CAS: 120-55-8; Oxybis(Ethane-2,1-Diyl) Dibenzoate

该化合物是一种主要用于聚合物应用的高性能催化剂和溶剂酯,与聚氯乙烯,纤维素树脂和合成橡胶非常相容,提高了灵活性和可加工性.二乙基二苯甲酸酯(DEGDB)具有低挥发性,高热稳定性和抗迁移性,适合高温处理.二乙基二苯甲酸乙酯(DEGDB)的粘性低和快速聚变特性提高了聚变剂制剂的效率.此外,DEGDB还起到二级催化剂的作用,经常与主要催化剂混合,以优化成本-性能比率.由于粘合剂的溶能和耐性,该化合物还被用于粘合剂和涂层中.其低味和无毒性特征进一步扩大了其工业适用性.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报CoRAP评估清单REACH预注册

上下游产品

benzoyl chloride diethylene glycol sodium benzoate 3-oxa-1,5-dichloropentaneacid sodium salt of benzohydroxamic acid

合成工艺路线路线简述

  • 合成目标产物 Diethylene Glycol Dibenzoate 主要起始原料 Benzoic Acid And Diethylene Glycol
  • (文献来源)合成步骤主要原料 Benzoic Acid 和 Diethylene Glycol
2,3,11,12-Tetraphenyl-2,3,11,12-Didehydro<18>Krone-6置于氧气,亚甲兰体系中,用 二氯甲烷 用作溶剂,化学反应 10.0H,反应生成二甘醇二苯甲酸酯
参考文献:Dioxetano-Crown Ethers. Stabilization Through Complexation With Metal Ions
标题:Dioxetano-Crown Ethers. Stabilization Through Complexation With Metal Ions
摘要:第一个双恶氧环醚 3 和 4 的成员是在亚甲基蓝敏化的光氧化反应中制备的,这些反应涉及 9 和 18 成员的苯乙烯环醚 1 和 2,并且获得了 3 和 4 的热解活化参数.双恶氧-18-ה冠-6 4 的热分解速率在存在碱金属盐的情况下根据反离子的亲核性而减慢或加快.
Doi:10.1246/cl.1983.431

海关参考信息

专利信息


专利号:WO-2015179088-A1
优先权日:2014-05-22
标题 :Conversion of 5-(halomethyl)-2-furaldehyde into polyesters of 5-methyl-2furoic acid
发明人:CAHANA AVIAD; MARTIN TIMOTHY J; GEORGE TIMOTHY R
权利人:XF TECHNOLOGIES INC
摘要:The present invention provides methods of synthesis of di-, tri-, and poly- ester derivatives of 5- methyl-2-furoic acid; di-, tri-, and poly- amide derivatives of 5-methyl-2-furoic acid; and di-, tri-, and poly- thioester derivatives of 5-methyl-2-furoic acid from 5-(halomethyl)-2-furaldehydes. These molecules are useful as plasticizers, solvents, coalescers, an ingredient in plastisol compositions, diluents, an ingredient in adhesive compositions, compatibilizer or compounding agent, or lubricant, as well as polymer compositions containing such ester compositions.

专利号:US-5194469-A
优先权日:1991-02-28
标题:Latex for coatings having improved flexibility
发明人:SRAIL RICHARD E; BURROWAY GARY L
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention relates to the synthesis of a latex which can be formulated into coatings having improved flexibility and good water resistance. Coatings of this type are particularly useful in roof coating applications because they offer excellent flexibility, excellent ultra-violet light resistance, and good water resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: n (1) free radical aqueous emulsion polymerizing, at a pH of less than about 3.5, a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 30 to about 70 weight percent vinyl aromatic monomers, (b) from about 25 to about 65 weight percent of at least one alkyl acrylate monomer, (c) from about 1 to about 5 weight percent of acrylic acid, and (d) about 0.4 to about 3 weight percent methacrylic acid, in the presence of about 0.2 to 0.4 phm at least one sulfonate surfactant and in the presence of about 4 to 8 phm of at least one nonionic surface active agent having a hydrophile-lipophile balance number which is within the range of about 12 to about 20 to produce a latex; and n (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to about 10.5 to produce the neutralized latex.

