2-N-Butylmalonic Acid Bis(1,2,2,6,6-Pentamethylpiperidin-4-yl) Ester,2,6-二叔丁基对(二甲氨甲基)苯酚置于溶剂黄146体系中,用 甲苯 作为反应溶剂,化学反应生成 [[3,5-二叔丁基-4-羟基苯基]甲基]丁基丙二酸二(1,2,2,6,6-五甲基-4-哌啶基)酯 参考文献:Substituted Malonic Acid Derivatives And Their Use As Stabilizers 标题:Substituted Malonic Acid Derivatives And Their Use As Stabilizers 摘要:来自4-羟基和4-氨基多烷基哌啶和在中心碳原子上用有机残基(最好是烷基,酯基烷基或膦烷基)取代的羟基苯甲酸的酯和酰胺是有机聚合物的优秀稳定剂,特别是对于聚烯烃.它们不仅可以保护聚合物免受光降解,还可以保护聚合物免受热氧化降解.这些化合物可以通过将相应的取代马来酸衍生物进行羟基苯甲基化来制备.双马来酸衍生物可以通过与甲醛反应来从单马来酸衍生物中获得.
专利号:US-2009318592-A1 优先权日:2005-10-11 标 题 :Process for the Synthesis of Amine Ethers 发明人:FREY MARKUS; BROENNIMANN VALERIE 权利人:CIBA GEIGY CORP 摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.
专利号:US-2007191516-A1 优先权日:2004-03-15 标题 :Process for the synthesis of amine ethers 发明人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS 权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS 摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.
专利号:US-7803959-B2 优先权日:2006-04-05 标 题 :Synthesis of aromatic silicon-containing compounds 发明人:COGGAN JENNIFER A; BENDER TIMOTHY P; TOTH ALAN EDWARD JOHN 权利人:XEROX CORP 摘要:Methods are provided for preparing aromatic silicon-containing compounds. The methods include providing an aromatic starting material; reacting the aromatic starting material with a base to form an aromatic salt; and reacting the aromatic salt with a halo-alkylene-silane to form an aromatic silicon-containing compound. Compositions prepared by these methods, protective layers that include hydrolysis and condensation products of such compositions, electrophotographic photoreceptors that include such protective layers, and image forming apparatuses that include such electrophotographic photoreceptors are also provided. In addition, method for preparing electrophotographic photoreceptors that include protective layers including hydrolysis and condensation products of aromatic silicon-containing compounds prepared by the methods for preparing aromatic silicon-containing compounds are provided.
专利号:US-7402675-B2 优先权日:2000-05-26 标题 :Process for the synthesis of amine ethers from secondary amino oxides 发明人:HAFNER ANDREAS; KIRNER HANS JUERG; SCHWARZENBACH FRANZ; VAN DER SCHAAF PAUL ADRIAAN; NESVADBA PETER 权利人:CIBA SC HOLDING AG 摘要:An amine ether of formula A n nwherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L;n E′ is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)—R 22 ; or T′ is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or —NR 18 —; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR 18 —; or T′ is —C(G 1 )(G 2 )-T″; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by n n n n n n n n n n n n T″ is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; n or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, n are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. n n n n n The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.
专利号:US-7576240-B2 优先权日:2006-04-26 标 题 :Arylamine processes 发明人:MURPHY LEANNE DAWN 权利人:XEROX CORP 摘要:Processes for selectively hydrogenating double and/or triple bonds in organic molecules include providing at least one organic molecule containing a double and/or triple bond, providing at least one hydrogen donor molecule, and hydrogenating the double and/or triple bond in the presence of at least one catalyst. Processes for preparing arylamine molecules include selectively hydrogenating double bonds in arylamine compounds by providing at least one organic molecule containing a multiple bond, providing at least one hydrogen donor molecule, and hydrogenating the multiple bond in the presence of at least one catalyst. The processes provide efficient, cost-effective and safe methods for conducting selective hydrogenation reactions in the synthesis of organic molecules, such as charge-transport molecules.
专利号:US-2005043552-A1 优先权日:2000-05-26 标 题:Process for the synthesis of amine ethers from secondary amino oxides
摘要:United States Environmental Protection Agency, Office of Pesticides and Toxic Substances., 8EHQ-0186-0585S 摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198