CAS: 504-20-1; 2,6-Dimethyl-2,5-Heptadien-4-One

该化合物是一种混凝土的狄甲酮化合物,其特点是α-β-不饱和的克酮结构,分子由于其电子衰竭的双环联结,表现出显著的反活性,使其成为有机合成中有价值的中间体,特别是在Diels-Alder反应和Michael添加物中,其结构特征,包括位于2和6个位置的甲基替代体,影响性能和电子特性,加强循环添加过程的选择性和核感性激素攻击过程,该化合物还因其不饱和的基骨骨,有助于其作为芳香化学品前体的潜力,因此对香味和口味应用感兴趣,其稳定性和定义明确的再活性特征使其适合研究和工业应用.

结构式图片

相似化合物

1604-28-0 625-33-2 3102-33-8

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

6-hydroxy-2,6-dimethyl-hept-2-en-4-one 3,5-dibromo-2,6-dimethylhepta-2,5-dien-4-one 2,6-dihydroxy-2,6-dimethyl-heptan-4-one oxalic acid diisobutyl ketone 1,1,2,2-tetraphenylethylene 1,1,4,4-tetraphenyl-butane dimedone

合成工艺路线路线简述

  • 合成目标产物 2,6-Dimethyl-2,5-Heptadien-4-One 主要起始原料 2,2,6,6-Tetramethyl-1-Nitroso-4-Piperidone
  • (文献来源)合成步骤主要原料 2,2,6,6-Tetramethyl-1-Nitroso-4-Piperidone
N-Benzyl-2,2,6,6-Tetramethyl-Piperidin-4-One置于c20H29Clo2P2Pt体系中,用 水,甲苯 作为反应溶剂,化学反应 5.0H,以90%的收率获得产物2,6-二甲基-2,5-庚二烯-4-酮
参考文献:铂-(亚膦酸-亚膦酸)配合物作为哌啶醇氧化裂解的双能催化剂:伯胺的入门
标题:铂-(亚膦酸-亚膦酸)配合物作为哌啶醇氧化裂解的双能催化剂:伯胺的入门
摘要:根据氢转移诱导方法,铂-(亚膦基-亚膦酸)络合物催化受阻哌啶醇的氧化断裂.这种催化剂在一锅两步法中连续充当氢载体和软路易斯酸.该方法可用于通过简单的酸碱萃取来合成多种纯净形式的伯胺,而无需进一步纯化.
DOI:10.1039/c9Ra08709E

海关参考信息

专利信息


专利号:US-6646127-B2
优先权日:2000-10-03
标 题:Process for the synthesis of 2,2,6,6-tetramethyl-4-oxopiperidine
发明人:MALZ JR RUSSELL E; SON YOUNG-CHAN; SUIB STEVEN L
权利人:UNIROYAL CHEM CO INC; UNIV CONNECTICUT
摘要:A process for the synthesis of 2,2,6,6-tetramethyl-4-oxopiperidine is disclosed wherein the process comprises reacting in a liquid phase reaction mixture:A) at least one acetone compound, andB) at least one ammonia donor compound,in the presence of a catalytically effective amount of a crystalline aluminosilicate containing calcium.

专利号:US-5874632-A
优先权日:1996-05-15
标 题 :Method of producing ketoisophorone
发明人:HAHN RAINER; GORA ULRICH; HUTHMACHER KLAUS; HUEBNER FRANK; KRILL STEFFEN
权利人:DEGUSSA
摘要:An improved method of producing 3,5,5-trimethylcyclohex-2-ene-1,4-dione (KIP) by the oxidation of 3,5,5-trimethylcyclohex-3-ene-1-one ( beta -IP) in the presence of managansalene-like catalysts and certain catalytic additives. Byproducts:uct in the synthesis of trimethylhydroquinone, an initial substance in the synthesis of vitamin E. Furthermore, KIP is an initial compound for the synthesis of various carotinoids.

专利号:US-2014296354-A1
优先权日:2013-04-01
标题 :Synthesis of peptoid-based small molecular gelators from multiple component reactions
发明人:WANG GUIJUN; MANGUNURU HARI P R
权利人:WANG GUIJUN; MANGUNURU HARI P R; OLD DOMINION UNIV RES FOUND
摘要:Described herein are the one-pot synthesis and characterization of a library of low molecular weight peptoid compounds that are able to form gels at room temperature. The compounds are synthesized from biologically-based starting materials, are biocompatible, and are resistant to degradation by proteases and peptidases. The compounds and gels synthesized therefrom can be used in such applications as tissue engineering, drug delivery, separation of biomolecules, and stimulus-responsive advanced materials

专利号:US-2010055750-A1
优先权日:2008-09-03
标 题:Polyester synthesis
发明人:WOSNICK JORDAN H
权利人:XEROX CORP
摘要:The present disclosure provides for enzymatic polymerization to produce polyester resins suitable for use in manufacturing toners. In embodiments, crystalline copolymers, which are polyesters, may be synthesized from lactones, cyclic anhydrides, cyclic carbonates, and combinations thereof. These crystalline copolymers, in turn, may be utilized in the synthesis of toner particles.

专利号:US-2005209355-A1
优先权日:2004-03-22
标 题:[Novel Reactions and the Products of Such Reactions]
发明人:ROITMAN LIPA L
权利人:ROITMAN LIPA L
摘要:A process for the synthesis of novel compounds is described comprising reacting tetrachloroethylene with substances containing active methylene group in the presence of free radical initiators. Also, a process for grafting tetrachloroethylene is described comprising reacting these compounds with polymers containing active methylene group in the presence of free radical initiators. Furthermore, a method of conducting such reactions to high conversion is described, comprising conducting the reactions in the reflux condensate. The present invention provides a novel and high yield route for heretofore unobtainable materials.

专利号:US-9458021-B2
优先权日:2013-07-27
标 题 :Sol-gel method for synthesis of nano-porous carbon
发明人:MITRA SHANTANU
权利人:FARAD POWER INC
摘要:The present patent application discloses a novel sol-gel process to synthesize a nano-porous solid carbon material—suitable for use in electrodes in energy storage applications—from a combination of liquid reagents that undergo a polymerization reaction to form a matrix.
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合成参考文献


摘要:Muñiz, K., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 10.
摘要:Archiv fuer Experimentelle Pathologie und Pharmakologie., 56(346), 1906
参考文献:10.1159/000138938
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参考文献:10.1007/bf02307174
摘要:Bien E, Vick K, Skorka G. Effects of exogenous factors on the cerebral glutathione in rodents. Arch Toxicol. 1992;66(4):279–85. doi: 10.1007/bf02307174.
摘要:Summer KH, Klein D, Lichtmannegger J, Wolff T. 2-Chloroacetophenone is an effective glutathione depletor in isolated rat hepatocytes. Arch Toxicol. 1996;71(1-2):127–9.
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