounds, pharmaceutical compositions comprising same, and methods for inhibiting beta-amyloid peptide release and/or its synthesis by use of such compounds 发明人:THOMPSON RICHARD C; WILKIE STEPHEN; STACK DOUGLAS R; VANMETER ELDON E; SHI QING; BRITTON THOMAS C; AUDIA JAMES E; REEL JON K; MABRY THOMAS E; DRESSMAN BRUCE A; CWI CYNTHIA L; HENRY STEVEN S; MCDANIEL STACEY L; STUCKY RUSSELL D; PORTER WARREN J 摘要:Disclosed are compounds which inhibit β-amyloid peptide release and/or its synthesis, and, accordingly, have utility in treating Alzheimer's disease. Also disclosed are pharmaceutical compositions that include a compound which inhibits β-amyloid peptide release and/or its synthesis as well as methods for treating Alzheimer's disease both prophylactically and therapeutically with such pharmaceutical compositions.