CAS: 1873-89-8; 1,1,1,5,5,5-Hexamethyl-3-((Trimethylsilyl)Oxy)Trisiloxane

该化合物是一种硅化合物,其特点是三甲基硅氧化合物组群与中硅原子捆绑在一起,这种技术级材料主要用于工业应用,包括表面改造,交叉连接和硅酮化学前体,其主要优点包括:由于存在多种硅氧化合物组,因此具有较高的再活性,有利于与基质或聚合物有效结合;该化合物具有热稳定性和疏水性能,适合涂层和粘合剂;技术级纯度确保大型工艺的成本效益,同时在严格的化学环境中保持一贯性能.

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3555-47-3 17928-28-8 17082-47-2

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CAS号107-46-0 六甲基二硅氧烷 | CAS号75-77-4 三甲基氯硅烷 | CAS号1066-40-6 三甲基硅醇 | CAS号18027-10-6 三甲基硅氧基钠 | CAS号556-67-2 八甲基环四硅氧烷 | CAS号917-54-4 甲基锂 | CAS号17477-97-3 三(三甲基硅基氧化)硅醇 | CAS号17905-99-6 三(三甲基硅氧基)氯硅烷 | CAS号74098-43-4 三(三甲硅烷氧基)硅醇

合成工艺路线路线简述

    三甲基硅醇置于吡啶,三氯硅烷体系中,用 正己烷 用作溶剂,以53%的收率获得三(三甲硅烷氧基)硅烷
    参考文献:需氧的co或cu / Nhpi催化氢化硅氧烷的氧化:合成硅氧烷醇
    标题:需氧的co或cu / Nhpi催化氢化硅氧烷的氧化:合成硅氧烷醇
    摘要:提出了一种高效的制备方法,该方法基于需氧的co(oac)2或cu(oac)2 / Nhpi催化的氢化硅氧烷的氧化,使用"绿色",市售,简单廉价的试剂和温和的反应条件进行.这是合成具有各种结构(直链,支链和环状)的单,低聚和聚合硅氧烷醇的一般反应.
    Doi:10.1039/c8Gc00424B

    专利信息


    专利号:US-2012238661-A1
    优先权日:2011-01-14
    标 题 :Processes for the Synthesis of Compounds from Cyclic Carbonates
    发明人:IYER RAMESH; MCKENNA PETER; SMALLRIDGE MARK; MATTHEWS MELISSA; NATESH ANBAZHAGAN
    权利人:IYER RAMESH; MCKENNA PETER; SMALLRIDGE MARK; MATTHEWS MELISSA; NATESH ANBAZHAGAN; COGNIS IP MAN GMBH
    摘要:The invention provides compounds containing the ring-opening products of ethylenically unsaturated cyclic carbonates for use in preparing hydrogel polymers, as well as methods for their preparation. A preferred method of the invention includes the reaction of nucleophilic compounds containing Si, F, N or O atoms, or combinations thereof, or latent moieties in the form of unsaturated or hydroxylated functional groups, with ethylenically unsaturated glycerol carbonate derivatives. The compounds and hydrogel polymers are useful for the preparation of contact lenses.

    专利号:US-4746750-A
    优先权日:1987-08-31
    标 题 :Synthesis of silyl ketene acetal from allyl 2-organoacrylates
    发明人:REVIS ANTHONY
    权利人:DOW CORNING
    摘要:A process is described for preparing silyl ketene acetals having the formula, n n (CH.sub.3)RCâ•?C(OSiR.sup.i.sub.3).sub.2, n n from allyl 2-organoacrylates. The process comprises contacting an allyl 2-organoacrylate with a trisubstituted silane in the presence of a rhodium catalyst; and separating and isolating the silyl ketene acetal. Silyl ketene acetal of greater than 85-90 percent purity can be recovered.

    专利号:US-5110970-A
    优先权日:1991-03-29
    标题 :Process for the manufacture of certain new silicone polyether copolymers for polyurethane foam manufacture
    发明人:BLEVINS II CHARLES H; MATLOCK PAUL L; MURPHY GERALD J
    权利人:UNION CARBIDE CHEM PLASTIC
    摘要:This invention relates to silicone surfactants, and more particularly, to synthesis of siloxane-polyether surfactants having polyether backbones.

    专利号:US-2013231488-A1
    优先权日:2010-10-25
    标 题 :Process for preparing 2-hydroxyphenyl alkenyl benzotriazole compounds; use of the said compounds obtained via the process in the synthesis of siloxane compounds containing a 2-hydroxyphenylbenzotriazole function

    专利号:US-9447123-B2
    优先权日:2010-10-25
    标 题:Process for preparing 2-hydroxyphenyl alkenyl benzotriazole compounds; use of the said compounds obtained via the process in the synthesis of siloxane compounds containing a 2-hydroxyphenylbenzotriazole function
    发明人:RICHARD HERVE; XU JINZHU; GUERREIRO PATRICIO; WANG YUAN; GUO JIANPING
    权利人:RICHARD HERVE; XU JINZHU; GUERREIRO PATRICIO; WANG YUAN; GUO JIANPING; OREAL
    摘要:The process for preparing 2-hydroxyphenyl alkenyl benzotriazole compounds and the process for preparing siloxane compounds containing 2-hydroxyphenyl benzotriazole function are disclosed.

    专利号:EP-2643309-A1
    优先权日:2010-11-24
    标题:Synthesis of n-heterocycles by reductive alkylation of cyan derivatives
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    主要参考文献

    参考标题:Synthesis, Crystal And Molecular Structure Of N,N-Dimethyl-3-[tris(Trimethylsiloxanyl)Silyl]Pyrrolinium Chloride
    作者:R. Rudert,G. Schmaucks |发布日期:1994.7
    摘要:The Synthesis Of N,N-Dimethyl-3-[tris(Trimethylsiloxanyl)Silyl]Pyrrolinium Chloride Was Carried Out By Hydrosilylation Of 1,4-Dichlorobut-2-Yne With Tris(Trimethylsiloxanyl)Silane Followed By The Reaction Of The Product With Dimethylamine. The Structure Of The Crystalline White Solid Was Determined By An X-Ray Diffraction Study. The Siosi Angles Range From 145.8(3)° To 161.4(4)°. The Molecules Are

    合成参考文献


    摘要:Baudrenghien, L.; Markó, I. E., Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis, (2016) 1, 317.
    摘要:Cheng, Z.; Zheng, Y.; Lu, Z., Science of Synthesis: Knowledge Updates, (2023) 1, 329.
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