专利号:US-12365760-B2 优先权日:2019-05-13 标题 :Process for the synthesis of polycarbonates from cyclic monothiocarbonates 发明人:RUDOLF PETER; THIEL INDRE; WURM THOMAS MAXIMILIAN 权利人:BASF SE 摘要:A process can be used for the synthesis of compounds containing at least one non-cyclic carbonate group, wherein a compound A) containing at least one five-membered cyclic monothiocarbonate group is reacted with at least one hydroxy group of a compound B) or of compound A) itself.
专利号:US-5073643-A 优先权日:1990-08-30 标 题 :High yield synthesis of hydroxyl-containing cationic photoinitiators 发明人:CRIVELLO JAMES V 权利人:POLYSET CORP 摘要:Synthesis use of a new class of diaryliodonium salt photo and thermal polymerization initiators in which the aryl groups are substituted with alkoxy group bearing hydroxy groups. Good to excellent yields are obtained of diaryliodonium salts in which the aryl groups are substituted with long chain alkoxy groups, which alkoxy groups also possess at least one hydroxyl moiety attached at the 2-position of an alkoxy group. The resultant salts have enhanced solubility when compared with their lower molecular weight counterparts. The hydroxyl groups serve as chain transfer agents; and, in cross linking UV-induced cationic polymerizations, the hydroxyl groups effect marked accelertion on polymerization rates. The salts also have excellent compatability with nonpolar monomers such as epoxidized oil and poly(1,2-butadience oxide) and provide further benefits when they are used along with copper cocatalysts in thermally curable polymer systems. In the latter form of cases, the secondary hydroxyl group serves as a reducing agent for the copper (II) complex.
专利号:US-7728088-B2 优先权日:2002-08-06 标题 :Synthesis of statistical microgels by means of controlled radical polymerisation 发明人:DESTARAC MATHIAS; BAVOUZET BRUNO; TATON DANIEL 权利人:RHODIA OPERATIONS 摘要:The invention relates to a method of preparing statistical microgels. The inventive method comprises a step involving the radical polymerisation of a composition containing: at least one monoethylenically-unsaturated monomer, at least one multiethylenically-unsaturated monomer, a free radical source and a control agent. The invention also relates to first generation microgels thus prepared and all the compounds resulting from said microgels (next-generation microgels).
专利号:US-6384216-B1 优先权日:2000-08-09 标 题 :Purification of alkenyl compounds 发明人:LORENZ RUDOLF ERICH; BOETTCHER ARND; PINKOS ROLF 权利人:BASF AG 摘要:A process for purifying alkenyl compounds having a divalent or trivalent heteroatom in the alpha-position relative to the double bond by distillation comprises carrying out at least two distillations in which the purified alkenyl compounds are obtained from the gas phase by condensation, where the time between the first distillation after the synthesis of the alkenyl compounds and at least one further distillation is at least one day and the purified alkenyl compounds have an APHA color number of <30.
专利号:WO-2013067646-A1 优先权日:2011-11-12 标题:Process for the synthesis of beta-aminocarbonyls 发明人:BEAUCHEMIN ANDRE MARTIN; CLAVETTE CHRISTIAN; GAN WEI; MARKIEWICZ THOMAS; TODERIAN AMY BEVERLY 权利人:UNIV OTTAWA 摘要:The present application provides processes and intermediates useful in the production of β- aminocarbonyl- or β-aminothiocarbonyl-containing compounds. Provided herein is a process for synthesizing β-aminocarbonyl- or β-aminothiocarbonyl-containing compounds from an alkene and a hydrazone. Also provided herein is a process for synthesizing β-aminocarbonyl- or β-aminothiocarbonyl-containing compounds from an alkene and a hydrazine. The present application further provides intermediate aminoisocyanate and iminoisocyanate compounds, and methods for synthesizing the starting hydrazone and hydrazine compounds.
专利号:US-5272233-A 优先权日:1992-07-17 标题 :Platinum-based catalysts for the polymerization of vinyl ether monomers and polymers 发明人:CRIVELLO JAMES V; FAN MINGXIN 权利人:GEN ELECTRIC 摘要:The present invention relates to a curable polyvinyl ether composition created using a novel catalyst system for the synthesis of polyethers from vinyl ether monomers or polymers. This catalyst system comprises a platinum complex catalyst and silicon hydride cocatalyst. The invention also relates to a method of producing polyethers from vinyl ether monomers or polymers using the above-mentioned catalyst system.
参考标题:Versatile Synthesis Of Bicyclo[4.3.0]Nonenes And Bicyclo[4.4.0]Decenes By A Domino Heck-Diels-Alder Reaction 作者:Kiah How Ang,Stefan Bräse,Arno G. Steinig,Frank E. Meyer,Amadeu Llebaria,Katharina Voigt,Armin De Meijere |发布日期:1996.8 摘要:Afterwards In A One-Pot Process) To Give Bicyclo[4.3.0]Nonene And Bicyclo[4.4.0]-Decene Derivatives In Good To Excellent Yields. Among The Examples Reported Are The First Cases Of Intramolecular Heck Reactions With A (Bromomethylene)Cyclopropane Starter Or/and A Methylenecyclopropane Terminator Which Occur Without Ring Opening Of The Cyclopropyl Group.