专利号:US-10968174-B2 优先权日:2016-12-21 标题:Synthesis of a thiosulfonic acid by a step of periodate mediated oxidative coupling of a thiosulfonic acid with an aniline 发明人:SINCLAIR JAMES PETER; NICOLL SARAH LOUISE; STOREY JOHN MERVYN DAVID; LARCH CHRISTOPHER PAUL 权利人:WISTA LAB LTD 摘要:The present invention pertains generally to the field of chemical synthesis, and more particularly to methods for the chemical synthesis of a thiosulfonic acid of Formula (1) by a step of periodate mediated oxidative coupling of a thiosulfonic acid of Formula (2) with an aniline of Formula (3), as described herein. The present invention also relates to such methods which incorporate one or more additional (subsequent and/or preceding) steps, for example, to prepare compounds of Formula (5) from compounds of Formula (1); to prepare compounds of Formula (6) from compounds of Formula (5); and to prepare compounds of Formula (2) from compounds of Formula (4), as described herein.
专利号:US-5523434-A 优先权日:1995-03-15 标 题 :Synthesis of bleach activators 发明人:BURNS MICHAEL E; SIMPSON ANTHONY J 权利人:PROCTER & GAMBLE 摘要:The synthesis of phenol sulfonate esters of alkanoyl amino acids is conducted in the presence of aqueous base to provide bleach activator compounds. Thus, the acid chloride of N-nonanoyl-6-aminocaproic acid is reacted with the sodium salt of p-phenol sulfonate in the presence of water at a pH in the range of about 9 to about 12 to yield the corresponding phenol sulfonate ester. The synthesis of the phenol sulfonate ester of the monononyl amide of adipic acid is also illustrated.
专利号:WO-9507882-A1 优先权日:1993-09-14 标 题:Synthesis of amido acids from carboxylic acid esters and amino acid salts 发明人:HEINZMAN STEPHEN WAYNE; DUPONT JEFFREY SCOTT 权利人:PROCTER & GAMBLE 摘要:Chemical synthesis of amido acids, and their conversion to amido acid phenyl ester sulfonates for use as bleach activators, starting from carboxylic acid esters and amino acid salts.
专利号:US-5534642-A 优先权日:1993-09-14 标题 :Synthesis of amido acids from carboxylic acids and lactams 发明人:HEINZMAN STEPHEN W; DUPONT JEFFREY S; TETTENHORST WILLIAM C 权利人:PROCTER & GAMBLE 摘要:Chemical synthesis of amido acids, and their conversion to amido acid phenyl ester sulfates for use as bleach activators, starting from carboxylic acids and lactams.
专利号:US-2004225153-A1 优先权日:2003-02-13 标题 :Synthesis of polyphosphazenes with sulfonimide side groups 发明人:ALLCOCK HARRY R; HOFMANN MICHAEL A; AMBLER CATHERINE M; MAHER ANDREW E; WOOD RICHARD M; WELNA DANIEL T 权利人:PENN STATE RES FOUND 摘要:The invention relates to sulfonimide bearing phenolic compounds and the use of those compounds to produce polyphosphazenes functionalized by one or more of those compounds alone, or in combination with cosubstituents. The invention also relates to blends of sulfonimide functionalized phosphazene polymers with other polymers, membranes formed of the functionalized polymers, and the use of those membranes in devices such as fuel cells.
专利号:US-4143050-A 优先权日:1977-01-05 标题 :Manufacture of 3-halosulfonylthiophene-carboxylic acid compounds 发明人:ROSSY PHILLIP A; HOFFMANN WERNER; MUELLER NORBERT 权利人:BASF AG 摘要:3-Halosulfonylthiophene-carboxylic acid compounds are manufactured by reacting 3-ketothiophane-carboxylic acid compounds with sulfonic acid compounds, reacting the end product from the 1st reaction stage with alkali metal polysulfides, reacting the end product from the 2nd stage with a dehydrogenating agent and finally reacting the end product from the 3rd stage with halogen and water. The products are starting compounds for the manufacture of drugs, dyes and crop protection agents and have an anti-inflammatory, analgesic and anti-rheumatic action. In particular, the end products I are starting materials for the manufacture of sweeteners which are non-toxic and free from an after-taste, flavor-improving agents, diabetic aids and feedstuffs, and provide the means of a simple and economical synthesis of thiophene-saccharins.
[参考文献]: A M Lambeir, Et Al. Kinetics Of The Oxidation Of Ascorbic Acid, Ferrocyanide And P-Phenolsulfonic Acid By Chloroperoxidase Compounds I And Ii. Eur J Biochem. 1987 Feb 16;163(1):123-7. [参考文献]: F R Johannsen, Et Al. Toxicity And Uptake Potential Of An Acrylic Polymer Comonomer And Its Biological Degradation Products. Bull Environ Contam Toxicol. 1988 Mar;40(3):325-31. [参考文献]: T Yokka, Et Al. [参考文献]: Shigaku. 1987 Jun;75(1):50-62.
合成参考文献
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