专利号:US-5122566-A
优先权日:1989-10-06
标 题 :Latex for coatings having reduced blushing characteristics
发明人:BURROWAY GARY L; GESENHUES ALBERT M; BRADEN JENNIFER T
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention relates to the synthesis of a latex which can be formulated into coatings having improved water resistance for both moisture vapor transmission and water spotting. Coatings which are formulated with the latex of this invention are particularly useful for coating metal substrates because they provide excellent rust and corrosion resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: (1) free radical aqueous emulsion polymerizing at a pH of less than about 3.5 a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 45 to about 85 weight percent vinyl aromatic monomers, (b) from about 15 to about 50 weight percent of at least one alkyl acrylate monomer, and (c) from about 1 to about 6 weight percent of at least one unsaturated carbonyl compound; in the presence of about 0.5 to 4.0 phm at least one phosphate ester surfactant and in the presence of about 0.5 to 4.0 phm of at least one water insoluble nonionic surface active agent to produce a latex; and (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to a bout 10.5 to produce the neutralized latex.

专利号:US-4968741-A
优先权日:1989-10-06
标题:Latex for coatings having reduced blushing characteristics
发明人:BURROWAY GARY L; GESENHUES ALBERT M; BRADEN JENNIFER T
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention relates to the synthesis of a latex which can be formulated into coatings having improved water resistance for both moisture vapor transmission and water spotting. Coatings which are formulated with the latex of this invention are particularly useful for coating metal substrates because they provide excellent rust and corrosion resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: n (1) free radical aqueous emulsion polymerizing at a pH of less than about 3.5 a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 45 to about 85 weight percent vinyl aromatic monomers, (b) from about 15 to about 50 weight percent of at least one alkyl acrylate monomer, and (c) from about 1 to about 6 weight percent of at least one unsaturated carbonyl compound; in the presence of about 0.5 to 4.0 phm at least one phosphate ester surfactant and in the presence of about 0.5 to 4.0 phm of at least one water insoluble nonionic surface active agent to produce a latex; and n (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to about 10.5 to produce the neutralized latex.

专利号:CA-2640585-A1
优先权日:2003-02-05
标题 :Synthesis of 2-butyl-3-(2'-(1-trityl-1h-tetrazol-5-yl)biphenyl-4-yl)-1,3-diazaspirol{4,4}-non-ene-4-one

专利号:US-2010113664-A1
优先权日:2008-06-11
标 题 :Asymmetric Cyclic Diester Compounds
发明人:BRADSHAW JOHN D; SCHAEFER GEORGE F; BALDWIN LARRY J; RALEIGH JR RONALD J; HOLLO BRENDA
权利人:FERRO CORP
摘要:Compounds useful as plasticizers and the synthesis thereof are disclosed. In general, the invention includes mixed alkyl/aryl asymmetric cyclic diesters where the aryl and alkyl ester moieties are attached to a cyclic structure at vicinal carbons. The invention also includes synthetic processes of making such compounds. Blends of these asymmetric cyclic diesters with other plasticizers are demonstrated to be of use in plasticizing polymers.
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参考标题: Conversion Of 5-(Halomethyl)-2-Furaldehyde Into Polyesters Of 5-Methyl-2Furoic Acid Conversion De 5- (Halométhyl) -2-Furaldéhyde En Polyesters D'Acide 5-Méthyl-2-Furoïque
摘要:The Present Invention Provides Methods Of Synthesis Of Di-, Tri-, And Poly- Ester Derivatives Of 5- Methyl-2-Furoic Acid; Di-, Tri-, And Poly- Amide Derivatives Of 5-Methyl-2-Furoic Acid; And Di-, Tri-, And Poly- Thioester Derivatives Of 5-Methyl-2-Furoic Acid From 5-(Halomethyl)-2-Furaldehydes. These Molecules Are Useful As Plasticizers, Solvents, Coalescers, An Ingredient In Plastisol Compositions, Diluents, An Ingredient In Adhesive Compositions, Compatibilizer Or Compounding Agent, Or Lubricant, As Well As Polymer Compositions Containing Such Ester Compositions.

合成参考文献


摘要:Gerhartz, W. (exec ed.). Ullmann's Encyclopedia of Industrial Chemistry. 5th ed.Vol A1: Deerfield Beach, FL: VCH Publishers, 1985 to Present., p. VA3 560
摘要:Meylan WM et al; Environ Sci Technol 28: 459-65 (1992)
摘要:NIOSH; National Occupational Exposure Survey (NOES) (1983)
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118
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