专利号:US-2024352216-A1 优先权日:2021-08-20 标 题:Pyrolysis of a polymeric polyurethane compound in order to recover raw materials 发明人:EIDEN STEFANIE; BELLINGHAUSEN RAINER; WOLF AUREL; ALBACH ROLF 权利人:COVESTRO DEUTSCHLAND AG 摘要:The invention relates to a method according to claim 1 for the commercial implementation of a pyrolysis, and to pyrolysis devices for the pyrolysis of pyrolysis stock used in this method. The pyrolysis stock contains a polymeric compound having at least one structural polyurethane unit of the formula (I), wherein Q is a hydrocarbon group with 2 to 8 carbon atoms, preferably 3 to 8 carbon atoms, and n represents a number from 2 to 4, most preferably 2, and -* represents a covalent bond to the polymer backbone. The method and the pyrolysis device according to the invention allow, even with higher compounds of pyrolysis stock an amount of pyrolysis product to be obtained that contains cleavage products which can be reused for the synthesis of polyurethane-containing material.
专利号:US-4243787-A 优先权日:1977-11-23 标 题 :Bulk anionic polymerization process using an alkali metal amide and the salt of the same alkali metal with a hydroxylic compound 发明人:BOILEAU SYLVIE L; CAUBERE PAUL J; NDEBEKA GILBERTE; LECOLIER SERGE L; RAYNAL SERGE F 权利人:POUDRES & EXPLOSIFS STE NALE 摘要:The invention relates to a process for the anionic polymerization and copolymerization of vinyl, dienic and heterocyclic monomers. According to the invention, the process consists in carrying out the reaction in the presence of an initiator consisting of a molecular combination of an alkali metal amide and the salt of the same alkali metal with at least one hydroxylic compound and in the absence of solvent. The initiator can be prepared by intimately mixing its constituents or in the presence of a solvent of low polarity which is subsequently evaporated off, or in situ in the monomer. Application to the synthesis of special or widely used polymers and copolymers.
专利号:US-10336912-B2 优先权日:2014-08-01 标 题 :Methods for producing and using aqueous polyurethane/polyacrylate hybrid dispersions and use of said aqueous polyurethane/polyacrylate hybrid dispersions in coating agents 发明人:JAHNS EKKEHARD; MANGEL TIMO; ROESCH CHRISTINE; ROMANATO PAOLA; BURK YENI; PAKUSCH JOACHIM 权利人:BASF SE 摘要:The present invention provides an aqueous polyurethane (PU)-polyacrylate hybrid dispersion obtainable by free radical polymerization of at least one acrylate polymer (A1) in the presence of at least one polyurethane (P1), a process for preparing these aqueous polyurethane-polyacrylate hybrid dispersions, wherein said process comprises a) preparing an aqueous polyurethane dispersion and b) using the polyurethane dispersion thus prepared as raw material for the further synthesis of a polyacrylate dispersion, and the use of the hybrid dispersion thus obtained as binder in filled coating materials, particularly as a binder for flexible roof coatings.
专利号:WO-2011159219-A1 优先权日:2010-06-16 标题:Solvent-free synthesis of cyclic carbonates 发明人:PYO SANG-HYUN; PERSSON PER; LUNDMARK STEFAN; HATTI-KAUL RAJNI 权利人:PERSTORP AB; DEVENZ AB; PYO SANG-HYUN; PERSSON PER; LUNDMARK STEFAN; HATTI-KAUL RAJNI 摘要:Disclosed is a process for production of a cycloaliphatic carbonate from a diol, triol or polyol and a carbon dioxide source, such as a dialkyl carbonate. Said process is performed in a solvent-free medium using a N-heterocyclic carbene or N-heterocyclic carbene complex as catalyst. Said N-heterocyclic carbene or carbene complex is preferably attached to a lipase. Said process comprises preferably a transesterification step and a thermal disproportionation step and yielded cycloaliphatic carbonate is in preferred embodiments a monocyclic carbonate having a five-membered or a six-membered ring.
专利号:US-2005043560-A1 优先权日:2000-06-19 标题:Novel beta-hydroxyamides 发明人:MANEA MIRCEA; PETERSSON CECILIA 权利人:PERGO EUROP AB 摘要:Disclosed is a novel β-hydroxylamide of general formula n n nwherein R 1 is a linear or branched aliphatic hydrocarbon group optionally comprising one or more ether and/or ester units, such as a group derived from at least one hydroxyfunctional n ncompound, R 2 is a linear or branched aliphatic and/or aromatic hydrocarbon group, such as a group derived from at least one carboxyfunctional compound or at least one anhydride halide or ester of a carboxyfunctional compound, R 3 is N-alkyl or N-cycloalkyl for instance derived from at least one alkanolamine, and wherein m is an integer and at least 1 and n is an integer and at least 2, In a further aspect the present invention refers to a process for synthesis of said β-hydroxyamide. The process comprises the Steps of (i) subjecting a di, tri or polyalcohol to alcoholysis with at least one di, tri or polyalkyl ester of a di, tri or polyfunctional carboxylic acid and (ii) subjecting obtained reaction product to aminolysis with at least one alkanolamine.
专利号:US-2003195373-A1 优先权日:2000-06-19 标 题 :Novel beta-hydroxyamides 发明人:MANEA MIRCEA; PETERSSON CECILIA 摘要:Disclosed is a noble β-hydroxyamide of general formula wherein R 1 is alkyl, alkoxyalkyl or hydroxyalkoxyalkyl derived from at least one hydroxyfunctional compound, R 2 is alkyl, aryl, alkylaryl or arylalkyl derived from at least one carboxyfunctional compound or at least one anhydride, halide or ester of at least one carboxyfunctional compound, R 3 is N-alkyl or N-cycloalkyl derived from at least one alkanolamine and wherein m and n are independent integers and at least 1. In a further aspect the present refers to a process for synthesis of said β-hydroxyamide. The process comprises the Steps of (i) subjecting a di, tri or polyalcohol to alcoholysis with at least one di, tri or polyalkyl ester of a di, tri or polyfunctional carboxylic acid and (ii) subjecting obtained reaction product to aminolysis with at least one alkanolamine.