专利号:US-8053548-B2 优先权日:2008-09-05 标 题 :Hydrophilic surface modification of polydimethylsiloxane 发明人:DHRUV HARSHIL; BRITT DAVID 权利人:UNIV UTAH STATE 摘要:A method for the preparation of hydrophilic elastomers involves the synthesis of polydimethylsiloxane with tunable hydrophilic surface properties. An elastomeric monolith with desired hydrophilic properties is produced by combining a polyethylene oxide polymeric surfactant additive with a PDMS base and curing agent during polymerization. The surfactant chain segment lengths are varied to control the hydrophobic/hydrophilic balance.
专利号:WO-2024242750-A1 优先权日:2023-05-23 标 题 :Silicone - (meth)acrylate - polyether copolymer and synthesis method 发明人:ZHANG FANG; CARTER MATTHEW; BOELTER SCOTT; MECCA JODI; LIU NANGUO; ZHOU WEIJUN; WANG HAI 权利人:DOW GLOBAL TECHNOLOGIES LLC; DOW SILICONES CORP; ROHM & HAAS 摘要:A silicone - (meth)acrylate - polyether copolymer includes a linear siloxane backbone with pendant (meth)acrylate - polyether moieties. The siloxane backbone is made up of a silicone moiety having a silicon bonded mercapto-alkyl linker (wherein the alkyl group in the linker is bonded to a silicon atom in the silicone moiety). The pendant (meth)acrylate - polyether moiety is covalently bonded to a sulfur atom in the mercapto-alkyl linker. The pendant (meth)acrylate - polyether moiety includes a (meth)acrylate - poly(alkylene glycol) unit. The silicone - (meth)acrylate - polyether copolymer is useful as a surfactant, formulation aid, and/or dispersant. The silicone - (meth)acrylate - polyether copolymer may be useful as a defoamer for coatings, oil and gas applications and/or pulp and paper applications. Furthermore, the silicone - (meth)acrylate - polyether copolymer may be useful as an additive for adjusting adhesion and/or release force in paper coatings such as pressure sensitive adhesive and/or release coating compositions.
专利号:PL-211901-B1 优先权日:2008-01-09 标题 :A new catalytic method for the synthesis of asymmetrical siloxanes
专利号:US-12331072-B2 优先权日:2018-11-30 标 题 :Deprotection method and resin removal method in solid-phase reaction for peptide compound or amide compound, and method for producing peptide compound 发明人:IWASAKI KOTARO; KOMIYA SHIO 权利人:CHUGAI PHARMACEUTICAL CO LTD 摘要:The present inventors found that peptide compounds/amide compounds in which the protecting groups of interest are removed and/or which are removed from resins for solid-phase synthesis can be produced without main chain damage by contacting starting peptide compounds/amide compounds with silylating agents.
参考文献:10.1007/s11356-015-5574-4 摘要:Ratola N, Ramos S, Homem V, Silva JA, Jiménez-Guerrero P, Amigo JM, Santos L, Alves A. Using air, soil and vegetation to assess the environmental behaviour of siloxanes. Environmental Science and Pollution Research. 2015 Oct 21;23(4):3273–84. doi: 10.1007/s11356-015-5574-4.