CAS: 821-95-4; 1-Undecene

• 英文名称1-Undecene
• 中文名称1-十-烯
• IUPAC名称undec-1-ene
• 其它别名n-1-Undecene; a-Undecene
• CAS编号821-95-4
• MFCD编号:MFCD00008956
• EINECS号:212-483-7
• 分子式:C11H22
• 分子量:154.3
• 产品CID: 1813406
• 产品分类有机原料 → 烃类化合物及其衍生物 → 无环烃

• 相似结构搜索
• 产品信息参考;
• InChIKey: DCTOHCCUXLBQMS-UHFFFAOYSA-N
• InChI=1S/C11H22/c1-3-5-7-9-11-10-8-6-4-2/h3H,1,4-11H2,2H3…
• 计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数8.0

物理性质

• 熔点−49  °C(文献)
• 沸点193.0±3.0 °C at 760 mmHg
• 闪点62.8±0.0 °C
• 密度0.8±0.1 g/cm3
• PSA:0.0
• LogP:6.09
• 折射率1.427
• 蒸汽压0.7±0.2 mmHg at 25°C
• 溶解性Sol in ether, chloroform, ligroin; insol in water
• 敏感性1. 存在于烟气中。
• 外观形态液体;Colorless to Almost colorless clear liquid
• 储存条件存放于惰性气体之中;避免空气
• 产品应用该化合物用于 (+) DEOXOPROSOPININE 的合成 .

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别急性毒性 类别4(吸入)
  急性毒性 类别4(经口)
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Warning(警告)
• 危险描述H332 |吸入有害.
  H302 |吞咽有害.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P261-P264-P280-P304+P340+P312-P337+P313-P403+P233-
• UN编号3295
• 危险品标志Xn,F
• 安全声明S26-S36
• 危险类别码R20/22,R36/37/38
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 1-Undecene 主要起始原料 P-Toluenesulfonic Acid N-Octyl Ester And Allylmagnesium Chloride
• 143-07-7 = 821-95-4
  反应条件:1.1 Reagents: Pivalic Anhydride Catalysts: Pyridine,2021209-62-9 Solvents: γ-Valerolactone; 15 H,110 °C
  标题:Green Solvent For The Synthesis Of Linear α-Olefins From Fatty Acids
  作者:Hopen Eliasson,Sondre H.; Et Al
  参考文献:Acs Sustainable Chemistry & Engineering 日期:2019 卷标:7(5) 页码:4903-4911]
  
  1779-49-3 + 112-31-2 = 821-95-4
  反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Tetrahydrofuran; 1 H,0 °C1.2 Solvents: Tetrahydrofuran; 0 °C; 1.5 H,Rt
  标题:Regio- As Well As Stereoselective Epoxide Ring Opening Reactions Using 3,3,3-Trifluoroprop-1-Yne
  作者:Yamazaki,Takashi; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2022 卷标:257 页码:257-258]
  
  112-53-8 = 821-95-4
  反应条件:1.1 Catalysts: 3-Methoxybenzoic Acid,Bis[(1,2,5,6-η)-1,5-Cyclooctadiene]Di-μ-Methoxydirhodium,1,1′-(9,9-Dimethyl-9H-Xanthene-4,5-Diyl)Bis[1,1-Diphenylphosphine] Solvents: Toluene; 3 Min,Rt1.2 Reagents: N,N-Dimethylacrylamide; 24 H,90 °C
  标题:Tandem Catalysis: Transforming Alcohols To Alkenes By Oxidative Dehydroxymethylation
  作者:Wu,Xuesong; Et Al
  参考文献:Journal Of The American Chemical Society 日期:2018 卷标:140(32) 页码:10126-10130]
  
  119099-74-0 = 821-95-4
  反应条件:1.1 Reagents: Water Solvents: 1,4-Dioxane; 0 °C1.2 Reagents: Boron Trifluoride Etherate; 1 H,0 °C
  标题:Unsaturated Sulfinamides. Xii. Substituted 4-(2-Alkenesulfinyl)Morpholines: Preparation And Conversion Into The Corresponding Sulfinic Acids And Esters. Stereochemistry Of Olefin Formation By Hydrolytic Desulfinylation Of Allylic Sulfinamides
  作者:Baudin,Jean-Bernard; Et Al
  参考文献:Bulletin De La Societe Chimique De France 日期:1995 卷标:132(2) 页码:196-214]
  
