CAS: 82304-66-3; 7,9-Di-Tert-Butyl-1-Oxaspiro[4.5]Deca-6,9-Diene-2,8-Dione

该化合物是一个化学化合物,具有独特的循环结构,包含一种二元和二元酮功能.该化合物具有一个包括一种醚联系的引信双环系统,有助于其稳定性和再活性.两种叔丁基组(1,1-二甲基乙基)的存在增强了其消毒量,可影响其物理特性,例如溶性点和沸点.二氯酮混合物可参与各种化学反应,包括核细胞添加和凝聚反应,使其在有机合成中可能有用.此外,该化合物的结构特征表明,它可能具有有趣的电子特性,这可能与材料科学或医药化学化学相关.

结构式图片

相似化合物

83237-15-4 10396-80-2 15356-74-8

物理性质

MSDS等安全信息

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上下游产品

3-(1-Amino-3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienyl)-propionic acid pentaerythritol ester of 4-hydroxy-3,5-di-tert-butylphenylpropionic acid acetonitrile methyl 3-(4-hydroxy-3,5-di-tert-butyl)phenylpropanoate methyl ester of trans-4-hydroxy-3,5-di-tert-butylcinnamic acid ethyl ester of trans-4-hydroxy-3,5-di-tert-butylcinnamic acid 4-hydroxy-3,5-di-tert-butylphenylpropionic acid 3,5-di-tert-butyl-4-hydroxycinnamic acid

合成工艺路线路线简述

  • 合成目标产物 7,9-Ditert-Butyl-1-Oxaspiro[4.5]Deca-6,9-Diene-2,8-Dione 主要起始原料 Methyl 3-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate
  • 6386-38-5 = 82304-66-3
    反应条件:1.1 Reagents: Tetraphenylporphyrin,Oxygen Solvents: Chloroform; 16 H,Rt1.2 Reagents: Triphenylphosphine Solvents: Chloroform; 20 Min,Rt1.3 Catalysts: P-Toluenesulfonic Acid Solvents: Chloroform; 4 H,50 °C
    标题:A Singlet Oxygen Approach To Oxaspirocycles
    作者:Jones,Kevin M.; Et Al
    参考文献:Tetrahedron Letters 日期:2013 卷标:54(25) 页码:3294-3297]

    = 82304-66-3 [标题:Reaction Conditions
    标题:Reaction Of 6,8-Di-Tert-Butylspiro[4.5]Deca-1-Oxa-5,8-Diene-2,7-Dione With Amines
    作者:Volod'Kin,A. A.; Et Al
    参考文献:Izvestiya Akademii Nauk Sssr 日期:1985 卷标:(5) 页码:1187-90]

    6386-38-5 = 82304-66-3 + 719-22-2 + 131692-75-6
    反应条件:1.1 Catalysts: Vanadate(6-),Nona-μ-Oxotrioxo(Pentadeca-μ-Oxononaoxononamolybdate)[μ12-[phospha... Solvents: Methanol
    标题:Catalytic Oxidation Of 4-Oxoalkyl-Substituted 2,6-Di-Tert-Butylphenol In The Presence Of Trivanadium Molybdophosphoric Heteropolyacids
    作者:Titova,T. F.; Et Al
    参考文献:Zhurnal Prikladnoi Khimii (Sankt-Peterburg 日期:1990 卷标:63(8) 页码:1761-5]

    = 82304-66-3
    反应条件:1.1 Reagents: Triphenylphosphine Solvents: Chloroform; 20 Min,Rt1.2 Catalysts: P-Toluenesulfonic Acid Solvents: Chloroform; Rt -> 50 °C; 4 H,50 °C
    标题:A Singlet Oxygen Approach To Oxaspirocycles
    作者:Jones,Kevin M.; Et Al
    参考文献:Tetrahedron Letters 日期:2013 卷标:54(25) 页码:3294-3297]

    13417-12-4 = 82304-66-3
    反应条件:1.1 Reagents: Triethyl Phosphite,Oxygen Catalysts: Cesium Hydroxide Solvents: Dimethyl Sulfoxide; 12 H,1 Atm,25 °C
    标题:Csoh Catalyzed Aerobic Oxidative Synthesis Of P-Quinols From Multi-Alkyl Phenols Under Mild Conditions
    作者:Liang,Yu-Feng; Et Al
    参考文献:Science China: Chemistry 日期:2015 卷标:58(8) 页码:1334-1339]

    6683-19-8 = 82304-66-3 [标题:Reaction Conditions
    标题:Oxidation Of 4-Substituted 2,6-Di-Tert-Butylphenols With Oxygen In An Alkaline Medium
    作者:Volod'Kin,A. A.; Et Al
    参考文献:Izvestiya Akademii Nauk Sssr 日期:1982 卷标:(7) 页码:1594-7]

    99591-64-7 = 82304-66-3 [标题:Reaction Conditions
    标题:Reaction Of 6,8-Di-Tert-Butylspiro[4.5]Deca-1-Oxa-5,8-Diene-2,7-Dione With Amines
    作者:Volod'Kin,A. A.; Et Al
    参考文献:Izvestiya Akademii Nauk Sssr 日期:1985 卷标:(5) 页码:1187-90]

    = 82304-66-3 [标题:Reaction Conditions
    标题:Reaction Of 6,8-Di-Tert-Butylspiro[4.5]Deca-1-Oxa-5,8-Diene-2,7-Dione With Amines
    作者:Volod'Kin,A. A.; Et Al
    参考文献:Izvestiya Akademii Nauk Sssr 日期:1985 卷标:(5) 页码:1187-90]

