1,3-Bis-(Allyloxy)-2,2-Dimethyl-Propan置于间氯过氧苯甲酸体系中,用 氯仿 用作溶剂,化学反应生成新戊二醇二缩水甘油醚 参考文献:Nucleophilic Opening Of Bis-Epoxides: A New Access To Symmetrically Functionalised Macrocycles 标题:Nucleophilic Opening Of Bis-Epoxides: A New Access To Symmetrically Functionalised Macrocycles 摘要:A Series Of Polyhydroxylated Symmetrical Macrocycles Has Been Prepared In Satisfactory Yield By 1:1 Condensation Of Several Bis-Epoxides With Various Bis-Nucleophiles. Preliminary Results Are Reported,Which Illustrate The Synthesis Of Crown Ethers And Oxa-Azacrown And Oxa-Thiacrown Compounds. (C) 2000 Elsevier Science Ltd. All Rights Reserved. Doi:10.1016/s0040-4039(99)02219-4
专利号:US-2023348657-A1 优先权日:2020-07-23 标题 :Synthesis of linear polyoxazolidinones using uretdiones as diisocyanate component 发明人:QUELL AGGELIKI; THOMAS HANS-JOSEF; ELING BEREND 权利人:BASF SE 摘要:A process for preparing a thermoplastic polymer involves reacting at least components (a) to (b), in the presence of a catalyst composition (c). Component (a) is an isocyanate composition containing at least one uretdione diisocyanate (a-i), and component (b) is an epoxide composition containing at least one diepoxide (b-i). The catalyst composition (c) contains at least one ionic liquid (c-i), preferably selected from 1-ethyl-3-methyl imidazolium bromide, 1-benzyl-3-methyl imidazolium chloride. 1-butyl-1-methylpiperidinium chloride, 1-ethyl-2,3-dimethylimidazolium bromide, 1-(2-hydroxyethyl)-3-methyl imidazolium chloride, butyl-1-methylpiperidinium acetate, or mixtures of two or more thereof. A thermoplastic polymer obtained or obtainable from the process is useful for the preparation of a fibre or a molded article or as a modifier for another thermoplastic material.
专利号:US-10385167-B2 优先权日:2015-02-13 标题:Process for the synthesis of polyoxazolidinone compounds with high stability 发明人:MÜLLER THOMAS ERNST; Gürtler Christoph; BASU SUSMIT; RANGHEARD CLAUDINE; RIVILLO DAVID; LEITNER WALTER; Köhler Burkhard 权利人:COVESTRO DEUTSCHLAND AG 摘要:The present invention relates to polyoxazolidinone compounds, a method for the production of polyoxazolidinone compounds, comprising the step of reacting a biscarbamate compound with a bisepoxide compound in the presence of a mono-carbamate, a mono-isocyanate and/or a mono-epoxide compound as chain regulator and a suitable base having a pK b value of ≤9 as catalyst. The invention further relates to the use of polyoxazolidinone compounds with high thermal stability.
专利号:US-11326018-B2 优先权日:2016-08-19 标 题:Process for the synthesis of polyoxazolidinone compounds 发明人:WEBER ANNA; RANGHEARD CLAUDINE; KESSLER MICHAEL; LEITNER WALTER; Gürtler Christoph; KOOPMANS CARSTEN; MÜLLER THOMAS ERNST 权利人:COVESTRO DEUTSCHLAND AG 摘要:A method for the production of polyoxazolidinone compounds, comprising the step of reacting an isocyanate compound (A) with an epoxide compound (B) in the presence of a catalyst (C), wherein the isocyanate compound (A) comprises a isocyanate compound (A 1 ) wherein the a isocyanate compound (A1) comprising at least two isocyanate groups (I 1 ≥2), preferred two isocyanate groups (I 1 =2), wherein the epoxide compound (B) comprises a epoxide compound (B 1 ) and an epoxide compound (B 2 ), wherein the epoxide compound (B 2 ) is different from the epoxide compound (B 1 ) wherein the epoxide compound (B 1 ) comprising at least two terminal epoxide groups (F1≥2), preferred two terminal epoxide groups (F 1 =2), linked together by a linking group (L1) and the epoxide compound (B 2 ) comprising at least two terminal epoxide groups (F 2 ≥2)), preferred two terminal epoxide groups (F 2 =2), linked together by a linking group (L 2 ), wherein the linking group (L 2 ) comprises acyclic and covalent bonds to each other free of conjugated multiple bonds within the main chain, wherein the epoxide compound (B 2 ) is present in the epoxide compounds B 1 and B 2 , in an amount of ≥0.01 mol-% to <10 mol-%, preferred 1-9 mol-% more preferred 3-8 mol-% based on the molar ratio the terminal epoxide groups in the epoxide compound (B 1 ) and of the sum of the terminal epoxide groups in the epoxide compound (B 1 ) and terminal epoxide groups in the epoxide compound (B 2 ).