  119099-74-0 = 821-95-4
  反应条件:1.1 Reagents: Boron Trifluoride Etherate,Water Solvents: 1,4-Dioxane
  标题:Unsaturated Sulfinamides. Iii. Conversion Of Several 4-(2'-Alkenesulfinyl)Morpholines Into The Corresponding Sulfinate Esters,Unsymmetrical Bisallylic Sulfones,And Olefins. Isolation Of Some Functionalized 2-Alkenesulfinic Acids
  作者:Baudin,Jean Bernard; Et Al
  参考文献:Tetrahedron Letters 日期:1988 卷标:29(26) 页码:3255-8]
  
  629-27-6 = 821-95-4
  反应条件:1.1 Reagents: Di-Sec-Butylmagnesium Solvents: Toluene; 4 H,40 °C1.2 -20 °C1.3 Reagents: Ammonium Chloride Solvents: Water1.4 Reagents: Dilithium Dichlorocyanocuprate Solvents: Tetrahydrofuran; 30 Min
  标题:Preparation Of Primary And Secondary Dialkylmagnesiums By A Radical I/mg-Exchange Reaction Using Sbu2Mg In Toluene
  作者:Sunagatullina,Alisa S.; Et Al
  参考文献:Angewandte Chemie 日期:2022 卷标:61(13)]
  
  62168-28-9 = 821-95-4
  反应条件:1.1 Reagents: Samarium,Samarium Iodide (Smi2) Solvents: Tetrahydrofuran
  标题:Alkylidenation Of Ketones By Gem-Dibromoalkane,Smi2,And Sm In The Presence Of Catalytic Amount Of Crcl3
  作者:Matsubara,Seijiro; Et Al
  参考文献:Chemistry Letters 日期:1995 卷标:(4) 页码:259-60]
  
  62168-28-9 = 821-95-4 [标题:Reaction Conditions
  标题:Synthesis Of Alkenes By Elimination Reactions
  作者:Kostikov,R. R.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:47 页码:771-881]
  
  2243-98-3 = 821-95-4
  反应条件:1.1 Reagents: Piperazine,Hydrogen Catalysts: Gold (Poly(Vinyl Alc.) Stabilized And Carbon Supported) Solvents: Ethanol; 24 H,6 Bar,80 °C
  标题:Piperazine-Promoted Gold-Catalyzed Hydrogenation: The Influence Of Capping Ligands
  作者:Fiorio,Jhonatan L.; Et Al
  参考文献:Catalysis Science & Technology 日期:2020 卷标:10(7) 页码:1996-2003]
  
  4117-09-3 + 693-04-9 = 821-95-4
  反应条件:1.1 Catalysts: Cupric Chloride Solvents: Tetrahydrofuran; Rt; Rt -> -78 °C1.2 Reagents: 1,3-Butadiene Solvents: Tetrahydrofuran; -78 °C; 24 H,25 °C1.3 Reagents: Hydrochloric Acid Solvents: Water
  标题:Copper-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions Using Hydrocarbon Additives: Efficiency Of Catalyst And Roles Of Additives
  作者:Iwasaki,Takanori; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2014 卷标:79(18) 页码:8522-8532]
  
  94088-25-2 = 821-95-4
  反应条件:1.1 Reagents: Formic Acid,Triethylamine Catalysts: Tributylphosphine,Palladium,Tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-Diphenyl-1,4-Pentadien-3-One]]Di-,... Solvents: Tetrahydrofuran
  标题:Selectivities In Organic Reactions Via π-Allylpalladium Complexes
  作者:Tsuji,Jiro
  参考文献:Pure And Applied Chemistry 日期:1989 卷标:61(10) 页码:1673-80]
  
