CAS: 111-27-3; 1-Hexanol

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6789-88-4 3839-35-8 95348-44-0

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CAS号66-25-1 正己醛 | CAS号142-62-1 正己酸 | CAS号106-70-7 己酸甲酯 | CAS号502-44-3 ε-己内酯 | CAS号6378-65-0 己酸己酯 | CAS号18107-40-9 triethyl(hexoxy... | CAS号847-83-6 (4-甲氧基苯基)二苯基甲醇 | CAS号91-01-0 二苯甲醇 | CAS号3295-94-1 Hexane,1-(2-pro... | CAS号928-95-0 反式-2-己烯-1-醇 | CAS号105769-77-5 dihexyl 9-ethyl... | CAS号111711-89-8 1-(benzenesulfo... | CAS号1070-59-3 hexyl N-butylca... | CAS号1087-26-9 Hexyl gallate | CAS号1119-06-8 庚酸己酯 | CAS号5421-17-0 苯乙酸己醇酯 | CAS号111-25-1 1-溴代正己烷 | CAS号3377-86-4 2-溴己烷 | CAS号33228-45-4 4-己基苯胺 | CAS号3839-35-8 对甲苯磺酸正己酯

2-甲基四氢吡喃置于氢气,Ytterbium(III) Triflate体系中,185.0 °C,4.14 Mpa 条件下,反应 18.0H,以90%的收率获得正己醇
参考文献:Etheric C-o Bond Hydrogenolysis Using A Tandem Lanthanide Triflateported Palladium Nanoparticle Catalyst System
标题:Etheric C-o Bond Hydrogenolysis Using A Tandem Lanthanide Triflateported Palladium Nanoparticle Catalyst System
摘要:Selective Hydrogenolysis Of Cyclic And Linear Ether C-O Bonds Is Accomplished By A Tandem Catalytic System Consisting Of Lanthanide Triflates And Sinter-Resistant Supported Palladium Nanoparticles In An Ionic Liquid. The Lanthanide Triflates Catalyze Endothermic Dehydroalkoxylation,While The Palladium Nanoparticles Hydrogenate The Resulting Intermediate Alkenols To Afford Saturated Alkanols With High Overall Selectivity. The Catalytic C-O Hydrogenolysis Is Shown To Have Significant Scope,And The C-O Bond Cleavage Is Turnover-Limiting.
Doi:10.1021/ja306309U

专利信息

专利号:US-9388131-B2
优先权日:2011-04-27
标题:Automated synthesis of small molecules using chiral, non-racemic boronates
发明人：BURKE MARTIN D; LI JUNQI; GILLIS ERIC P
权利人:UNIV ILLINOIS
摘要:Provided are methods for making and using chiral, non-racemic protected organoboronic acids, including pinene-derived iminodiacetic acid (PIDA) boronates, to direct and enable stereoselective synthesis of organic molecules. Also provided are methods for purifying PIDA boronates from solution. Also provided are methods for deprotection of boronic acids from their PIDA ligands. The purification and deprotection methods may be used in conjunction with methods for coupling or otherwise reacting boronic acids. Iterative cycles of deprotection, coupling, and purification can be performed to synthesize chiral, non-racemic compounds. The methods are suitable for use in an automated chemical synthesis process. Also provided is an automated small molecule synthesizer apparatus for performing automated stereoselective synthesis of chiral, non-racemic small molecules using iterative cycles of deprotection, coupling, and purification.

专利号:US-2021107859-A1
优先权日:2018-04-06
标题 :A process for the synthesis of carbon labeled organic compounds
发明人：AUDISIO DAVIDE; CANTAT THIBAULT; DESTRO GIANLUCA
权利人:COMMISSARIAT ENERGIE ATOMIQUE
摘要:A process for the synthesis of a carbon labeled organic compound containing a carbon labeled carboxyl group is described. A method of using carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; a process for manufacturing labeled pharmaceuticals and agrochemicals comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; and a process for producing tracers comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure are also described.

专利号:US-9126995-B2
优先权日:2011-11-08
标题:Method for catalytic asymmetric synthesis of optically active isoxazoline compound and optically active isoxazoline compound
发明人：TOYAMA KEN-ICHI; MORIYAMA YUJI; MATOBA KAZUTAKA; YAOSAKA MANABU; IKEDA EITATSU
权利人:NISSAN CHEMICAL IND LTD
摘要:There is provided a method for catalytic asymmetric synthesis of optically active isoxazoline compound and an optically active isoxazoline compound. A method for catalytic asymmetric synthesis of optically active isoxazoline compound of a formula (6) including reacting an α,β-unsaturated carbonyl compound of a formula (1) and a hydroxylamine in a solvent in the presence of a base by adding a chiral phase transfer catalyst. An optically active isoxazoline compound of a formula (13) that can be synthesized by the method.

专利号:US-8669356-B2
优先权日:2009-10-21
标 题 :Linker and support for solid phase synthesis of nucleic acid
发明人：HAYAKAWA YOSHIHIRO; TSUKAMOTO MASAKI; MORI KENJIRO; MINOMI KENJIRO; MAETA ERI; KONISHI TATSUYA
权利人:HAYAKAWA YOSHIHIRO; TSUKAMOTO MASAKI; MORI KENJIRO; MINOMI KENJIRO; MAETA ERI; KONISHI TATSUYA; NITTO DENKO CORP; UNIV NAGOYA NAT UNIV CORP
摘要:The invention provides a universal linker capable of synthesizing nucleic acid having a phosphate group at the 3′ terminal, a universal support carrying the linker, and a synthesis method of nucleic acid using the universal support. The linker for solid phase synthesis of nucleic acid contains a compound represented by at least one of the following formulae n nwherein each symbol is as defined in the specification.

专利号:US-10253153-B2
优先权日:2015-04-24
标题 :Linker and support for solid phase synthesis of nucleic acid, and production method of nucleic acid using said support
发明人：MAETA ERI; MORI KENJIRO; HORIE SHOHEI; ITO TAKAHIKO; SAITO SHOICHIRO; NAGAO RYUHEI
权利人:NITTO DENKO CORP
摘要:The present invention provides a linker for solid phase synthesis of nucleic acid, which consists of a compound represented by the formula (I) or the formula (II), a support for solid phase synthesis of nucleic acid, which has a structure represented by the formula (III), and a production method of a nucleic acid, which uses the support: n nwherein each symbol is as defined in the SPECIFICATION.

专利号:US-12209023-B2
优先权日:2017-01-25
标题:Low temperature, high yield synthesis of hydrogen terminated highly porous amorphous silicon, and nanomaterials and composites from Zintl phases
发明人：WAGNER MICHAEL J; BANEK NATHAN A
权利人:UNIV GEORGE WASHINGTON
摘要:The present disclosure relates to an improved process for the synthesis of hydrogen terminated silicon from Zintl phases. The hydrogen terminated silicon is useful, for example, as explosives, chemical and biochemical sensors, optoelectronic materials and Li-ion battery anode ion storage materials. The present disclosure also relates to an improved process for the synthesis of nanomaterials and composites from Zintl phases. The nanomaterials and composites are useful, for example, as ion storage materials.