CAS: 63223-86-9; (2R,3R,4S,5S,6R)-2-(((3S,5R,6S,8R,9R,10R,12R,13R,14R,17S)-3,12-Dihydroxy-17-((S)-2-Hydroxy-6-Methylhept-5-En-2-yl)-4,4,8,10,14-Pentamethylhexadecahydro-1H-Cyclopenta[a]Phenanthren-6-yl)Oxy)-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-3,4,5-Triol

• 英文名称(2R,3R,4S,5S,6R)-2-(((3S,5R,6S,8R,9R,10R,12R,13R,14R,17S)-3,12-Dihydroxy-17-((S)-2-Hydroxy-6-Methylhept-5-En-2-yl)-4,4,8,10,14-Pentamethylhexadecahydro-1H-Cyclopenta[a]Phenanthren-6-yl)Oxy)-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-3,4,5-Triol
• 中文名称人参皂苷Rh1
• IUPAC名称(2R,3R,4S,5S,6R)-2-(((3S,5R,6S,8R,9R,10R,12R,13R,14R,17S)-3,12-dihydroxy-17-((S)-2-hydroxy-6-methylhept-5-en-2-yl)-4,4,8,10,14-pentamethylhexadecahydro-1H-cyclopenta[a]phenanthren-6-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
• 其它别名(3beta,6alpha,12beta)-3,12,20-Trihydroxydammar-24-en-6-yl?beta-D-glucopyranoside; Sanchinoside Rh1
• CAS编号63223-86-9
• MFCD编号:MFCD09951797
• EINECS号:683-201-1
• FDA UNII编号:XBR6F7G8FU
• 分子式:C36H62O9
• 分子量:638.88
• 产品CID: 1613832
• 产品分类生物化工 → 提取物

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: RAQNTCRNSXYLAH-RFCGZQMISA-N
• RAQNTCRNSXYLAH-CCJJTDGONA-N…
• 计算化学: 氢键受体数9.0氢键供体数7.0可旋转键数7.0

物理性质

• 沸点755.1±60.0 °C at 760 mmHg
• 闪点410.5±32.9 °C
• 密度1.2±0.1 g/cm3
• pKa:12.91±0.70(预测)
• PSA:160.07
• LogP:3.74
• 折射率1.581
• 蒸汽压0.0±5.7 mmHg at 25°C
• 溶解性DMSO: 100 mg/mL (156.53 Mm; Need Ultrasonic)
• 外观形态白色粉末
• 储存条件2-8°C

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别急性毒性 类别4(经口)
• 警示词Warning(警告)
• 危险描述H302 |吞咽有害.
• 防范说明P264-P270-P301+P312-P330-P501
• UN编号NONH for all modes of transport
• 危险品标志Xn
• 安全声明H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
• 危险类别码22
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 22427-39-0 = 63223-86-9 + 97744-96-2 + 174721-08-5
  反应条件:1.1 Solvents: Ethanol,Water; 4 D,26 °C
  标题:Microbial Transformation Of 20(S)-Protopanaxatriol-Type Saponins By Absidia Coerulea
  作者:Chen,Guangtong; Et Al
  参考文献:Journal Of Natural Products 日期:2007 卷标:70(7) 页码:1203-1206]
  
  80418-24-2 = 63223-86-9 + 97744-96-2 + 948046-16-0 + 948046-15-9 + 174721-08-5 + 80418-25-3 + 948046-18-2
  反应条件:1.1 Solvents: Ethanol,Water; 4 D,26 °C
  标题:Microbial Transformation Of 20(S)-Protopanaxatriol-Type Saponins By Absidia Coerulea
  作者:Chen,Guangtong; Yang,Min; Lu,Zhiqiang; Zhang,Jinqiang; Huang,Huilian; Et Al
  参考文献:Journal Of Natural Products 日期:2007 卷标:70(7) 页码:1203-1206]
  
  52286-74-5 = 63223-86-9 + 34080-08-5 + 1453-93-6
  反应条件:1.1 Reagents: Sodium Solvents: 1-Butanol
  标题:Alkaline Cleavage Of Ginsenosides
  作者:Chen,Yingjie; Et Al
  参考文献:Chemical & Pharmaceutical Bulletin 日期:1987 卷标:35(4) 页码:1653-5]
  
  22427-39-0 = 63223-86-9 + 364779-15-7 + 53963-43-2 + 80952-73-4 + 2319608-29-0 + 340270-88-4
  反应条件:1.1 Catalysts: 12-Tungstosilicic Acid Solvents: Methanol,Water; 5 H,Ph 3,Rt -> 60 °C
  标题:A Novel Catalytic Application Of Heteropoly Acids: Chemical Transformation Of Major Ginsenosides Into Rare Ginsenosides Exemplified By Rg1
  作者:Cao,Jie; Et Al
  参考文献:Science China: Chemistry 日期:2017 卷标:60(6) 页码:748-753]
  
  52286-59-6 = 63223-86-9 + 80928-46-7 + 97744-96-2 + 174721-08-5 + 52286-74-5 + 948046-19-3
  反应条件:1.1 Solvents: Ethanol,Water; 4 D,26 °C
  标题:Microbial Transformation Of 20(S)-Protopanaxatriol-Type Saponins By Absidia Coerulea
  作者:Chen,Guangtong; Et Al
  参考文献:Journal Of Natural Products 日期:2007 卷标:70(7) 页码:1203-1206

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管