  94088-25-2 = 821-95-4
  反应条件:1.1 Reagents: Formic Acid,Triethylamine,Tributylphosphine Catalysts: Palladium,Tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-Diphenyl-1,4-Pentadien-3-One]]Di-,... Solvents: Tetrahydrofuran
  标题:Preparation Of 1-Alkenes By The Palladium-Catalyzed Hydrogenolysis Of Terminal Allylic Carbonates And Acetates With Formic Acid-Triethylamine
  作者:Tsuji,Jiro; Et Al
  参考文献:Synthesis 日期:1986 卷标:(8) 页码:623-7]
  
  94088-25-2 = 821-95-4
  反应条件:1.1 Reagents: Poly(Methylhydrosiloxane) Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran
  标题:Ionic And Organometallic-Catalyzed Organosilane Reductions
  作者:Larson,Gerald L.; Et Al
  参考文献:Organic Reactions (Hoboken 日期:2008 卷标:71 页码:1-737]
  
  17049-49-9 = 821-95-4
  反应条件:1.1 Catalysts: Bis(Tri-Tert-Butylphosphine)Palladium Solvents: Tetrahydrofuran; 25 °C; 5 - 10 Min,25 °C; 3 H,25 °C
  标题:Palladium-Catalyzed Desulfinylative C-C Allylation Of Grignard Reagents And Enolates Using Allylsulfonyl Chlorides And Esters
  作者:Rao Volla,Chandra M.; Et Al
  参考文献:Tetrahedron 日期:2009 卷标:65(2) 页码:504-511]
  
  80262-79-9 = 821-95-4 [标题:Reaction Conditions
  标题:Chemistry Of Alkali Metal Tetracarbonylferrates. Synthesis Of Amines And Dehalogenation Reactions By A Polymer Supported Iron Carbonyl Complex
  作者:Boldrini,Gian Paolo; Et Al
  参考文献:Journal Of Organometallic Chemistry 日期:1983 卷标:243(2) 页码:195-8]
  
  2622-05-1 + 3386-35-4 = 821-95-4
  反应条件:1.1 Reagents: Chloroethenylmagnesium Solvents: Tetrahydrofuran; 1 Min,25 °C1.2 Reagents: Hydrochloric Acid Solvents: Water
  标题:Novel Nickel-Catalyzed Coupling Reaction Of Allyl Ethers With Chlorosilanes,Alkyl Tosylates,Or Alkyl Halides Promoted By Vinyl-Grignard Reagent Leading To Allylsilanes Or Alkenes
  作者:Terao,Jun; Et Al
  参考文献:Advanced Synthesis & Catalysis 日期:2004 卷标:346(13-15) 页码:1674-1678]
  
  115221-59-5 = 821-95-4
  反应条件:1.1 Reagents: Butyllithium,Zirconocene,Dichloride Solvents: Tetrahydrofuran1.2 Reagents: Hydrochloric Acid Solvents: Water
  标题:Stereoselective Preparation Of E Vinyl Zirconium Derivatives From E Or Z Enol Ethers
  作者:Liard,Annie; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2000 卷标:65(21) 页码:7218-7220]
  
  51148-67-5 = 821-95-4
  反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 0 °C; 3 H,Reflux; Reflux -> 0 °C1.2 Reagents: Sodium Sulfate Solvents: Diethyl Ether,Water; 0 °C
  标题:Total Synthesis And Antifungal Activity Of (2S,3R)-2-Aminododecan-3-Ol
  作者:Vijai Kumar Reddy,T.; Et Al
  参考文献:Bioorganic & Medicinal Chemistry Letters 日期:2012 卷标:22(14) 页码:4678-4680]
  
  62168-28-9 = 821-95-4
  反应条件:1.1 Reagents: Butyllithium Solvents: Diethyl Ether
  标题:Decomposition And Electrophilic Properties Of Nonfunctionalized Monohalogenated Carbenoids
  作者:Villieras,J.; Et Al
  参考文献:Bulletin De La Societe Chimique De France 日期:1985 卷标:(5) 页码:837-43]
  
