2-(3-Methyl-But-2-Enyloxy)-Benzoic Acid 3-Methyl-But-2-Enyl Ester置于sodium Tetrahydroborate,氯化锆(Iv)体系中,用 二氯甲烷 作为反应溶剂,化学反应 1.5H,以96%的收率获得产物2-羟基苯甲酸-3-甲基-2-丁烯酯
参考文献:Highly Efficient And Chemoselective Cleavage Of Prenyl Ethers Using Zrcl4/nabh4
标题:Highly Efficient And Chemoselective Cleavage Of Prenyl Ethers Using Zrcl4/nabh4
摘要:An Efficient And Chemoselective Deprotection Of Prenyl Ethers Of Phenols And Alcohols With Zrcl4/nabh4 In Dcm Was Achieved In High Yields. The Selectivity Of Prenyl Ether Deprotection Is Well Demonstrated By Carrying Out The Reaction In The Presence Of Several Other Ether And Ester Functionalities. (C) 2003 Elsevier Science Ltd. All Rights Reserved.
DOI:10.1016/s0040-4039(03)00330-7