专利号:US-9289755-B2 优先权日:2012-12-07 标题 :Synthesis of ZSM-5 crystals with improved morphology 发明人:LAI WENYIH FRANK; ROLLMAN NICHOLAS S 权利人:LAI WENYIH FRANK; ROLLMAN NICHOLAS S; EXXONMOBIL RES & ENG CO 摘要:Methods are provided for synthesizing crystals having a ZSM-5 framework structure from synthesis mixtures suitable for synthesis of ZSM-12 framework structure crystals in the absence of seed crystals with a ZSM-5 framework structure, such as in the absence of any seed crystals. For synthesis mixtures with a sufficiently high XO 2 :Y 2 O 3 ratio, seeding a synthesis mixture with ZSM-5 seed crystals can result in production of pure phase ZSM-5 crystals with a new morphology. The morphology can include rod-like primary crystallites with a length of about 0.5 μm or less that are organized/aggregated into larger secondary crystal structures. The aggregation of the primary crystallites into a secondary crystal structure can allow for an unexpectedly large mesoporous surface area for the ZSM-5 crystals.
专利号:US-2004058888-A1 优先权日:2000-01-13 标题:Methods for synthesis of alpha-d-gal (1~>3) gal-containing oligosaccharides 发明人:BORNAGHI LAURENT; DEKANY GYULA; DRINNAN NICHOLAS BARRY; PAPAGEORGIOU JOHN; WEST MICHAEL LEO 摘要:This invention relates to reagents and methods for synthesis of biologically active di- and tri-saccharides comprising α-D-Gal(1→3)-D-Gal. In particular the invention provides novel reagents, intermediates and processes for the solution or solid phase synthesis of α-D-galactopyranosyl-(1→3)-D-galactose, and derivatives thereof. In one preferred embodiments the invention provides a protected monosaccharide building block of general formula (II): in which R 3 is methoxy or methyl; R 1 is H, benzoyl, pivaloyl, 4-chlorobenzoyl, acetyl, chloroacetyl, levulinoyl, 4-methylbenzoyl, benzyl, 3,4-methylenedioxybenzyl, 4-methoxybenzyl, 4-chlorobenzyl, 4-acetamidobenzyl, or 4-azidobenzyl; and R 2 is H, Fmoc, benzoyl, pivaloyl, 4-chlorobenzoyl, acetyl, chloroacetyl, levulinoyl, 4-methylbenzoyl, benzyl, 3,4-methylenedioxybenzyl, 4-methoxybenzyl, 4 -chlorobenzyl, 4-acetamidobenzyl, or 4-azidobenzyl.
专利号:US-7247287-B2 优先权日:2003-06-11 标 题 :Synthesis of aluminophosphates and silicoaluminophosphates 发明人:CAO GUANG; SHAH MATU J 权利人:EXXONMOBIL CHEM PATENTS INC 摘要:The invention is directed to a method of synthesising silicoaluminophosphate and aluminophosphate molecular sieves using synthesis templates that contain at least one template of general formula R 1 R 2 N—R 3 , wherein R 1 and R 2 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R 3 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms, and 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S. In particular, the present invention relates to the synthesis of silicoaluminophosphate molecular sieves of the CHA framework type having a low silicon to aluminium atomic ratio.
专利号:US-6540970-B1 优先权日:1999-11-18 标题:Method for the synthesis of molecular sieves 发明人:STROHMAIER KARL G; VAUGHAN DAVID E W 权利人:EXXON MOBIL CHEM PATENTS INC 摘要:The present invention provides a method for the synthesis of MeAPO molecular sieves which includes the following steps: providing a source of alumina, a source of phosphorus, water, and a template suitable for forming a MeAPO molecular sieve; providing a source of metal (Me) including metal particles, the metal particles measuring, in their largest dimension, equal to or less than five nanometers; providing a water soluble organic solvent capable of solubilizing the source of metal; forming a synthesis mixture from the source of alumina, the source of phosphorus, the water, the template, the source of metal, and the solvent; and forming a MeAPO molecular sieve from the synthesis mixture.
专利号:US-2008103312-A1 优先权日:2006-08-29 标 题:Processes for the synthesis of 5-phenyl-1-trityl-1H-tetrazole 发明人:KANSAL VINOD K; MISTRY DHIRENKUMAR N; VASOYA SANJAY L; LUNAGARIYA VIJAYKUMAR D 权利人:KANSAL VINOD K; MISTRY DHIRENKUMAR N; VASOYA SANJAY L; LUNAGARIYA VIJAYKUMAR D 摘要:Provided are processes for the synthesis of 5-phenyl-1-trityl-1H-tetrazole, an intermediate useful in the synthesis of irbesartan.
专利号:WO-2024047178-A1 优先权日:2022-09-02 标题 :A method for simultaneous synthesis of a plurality of oligonucleotides 发明人:ZIV OMER; THORPE CAMERON; TANPURE ARUN; ERLICH YANIV 权利人:ELEVEN THERAPEUTICS LTD 摘要:Disclosed is a method and compounds useful for performing said method for simultaneous synthesis of a plurality of oligonucleotide molecules, and more specifically for orthogonal synthesis of at least two different oligonucleotide molecules at the same time with applications in combinatorial chemistry and DNA encoded libraries (DEL).
[参考文献]: Iikka Salmela, Et Al. Cellular Elements For Seeing In The Dark: Voltage-Dependent Conductances In Cockroach Photoreceptors. Bmc Neurosci. 2012 Aug 6:13:93. [参考文献]: Jayabalan Nirmal, Et Al. Evaluation Of The Functional Importance Of Organic Cation Transporters On The Ocular Disposition Of Its Intravitreally Injected Substrate In Rabbits. Curr Eye Res. 2012 Dec;37(12):1127-35. [参考文献]: Myung-Woo Byun, Et Al. Effect Of Procyanidin C1 On Nitric Oxide Production And Hyperpolarization Through Ca(2+)-Dependent Pathway In Endothelial Cells. J Med Food. 2012 Nov;15(11):1032-7. [参考文献]: Nathanael S Heyman, Et Al. Trek-1 Currents In Smooth Muscle Cells From Pregnant Human Myometrium. Am J Physiol Cell Physiol. 2013 Sep 15;305(6):C632-42. [参考文献]: R K Kar, Et Al. Differential Role Of Ethylene And Hydrogen Peroxide In Dark-Induced Stomatal Closure. Pak J Biol Sci. 2013 Dec 15;16(24):1991-6.
合成参考文献
摘要:de Meijere, A.; Kozhushkov, S. I., Science of Synthesis, (2009) 48, 489. 摘要:Wicha, J., Science of Synthesis, (2009) 48, 169. 摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 854. 摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 780. 摘要:Podlech, J., Science of Synthesis Knowledge Updates, (2013) 2, 280.