专利号:US-2016214860-A1 优先权日:2013-09-19 标题:Method of synthesis of unsolvated mixed cation borohydrides 发明人:JARON TOMASZ; WEGNER WOJCIECH; GROCHALA WOJCIECH 权利人:JAROÑ Tomasz; WEGNER WOJCIECH; GROCHALA WOJCIECH 摘要:The present invention relates to a novel method of synthesis of unsolvated mixed cation borohydrides of a general formula M x M′ y (BH 4 ) z , where M and M′ stand for metal cations, x, y, and z are stoichiometric coefficients. The method of synthesis according to the present invention is characterised in that the precursors having a general formula M[A n ] u and [Cat] v M′(BH 4 ) w are used for the synthesis, where [An] stands for a weakly coordinating anion; [Cat] stands for weakly coordinating cation; u, v, and w are the stoichiometric coefficients; and the synthesis is carried out under an inert to the reagents atmosphere—according to the general reaction equation: x M[An] u +y [Cat] v M′(BH 4 ) w →M x M′ y (BH 4 ) z +xu [Cat][An] where z=yw, xu=yv; M x M′ y (BH 4 ) z is the product of the reaction.
专利号:US-7423171-B2 优先权日:2006-06-20 标题 :One-step catalytic process for the synthesis of isocyanates 发明人:SERRANO FERNANDEZ FRANCISCO LU; ALMENA MUNOZ BEATRIZ; PADILLA POLO ANA; OREJON ALVAREZ ARANCHA; CLAVER CABRERO CARMEN; CASTILLON MIRANDA SERGIO; SALAGRE CARNERO PILAR; AGHMIZ ALI 权利人:REPSOL YPF SA 摘要:A one-pot process for the synthesis of isocyanates, polyisocyanates or mixtures thereof which includes the steps of:n i. preparing a mixture comprising an amine, an alcohol, an oxygen-containing gas, carbon monoxide, a metal complex catalyst selected from the group consisting of macrocyclic complex catalysts and cobalt Shiff base catalysts; and a solvent selected from the group consisting of aliphatic or aromatic halocarbons, perhalogenated alcohols, halogenated ethers, halogenated ketones, perfluorinated hydrocarbons, polymers of chlorotrifluoroethylene having the formula —(CF 2 —CFCl) n wherein n is between 2 and 10, and mixtures thereof; ii. subjecting the resulting mixture to a first heating under pressure; iii. cooling and depressurizing the mixture resulting from the previous step; and iv. subjecting the mixture of the previous step to a second heating to separate out the isocyanate product from the mixture.
专利号:US-7718578-B2 优先权日:2003-03-31 标 题 :Method of synthesis and testing of combinatorial libraries using microcapsules 发明人:GRIFFITHS ANDREW DAVID; ABELL CHRIS; HOLLFELDER FLORIAN; MASTROBATTISTA ENRICO 权利人:MEDICAL RES COUNCIL 摘要:The invention describes a method for the synthesis of compounds comprising the steps of: (a) compartmentalizing two or more sets of primary compounds into microcapsules; such that a proportion of the microcapsules contains two or more compounds; and (b) forming secondary compounds in the microcapsules by chemical reactions between primary compounds from different sets. The invention further allows for the identification of compounds which bind to a target component of a biochemical system or modulate the activity of the target, and which is co-compartmentalized into the microcapsules.
专利号:US-2021369846-A1 优先权日:2018-10-26 标 题 :New Ammonium Salts Of Fluorinated Organic Acids, Method Of Their Synthesis and Application 发明人:STEFANEK AGATA; CIACH TOMASZ; LECZYCKAWILK KATARZYNA; CZARNOCKA-SNIADALA SYLWIA; GRAFSTEIN JOANNA; DRESLER MAGDALENA; NOWAK ALEKSANDRA; WGLINKSKI JAKUB 权利人:NANOSANGUIS 摘要:The exemplary arrangements relate to ammonium salts of partially fluorinated organic acids. The exemplary arrangements also relate to methods of synthesis of the ammonium salts of partially fluorinated organic acids. The exemplary arrangements also relate to methods of use of the ammonium salts of partially fluorinated organic acids to produce stabilizing emulsions of the oil-in-water and/or water-in-oil type. The exemplary arrangements also relate to methods of use and applications of the ammonium salts of partially fluorinated organic acids, for example use as stabilizing agents in blood substitute preparations.
专利号:US-11008273-B2 优先权日:2019-02-15 标题 :Process for the manufacture of fluorinated benzenes and fluorinated benzophenones, and derivatives thereof 发明人:ZHOU CHANGYUE; DU HONGJUN; WU WENTING 权利人:FUJIAN YONGJING TECH CO LTD 摘要:The invention relates to a new process for the manufacture or synthesis, respectively, of fluorinated benzenes and fluorinated benzophenones, and derivatives thereof, in particular of fluorobenzenes and derivatives thereof. The present invention particularly pertains to a novel environmentally friendly process for the synthesis of fluorinated benzenes and benzophenones as raw materials for the manufacture of polyaryletherketones (PAEKs).
专利号:US-2018171086-A1 优先权日:2016-12-16 标题 :Large area monolayer of perfluoro polymers 发明人:SUN HAORAN 权利人:SOUTH DAKOTA BOARD OF REGENTS 摘要:Synthesis and growth of large area free-standing ultra-thin two-dimensional (2D) polymeric films including 2D covalent organic frameworks (COF) are achieved by utilizing fluorocarbon-soluble fluorinated aldehyde derivatives and hydrocarbon-soluble amine derivatives at a liquid-liquid interface of respective fluorocarbon and hydrocarbon solvents.
1: Tamimi F, Comeau P, Le Nihouannen D, Zhang YL, Bassett DC, Khalili S, Gbureck U, Tran SD, Komarova S, Barralet JE. Perfluorodecalin and bone regeneration. Eur Cell Mater. 2013 Jan 2;25:22-36. doi: 10.22203/ecm.v025a02.
合成参考文献
摘要:Sellars, J. D., Science of Synthesis Knowledge Updates, (2014) 1, 403. 摘要:Bulletin of Experimental Biology and Medicine, 90(1513), 1980 摘要:Personal Communication from Dr. G.F. May, BNFL Fluorochemicals Ltd., Bldg. 619, Springfields, Salwick, Preston, Lancashire PR4 OXJ. UK, Aug. 25, 1995., 25AUG1995 摘要:Problemy Gematologii i Perelivaniia Krovi. Problems of Hematology and Blood Transfusion., 27(10)(8), 1982 摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118