锆置于fluoroplast-4体系中,用 Neat (No Solvent) 作为反应溶剂,化学反应生成 氟化锆 参考文献:Batsanov,S. S.; Kopaneva,L. I.; Lazareva,E. V.,Russian Journal Of Inorganic Chemistry,1983,Vol. 28,P. 603-604 标题:Batsanov,S. S.; Kopaneva,L. I.; Lazareva,E. V.,Russian Journal Of Inorganic Chemistry,1983,Vol. 28,P. 603-604
专利信息
专利号:US-7098354-B2 优先权日:2002-10-25 标 题:Racemoselective synthesis of rac-diorganosilylbis(2-methylbenzo[e]indeyl)zirconium compounds 发明人:DAMRAU HANS-ROBERT; MUELLER PATRIK; GARCIA VALERIE; SIDOT CHRISTIAN; TELLIER CHRISTIAN; LELONG JEAN-FRANCOIS 权利人:BASELL POLYOLEFINE GMBH 摘要:The present invention relates to a specific process for the diastereoselective synthesis of rac-diorganosilylbis(2-methylbenzo[e]indenyl)zirconium compounds of the formula I, n nby reacting the silyl-bridged bisindenyl ligand with a dihalozirconium bis(3,5-di-tert-butylphenoxide)-base adduct to form the diorganosilylbis(2-methylbenzo[e]indenyl)zirconium bis(3,5-di-tert-butylphenoxide) and subsequently replacing the phenoxide groups by X using suitable replacement reagents to give the compound of the formula I; where the substituents X can be identical or different and are each F, Cl, Br, I or linear, cyclic or branched C 1-10 -alkyl; and the substituents R can be identical or different and are each linear, cyclic or branched C 1-10 -alkyl or C 6-10 -aryl; and also to the use of these compounds as catalysts.
专利号:US-12163079-B2 优先权日:2019-08-12 标 题 :Synthesis of blue-emitting ZnSe1-xTex alloy nanocrystals with low full width at half-maximum 发明人:NEWMEYER BENJAMIN; IPPEN CHRISTIAN; MA RUIQING 权利人:SHOEI CHEMICAL IND CO 摘要:The invention pertains to the field of nanotechnology. The invention provides highly luminescent nanostructures, particularly highly luminescent nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers. The nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers display a low full width at half-maximum and a high quantum yield. The invention also provides methods of producing the nanostructures.
专利号:US-6657068-B2 优先权日:2002-03-22 标题:Liquid phase oxidation of halogenated ortho-xylenes 发明人:COLBORN ROBERT EDGAR; HALL DAVID BRUCE; KOCH PETER; OECKEL GERALD 权利人:GEN ELECTRIC 摘要:A method for the manufacture of halophthalic acid by liquid phase oxidation of halo-ortho-xylene is disclosed. The halophthalic acid may be dehydrated to form halophthalic anhydride which is useful in the synthesis of polyetherimide.
专利号:US-6649773-B2 优先权日:2002-03-22 标题:Method for the manufacture of halophthalic acids and anhydrides 发明人:COLBORN ROBERT EDGAR; HALL DAVID BRUCE; KOCH PETER; OECKEL GERALD 权利人:GEN ELECTRIC 摘要:A method for the manufacture of halophthalic acid by liquid phase oxidation of halo-ortho-xylene is disclosed. The halophthalic acid may be dehydrated to form halophthalic anhydride which is useful in the synthesis of polyetherimide.
专利号:US-6657067-B2 优先权日:2002-03-22 标题 :Method for the manufacture of chlorophthalic anhydride 发明人:COLBORN ROBERT EDGAR; HALL DAVID BRUCE; KOCH PETER; OECKEL GERALD 权利人:GEN ELECTRIC 摘要:A method for the manufacture of chlorophthalic acid by liquid phase oxidation of chloro-ortho-xylene is disclosed. The chlorophthalic acid may be dehydrated to form chlorophthalic anhydride which is useful in the synthesis of polyetherimide.
专利号:US-2017312313-A1 优先权日:2016-04-28 标 题 :Synthesis of ultra-small ceria-zirconia nanoparticles and ceria-zirconia nano complex and its application as a therapeutic agent for sepsis