    = 82304-66-3 [标题:Reaction Conditions
    标题:Reaction Of 6,8-Di-Tert-Butylspiro[4.5]Deca-1-Oxa-5,8-Diene-2,7-Dione With Amines
    作者:Volod'Kin,A. A.; Et Al
    参考文献:Izvestiya Akademii Nauk Sssr 日期:1985 卷标:(5) 页码:1187-90]

    = 82304-66-3 [标题:Reaction Conditions
    标题:Reaction Of 6,8-Di-Tert-Butylspiro[4.5]Deca-1-Oxa-5,8-Diene-2,7-Dione With Amines
    作者:Volod'Kin,A. A.; Et Al
    参考文献:Izvestiya Akademii Nauk Sssr 日期:1985 卷标:(5) 页码:1187-90]

    = 82304-66-3 [标题:Reaction Conditions
    标题:Reaction Of 6,8-Di-Tert-Butylspiro[4.5]Deca-1-Oxa-5,8-Diene-2,7-Dione With Amines
    作者:Volod'Kin,A. A.; Et Al
    参考文献:Izvestiya Akademii Nauk Sssr 日期:1985 卷标:(5) 页码:1187-90]

    = 82304-66-3 [标题:Reaction Conditions
    标题:Reaction Of 6,8-Di-Tert-Butylspiro[4.5]Deca-1-Oxa-5,8-Diene-2,7-Dione With Amines
    作者:Volod'Kin,A. A.; Et Al
    参考文献:Izvestiya Akademii Nauk Sssr 日期:1985 卷标:(5) 页码:1187-90]

    20170-32-5 = 82304-66-3
    反应条件:1.1 Reagents: Sulfuric Acid; 16 H,Reflux2.1 Reagents: Tetraphenylporphyrin,Oxygen Solvents: Chloroform; 16 H,Rt2.2 Reagents: Triphenylphosphine Solvents: Chloroform; 20 Min,Rt2.3 Catalysts: P-Toluenesulfonic Acid Solvents: Chloroform; 4 H,50 °C
    标题:A Singlet Oxygen Approach To Oxaspirocycles
    作者:Jones,Kevin M.; Et Al
    参考文献:Tetrahedron Letters 日期:2013 卷标:54(25) 页码:3294-3297]

    6386-38-5 = 82304-66-3 + 719-22-2 + 131692-74-5
    反应条件:1.1 Catalysts: Vanadate(6-),Nona-μ-Oxotrioxo(Pentadeca-μ-Oxononaoxononamolybdate)[μ12-[phospha... Solvents: Benzene
    标题:Catalytic Oxidation Of 4-Oxoalkyl-Substituted 2,6-Di-Tert-Butylphenol In The Presence Of Trivanadium Molybdophosphoric Heteropolyacids
    作者:Titova,T. F.; Et Al
    参考文献:Zhurnal Prikladnoi Khimii (Sankt-Peterburg 日期:1990 卷标:63(8) 页码:1761-5]

    8068-03-9 = 82304-66-3 + 96-76-4 + 57-11-4 + 121-33-5 + 57-10-3
    反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 180 Min,22 +/- 2 °C
    标题:Electrochemical Oxidation Of Lignin For The Simultaneous Production Of Bioadhesive Precursors And Value-Added Chemicals
    作者:Conde,Julio J.; Et Al
    参考文献:Biomass And Bioenergy 日期:2023 卷标:169
3-(3,5-二叔丁基-4-羟基苯基)丙酸置于硫酸,氧气,Tetraphenylporphyrin,三苯基膦体系中,用 氯仿 作为反应溶剂,化学反应 36.33H,反应生成 7,9-二叔丁基-1-氧杂螺[4.5]癸-6,9-二烯-2,8-二酮
参考文献:A Singlet Oxygen Approach To Oxaspirocycles
标题:A Singlet Oxygen Approach To Oxaspirocycles
摘要:A Method For The Preparation Of Oxygen Containing Spirocycles Using Singlet Oxygen Is Reported. A Series Of Phenols Were Converted Into The Corresponding Peroxy-Cyclohexadienone Derivatives By Irradiation With Visible Light In The Presence Of A Sensitizer And Oxygen. The Resulting Peroxides Could Be Converted Into Ether And Lactone Spirocycles In One Or Two Steps. The Synthesis Of The Oxaspirocycles From The Phenols Can Also Be Performed In A One-Pot Fashion,Avoiding The Isolation Of The Peroxide Intermediates. (C) 2013 Elsevier Ltd. All Rights Reserved.
DOI:10.1016/j.Tetlet.2013.04.064

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主要参考文献

参考标题:Csoh Catalyzed Aerobic Oxidative Synthesis Of P-Quinols From Multi-Alkyl Phenols Under Mild Conditions
作者:Yu-Feng Liang,Kai Wu,Zhiqing Liu,Xiaoyang Wang,Yujie Liang,Chenjiang Liu,Ning Jiao |发布日期:2015.8
摘要:Research Of C-H Bond Hydroxylation, We Found That Multi-Alkyl Phenols Could React With Molecular Oxygen Under Mild Conditions. Herein, We Describe An Efficient Oxidative De-Aromatization Of Multi-Alkyl Phenols To P-Quinols. 1 Atm Of Molecular Oxygen Was Used As The Oxidant. Many Multi-Alkyl Phenols Could React Smoothly At Room Temperature. Isotopic Labeling Experiment Was Also Performed, And The Result

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摘要:S120 | DUSTCT2024 | Substances from Second NORMAN Collaborative Dust Trial | DOI:10.5281/zenodo.13835254
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