  2243-98-3 = 821-95-4
  反应条件:1.1 Reagents: Hydrogen Catalysts: Nickel (Nano Ni Graphene Oxide Polyaniline Hybrid Catalyst) Solvents: Dichloromethane; 24 H,Rt
  标题:Nickel-Decorated Graphene Oxide/polyaniline Hybrid: A Robust And Highly Efficient Heterogeneous Catalyst For Hydrogenation Of Terminal Alkynes
  作者:Panwar,Vineeta; Et Al
  参考文献:Industrial & Engineering Chemistry Research 日期:2015 卷标:54(45) 页码:11493-11499]
  
  629-27-6 + 1730-25-2 = 821-95-4
  反应条件:1.1 Catalysts: Cuprous Iodide Solvents: Diethyl Ether; 0 °C
  标题:Allylmagnesium Bromide-Copper(I) Iodide
  作者:Greco,Michael N.
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1]
  
  629-27-6 + 1730-25-2 = 821-95-4
  反应条件:1.1 Reagents: Cuprous Iodide Solvents: Diethyl Ether
  标题:Organocopper Reagents: Substitution,Conjugate Addition,Carbo/metallocupration,And Other Reactions
  作者:Lipshutz,Bruce H.; Et Al
  参考文献:Organic Reactions (Hoboken 日期:1992 卷标:41]
  
  629-27-6 + 1730-25-2 = 821-95-4
  反应条件:1.1 Reagents: Cuprous Iodide Solvents: Diethyl Ether
  标题:Copper(I)-Catalyzed Reactions Of Organolithiums And Grignard Reagents
  作者:Erdik,Ender
  参考文献:Tetrahedron 日期:1984 卷标:40(4) 页码:641-57]
  
  = 821-95-4
  反应条件:1.1 Reagents: Methyllithium,2-Chloro-1,3,2-Benzodioxaphosphole Solvents: Tetrahydrofuran,Water
  标题:New Method For The Synthesis Of Olefins Via β-Hydroxyalkyl Phenyl Sulfides
  作者:Kuwajima,Isao; Et Al
  参考文献:Tetrahedron Letters 日期:1972 卷标:(9) 页码:737-9]
  
  3020-28-8 + 112-31-2 = 821-95-4
  反应条件:1.1 Reagents: 1,1′-Tellurobis[butane] Solvents: Tetrahydrofuran
  标题:Application Of Groups 15 And 16 Organoelement Compounds In Organic Synthesis. Part 84. A Novel Methylenation Method Of Aldehydes Mediated By Dibutyl Telluride
  作者:Li,Saowei; Et Al
  参考文献:Chemische Berichte 日期:1990 卷标:123(6) 页码:1441-2]
  
  17049-49-9 = 821-95-4
  反应条件:1.1 Catalysts: Iron(Iii) Acetylacetonate Solvents: Tetrahydrofuran; 25 °C; 6 H,25 °C1.2 Reagents: Ammonium Chloride Solvents: Water; 25 °C
  标题:Ligandless Iron-Catalyzed Desulfinylative C-C Allylation Reactions Using Grignard Reagents And Alk-2-Enesulfonyl Chlorides
  作者:Volla,Chandra M. R.; Et Al
  参考文献:European Journal Of Organic Chemistry 日期:2009 卷标:(36) 页码:6281-6288]
  
  80262-79-9 = 821-95-4
  反应条件:1.1 Reagents: Disodium Sulfide
  标题:A New Reduction System: Combination Of Sodium Sulfide (Sodium Hydrosulfide) With Phase Transfer Agent In A Two-Phase Mixture. Reductive Debromination Of Vic-Dibromides To Olefins
  作者:Nakayama,Juzo; Et Al
  参考文献:Tetrahedron Letters 日期:1983 卷标:24(29) 页码:3001-4]
  
  80262-79-9 = 821-95-4 [标题:Reaction Conditions
  标题:Synthesis Of Alkenes By Elimination Reactions
  作者:Kostikov,R. R.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:47 页码:771-881

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
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• ➥ 象形图和危险代码
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