CAS: 106-35-4; Heptan-3-One

该化合物是一个以七碳链为特征的开关,而碳球组位于第三个碳原子,该化合物是室温中无色液体,具有独特,甜和果味的气味,通常可与成熟水果相仿,在乙醇和乙醚等有机溶剂中溶解,但由于其疏水碳链,其溶解性有限. 3-七氯酮易燃,应在通风良好的地区谨慎处理,其沸点相对中度,在各种应用中有用,包括溶剂,调味剂和其他有机化合物的合成中.此外,该化合物在某些天然产品中可找到微量,有时用于食品工业的调味性.与许多氯酮一样,它会发生典型的碳基化合物反应,如核糖添加和氧化,使其在有机合成中成为多用途的中间体.

结构式图片

欧盟法规

统一分类与标签压力设备指令-第1组危险流体ECHA物质欧盟气雾剂指令-标签制度欧盟化学物质指示性职业接触限值ECHA物质工作场所安全标识要求C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号4938-52-7 1-庚烯-3-醇 | CAS号123-05-7 2-乙基已基醛 | CAS号4164-92-5 2-ethylhexanamide | CAS号589-82-2 3-庚醇 | CAS号2108-81-8 (NE)-N-heptan-3... | CAS号34910-43-5 2-azido-1-hexene | CAS号917-54-4 甲基锂 | CAS号142-82-5 正庚烷 | CAS号66227-99-4 4-(trimethylsil... | CAS号87722-28-9 1-tributylstann... | CAS号5396-61-2 3-乙基-1-庚炔-3-醇 | CAS号5582-82-1 3-甲基-3-庚醇 | CAS号64-19-7 冰醋酸 | CAS号598-72-1 2-溴丙酸 | CAS号109-52-4 正戊酸 | CAS号1436-35-7 2-butyl-2-ethyl... | CAS号4346-64-9 methylselanylbenzene | CAS号20754-04-5 3-甲基-4-辛酮 | CAS号107-92-6 正丁酸

合成工艺路线路线简述

  • 合成目标产物 3-Heptanone 主要起始原料 Heptane
  • (文献来源)合成步骤主要原料 Heptane
2-乙基-3-丙基环氧乙烷置于zinc(II) Chloride体系中,化学反应生成3-庚酮
参考文献:Favorsky; Tschitchonkine; Iwanow,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1934,Vol. 199,P. 1230
标题:Favorsky; Tschitchonkine; Iwanow,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1934,Vol. 199,P. 1230

海关参考信息

专利信息


专利号:US-2014296354-A1
优先权日:2013-04-01
标题 :Synthesis of peptoid-based small molecular gelators from multiple component reactions
发明人:WANG GUIJUN; MANGUNURU HARI P R
权利人:WANG GUIJUN; MANGUNURU HARI P R; OLD DOMINION UNIV RES FOUND
摘要:Described herein are the one-pot synthesis and characterization of a library of low molecular weight peptoid compounds that are able to form gels at room temperature. The compounds are synthesized from biologically-based starting materials, are biocompatible, and are resistant to degradation by proteases and peptidases. The compounds and gels synthesized therefrom can be used in such applications as tissue engineering, drug delivery, separation of biomolecules, and stimulus-responsive advanced materials

专利号:US-3959322-A
优先权日:1960-09-22
标 题:Synthesis of 13-alkyl-gon-4-ones
发明人:HUGHES GORDON ALAN; SMITH HERCHEL
权利人:SMITH HERCHEL
摘要:The preparation of 13-methylgon-4-enes and novel 13-polycarbonalkylgon-4-enes by a new total synthesis is described. 13-Alkylgon-4-enes having progestational, anabolic and androgenic activities are prepared by forming a tetracylic gonane structure unsaturated in the 1,3,5(10),9(11) and 14-positions, selectively reducing in the B- and C-rings, and converting the aromatic A-ring compounds so-produced to gon-4-enes by Birch reduction and hydrolysis.

专利号:US-10865163-B2
优先权日:2017-12-20
标题:Carbon dioxide as a directing group for C—H functionalization reactions involving Lewis basic amines, alcohols, thiols, and phosphines for the synthesis of compounds
发明人:YOUNG MICHAEL C; KAPOOR MOHIT
权利人:UNIV TOLEDO
摘要:Methods of synthesizing compounds using CO 2 as a directing group for C—H functionalization, and compounds made thereby, are described.

专利号:US-2005209355-A1
优先权日:2004-03-22
标 题:[Novel Reactions and the Products of Such Reactions]
发明人:ROITMAN LIPA L
权利人:ROITMAN LIPA L
摘要:A process for the synthesis of novel compounds is described comprising reacting tetrachloroethylene with substances containing active methylene group in the presence of free radical initiators. Also, a process for grafting tetrachloroethylene is described comprising reacting these compounds with polymers containing active methylene group in the presence of free radical initiators. Furthermore, a method of conducting such reactions to high conversion is described, comprising conducting the reactions in the reflux condensate. The present invention provides a novel and high yield route for heretofore unobtainable materials.

专利号:US-5188951-A
优先权日:1990-04-17
标题:Enzymatic synthesis of soluble phosphatides from phospholipids
发明人:TREMBLAY PAUL-ALAIN; MARZIANI FRANK; TINO JOHN A F; PILKIEWICZ FRANK G
权利人:LIPOSOME CO INC
摘要:A method of preparing a soluble monovalent salt of a phosphatidyl ester which comprises reacting a phospholipid with a primary alcohol in the presence of an enzyme catalyst in a divalent cationic buffered solution and a water immiscible non-ether solvent that does not inactivate the enzyme, to form a divalent cationic salt of the phosphatidyl ester, and suspending the product in the presence of a stoichiometric amount of a monovalent cationic salt whose anion forms an insoluble salt with the divalent cation. The use of Centrifugal Partition Chromatography facilitates the enzyme reaction. The monovalent salt is preferably an ammonium/sodium mixed salt.

专利号:US-4694108-A
优先权日:1986-08-01
标题:Synthesis of higher ketones
发明人:ELLIOTT DAVID J
权利人:PHILLIPS PETROLEUM CO
摘要:A process of producing higher ketones comprises the step of contacting under suitable conditions a feed comprising (a) at least one C3-C6 aliphatic ketone, (b) at least one C2-C6 aliphatic aldehyde and, preferably, also (c) carbon monoxide with a catalyst composition comprising (i) copper or an oxide thereof and (ii) zinc oxide. Preferably, the feed ketone is methyl ethyl ketone, the feed aldehyde is propanal, and the product comprises at least one C7 ketone.
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合成参考文献


摘要:Sharma, U.; Kumar, R.; Gupta, S. S.; Chandra, D., Science of Synthesis Knowledge Updates, (2022) 2, 330.
摘要:De Wildeman, S.; Sereinig, N., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 169.
摘要:Schmid, T. E.; Crévisy, C.; Baslé, O.; Mauduit, M., Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis, (2016) 2, 361.
摘要:Journal of Industrial Hygiene and Toxicology., 31(60), 1949
摘要:Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 7-4, 7-5, 8-12 (1990)
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