CAS: 768-95-6; Adamantan-1-Ol

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金刚烷置于亚碘酰苯,[rucl(Bpga)(Pph3)]Cl,三氟乙酸体系中,用 1,1,2,2-四氯乙烷 作为反应溶剂,化学反应 1.0H,以77%的收率获得产物1-金刚烷醇
参考文献:非血红素型钌催化化学和位点选择性ch氧化.
标题:非血红素型钌催化化学和位点选择性ch氧化.
摘要:本文中,我们开发了可用于催化化学和位点选择性ch氧化的ru(II)(bpga)络合物.所描述的钌络合物是通过用给电子的酰胺配体取代三(2-吡啶基甲基)胺上的一个吡啶基而设计的,该供电子对促进这种类型的反应至关重要.更重要的是,对于使用顺式钌配合物而不是反式-钌配合物的反应,观测到更高的反应性以及更好的化学和位点选择性.该反应可用于将包括天然产物在内的各种有机底物的空间位阻较少的亚甲基和/或亚甲基ch键转化为有价值的醇或酮产物.
DOI:10.1002/asia.202000134

专利信息

专利号:US-11034664-B1
优先权日:2020-05-11
标题 :Synthesis of cyclic carbonate monomers
发明人：PARK NATHANIEL H; HEDRICK JAMES L; PIUNOVA VICTORIA A; ARRECHEA PEDRO; ERDMANN TIM
权利人:IBM
摘要:Techniques regarding the synthesis of cyclic carbonate monomers are provided. For example, one or more embodiments described herein can comprise a method, which can include cyclizing a functionalized diol monomer with N,N′-carbonyldiimidazole, wherein the cyclizing produces a cyclic carbonate monomer and an imidazole carbamate. The method can also include activating the imidazole carbamate with an acid, wherein the activating promotes cyclization of the imidazole carbamate into the cyclic carbonate monomer.

专利号:US-5789576-A
优先权日:1994-12-09
标题 :Methylphosphonate dimer synthesis
发明人：DAILY WILLIAM J; SCHWARTZ DAVID AARON
权利人:GENTA INC
摘要:Processes for the stereospecific synthesis of 2',2''-bis(deoxy)di-nucleosides and for the stereoselective synthesis of 2',2''-bis(substituted) dinucleosides are provided. Also provided are activated 2'-substituted-nucleoside alkylphosphonate active esters useful in the synthesis of these dinucleosides.

专利号:US-8119835-B2
优先权日:2006-12-28
标 题:Method for preparation of 6-[3-(1-adamantyl)-4-methoxyphenyl]-2-naphtoic acid
发明人：KALVINSH IVARS; CHERNOBROVIJS ALEKSANDRS; TRIBULOVICH VYACHESLAV; LABEISH VLADIMIR
权利人:KALVINSH IVARS; CHERNOBROVIJS ALEKSANDRS; TRIBULOVICH VYACHESLAV; LABEISH VLADIMIR; JSC GRINDEKS
摘要:A method for preparation of 6-[3-(1-adamantyl)-4-methoxyphenyl]-2-naphthoic acid is disclosed based on “one potâ€? synthesis approach including a direct synthesis of boronic acid derivative from 2-(1-adamantyl)-4-bromoanisole and cycloboranes with a subsequent Suzuki-Miyaura coupling with 6-halonaphtenoates and basic hydrolysis of the reaction product in ethylene glycol or 1,2-propanediol.

专利号:US-2008125354-A1
优先权日:2005-11-21
标题 :Selective inhibition of matrix metalloproteinases
发明人：FIELDS GREGG B; HAMMER ROBERT
权利人:UNIV FLORIDA ATLANTIC; UNIV LOUISIANA STATE
摘要:Synthetic triple-helical peptides (THPs) are used for the design and synthesis of triple-helical transition state analog inhibitors. These inhibitors feature a phosphonate ester or phosphinic moiety in place of the scissle bond. These groups inhibit MMPs, and methods been developed for their convenient incorporation within a peptide sequence by solid-phase methods.

专利号:US-7399806-B2
优先权日:2003-06-26
标 题:Synthesis of photoresist polymers
发明人：BENOIT DIDIER; SAFIR ADAM; CHANG HAN-TING; CHARMOT DOMINIQUE; OKAMOTO KENJI; NISHIMURA ISAO; WANG YONG
权利人:SYMYX TECHNOLOGIES INC
摘要:The present invention is directed to the preparation of photoresist polymers via living free radical polymerization techniques. Sterically bulky ester monomers are utilized as the polymerization components. Use of chain transfer agents is included in polymerization processing conditions. Cleavage of polymer terminal end groups that include a heteroatom are described.

专利号:US-5688941-A
优先权日:1990-07-27
标题:Methods of making conjugated 4' desmethyl nucleoside analog compounds
发明人：COOK PHILLIP DAN; TENG KELLY
权利人:ISIS PHARMACEUTICALS INC
摘要:Tetrahydrofuranyl compounds are provided that are functionalized to include pendant conjugate groups, and which are useful in diagnostic assays and as research reagents. Novel intermediates for the synthesis of the compounds are also provided.