专利号:US-7880026-B2 优先权日:2006-04-14 标 题 :MOF synthesis method 发明人:NI ZHENG; MASEL RICHARD I 权利人:UNIV ILLINOIS 摘要:A rapid, simple and versatile metal organic framework molecule (MOF) synthesis method particularly adapted to make non-linear MOFs includes heating MOF precursors, such as a metal or metal oxide and an organic ligand, in a microwave oven for a period sufficient to achieve crystallization. Microwave-assisted MOF synthesis yields high quality MOF crystals in a reaction time ranging from about 5 seconds to about 2.5 minutes, compared to hours and days required in conventional solvothermal and hydrothermal methods. In addition, microwave assisted methods provide MOF materials with uniform crystal size and well-defined shape. Further, microwave synthesis of MOFs allows the size and shape of MOF crystals to be tailored for use in a wide range applications by manipulating reaction conditions. Secondary growth processes may also be employed to grow larger crystals using seeds obtained from microwave-assisted synthesis methods.
专利号:US-8835476-B2 优先权日:2005-03-04 标 题:Synthesis of novel antimicrobials 发明人:WU FAN; WEAVER DONALD; BARDEN CHRIS; MCMASTER CHRISTOPHER; BYERS DAVID; HENNEBERRY ANNETTE; BAN FUQIANG 权利人:WU FAN; WEAVER DONALD; BARDEN CHRIS; MCMASTER CHRISTOPHER; BYERS DAVID; HENNEBERRY ANNETTE; BAN FUQIANG 摘要:The synthesis and activity of novel LpxA inhibitors is described, these inhibitors present antibacterial activity. The compounds were designed based on a receptor model developed using the crystal structure of LpxA and are arranged to have a favorable binding interaction at the active site of the enzyme. In particular, the compounds present the following formula (I) where V, W, X, Y and Z can be independently C, S, N or O and P1, P2 and P3 are ligands to bind to the three points of the proposed pharmacophore model. They can be chosen from a variety of groups.
专利号:US-11896947-B2 优先权日:2016-06-17 标题:System and process for continuous and controlled production of metal-organic frameworks and metal-organic framework composites 发明人:MOTKURI RADHA KISHAN; BONTHA JAGANNADHA R; MCGRAIL B PETER 权利人:BATTELLE MEMORIAL INSTITUTE 摘要:A MOF production system and method of making are detailed for continuous and controlled synthesis of MOFs and MOF composites. The system can provide optimized yields of MOFs and MOF composites greater than or equal to 95%.
专利号:US-10710971-B2 优先权日:2015-03-20 标题:Carbonate-promoted carboxylation reactions for the synthesis of valuable organic compounds 发明人:KANAN MATTHEW W; BANERJEE AANINDEETA 权利人:UNIV LELAND STANFORD JUNIOR; THE BOARD OF THE TRUSTEES OF THE LELAND STANFORD JUNIOR UNIV 摘要:A method for synthesizing a dicarboxylate containing an aromatic heterocycle is provided. A carboxylic acid containing a heterocycle is provided. A CO32− salt is provided to form a mixture, which converts the carboxylic acid containing an aromatic heterocycle to a carboxylate containing an aromatic heterocycle. CO2 gas is provided to the mixture. The mixture is heated to a temperature to at least partially melt the carboxylate containing an aromatic heterocycle.
专利号:US-11739112-B2 优先权日:2017-02-02 标 题:Low temperature process for the synthesis of MOF carboxylate nanoparticles 发明人:PANCHAL MONIK; NOUAR FARID; SERRE CHRISTIAN; BENZAQUI MARVIN; SENE SAAD; STEUNOU NATHALIE; GIMÉNEZ MARQUÉS MONICA 权利人:CENTRE NAT RECH SCIENT; UNIV DE VERSAILLES—SAINT QUENTIN EN YVELINES 摘要:The present invention relates to low temperature process for preparing nanoparticles of porous crystalline Fe-, Al- or Ti-based MOF carboxylate materials with low polydispersity index, and uses thereof, particularly as catalyst support for carrying out heterogeneously catalyzed chemical reactions, or as gas storage/separation/purification material, or as matrix for encapsulating active principles (medicine, cosmetics).
专利号:US-5087691-A 优先权日:1989-09-01 标题 :Poly-phenylated diamines and their use as polycondensation monomers in the synthesis of polyamide, poly(amide-imide), and polyimide polymers 发明人:HARRIS FRANK W 权利人:UNIV AKRON 摘要:New polyphenylated polynuclear aromatic diamines, such as 1,3-bis[4-aminophenyl]-2,3,5-triphenylbenzene, a process for their manufacture and their use as polycondensation components for the manufacture of polyamide, polyamide-imide and polyimide polymers are described. The polymers obtained with the aromatic diamines according to the invention are readily soluble, rigid-rod polymers and are distinguished by outstanding modulus, tensile compression strength, energy absorption, coefficient of expansion and electrical properties.
[参考文献]: Aude Demessence, Et Al. Structure And Magnetic Properties Of A New Cobalt(Ii) Thiophenedicarboxylate Coordination Polymer Showing Unprecedented Coordination. Inorg Chem. 2007 Apr 30;46(9):3423-5.
合成参考文献
参考文献:10.1107/s1600536810034410 摘要:Xia G, Liu J, Li Z, Ji M, Sun G. Dimethyl 3,3'-diphenyl-2,2'-[(S)-thio-phene-2,5-diylbis(carbonyl-aza-nedi-yl)]dipropano-ate tetra-hydro-furan monosolvate. Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 04;66(Pt 10):o2489.