专利号:US-7232877-B2 优先权日:2001-10-01 标 题:Preparation of oligomeric cyclocarbonates and their use in ionisocyanate or hybrid nonisocyanate polyurethanes 发明人:FIGOVSKY OLEG; SHAPOVALOV LEONID 权利人:HOMECOM COMMUNICATIONS INC 摘要:A method and apparatus for synthesis of oligomeric cyclocarbonates from epoxy compounds and carbon dioxide in the presence of a catalyst. Star epoxy compounds and their preparation and use in making star cyclocarbonates, star hydroxy urethane oligomers, and star NIPU and HNIPU. Acrylic epoxy compounds, acrylic cyclocarbonates, acrylic hydroxy urethane oligomers, and acrylic NIPU and HNIPU and their methods of preparation.
专利号:US-2025075200-A1 优先权日:2022-05-27 标题:Biocatalysts for organic synthesis 发明人:ALVARENGA DA SILVA NATALIA; STRIDFELDT ELIN; VOLKOV ALEXEY; RUGGIERI FEDERICA; HENDIL-FORSSELL PETER; RÄMGÃ…RD CARL; BAUMGARTEN THOMAS; MATTEY ASHLEY; MURPHY VINCE; THOMPSON MATTHEW P; CLEMMENTS ALDEN M; GERGEL SEBASTIAN 权利人:ENGINZYME AB 摘要:The invention relates to a biocatalyst for organic synthesis, comprising a controlled porosity silica (CPS) as support material, wherein the pore diameter is between about 20 and about 100 nm, said support material comprising an amino-functionalized surface; and one or more catalytically active enzyme(s) immobilized on the support material. The invention also relates to uses of such biocatalysts and methods of manufacture thereof.
专利号:US-2023182087-A1 优先权日:2020-04-28 标 题:Thin-Film Composite Membranes Synthesized by Multi-Step Coating Methods 发明人:DAVENPORT DOUGLAS; VANKELECOM IVO; VERBEKE RHEA 权利人:UNIV LEUVEN KATH 摘要:The invention relates to methods for the synthesis of a thin-film composite membrane, comprising the following steps: a) providing an ultrafiltration porous support membrane, coated at the outer surface with a thin film, synthesized through interfacial polymerisation or interfacial initiation of polymerisation, b) contacting the membrane with a first solution comprising a first monomer, and allowing the solution to impregnate inside the thin film of the membrane, c) discarding the first solution comprising the first monomer, d) contacting the membrane with a second solution comprising a second monomer, and allowing the solution to impregnate inside the thin film of membrane, whereby the second monomer reacts with the first monomer and optionally with reactive groups of the thin film, e) discarding the second solution comprising the second monomer.
[参考文献]: Lucas Vu, Et Al. Generation Of A Focused Poly(Amino Ether) Library: Polymer-Mediated Transgene Delivery And Gold-Nanorod Based Theranostic Systems. Theranostics. 2012;2(12):1160-73.
合成参考文献
摘要:Patty's Industrial Hygiene and Toxicology, 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2n rev. ed. in 1985., 2A(2212), 1981