CAS: 7789-69-7; Phosphorus Pentabromide

该化合物是一种化学化合物,其结构和特性独特,具有独特性;磷原子结为五溴原子,形成一种高度溴化的物种;该化合物一般是白色的,黄色的固体,在环境条件下因其稳定性而闻名;五溴二苯醚主要用于有机合成,作为将磷和溴引入有机分子的试剂;其再活动可归因于磷-溴联结的存在,可参与各种化学反应,包括核循环替代;此外,由于其高溴含量,该化合物具有阻燃性,引起对材料科学的兴趣;然而,由于该化合物的潜在毒性和环境影响,在处理该化合物时需要谨慎行事,因此需要在实验室和工业环境中采取适当的安全措施.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号7726-95-6 溴素 | CAS号7789-60-8 三溴化磷 | CAS号12185-10-3 黄磷 | CAS号3931-89-3 phosphorus thio... | CAS号10026-13-8 五氯化磷 | CAS号10035-10-6 氢溴酸 | CAS号10025-87-3 三氯氧磷 | CAS号506-96-7 乙酰溴 | CAS号7789-59-5 三溴氧磷 | CAS号10035-10-6 氢溴酸 | CAS号594-77-4 3,3-Dibromo-2,2... | CAS号30263-65-1 1,1-二溴频哪酮 | CAS号5469-26-1 1-溴频哪酮 | CAS号507-16-4 二溴亚砜 | CAS号58556-75-5 2,7-二溴萘 | CAS号3982-91-0 硫代磷酰氯 | CAS号13455-06-6 bromo-dichloro-...

合成工艺路线路线简述

    Phosphorous置于溴体系中,用 二硫化碳 作为反应溶剂,化学反应生成 五溴化磷
    参考文献:Jacobs,R. B.,Journal Of The Chemical Society,1937,Vol. 5,P. 945-953
    标题:Jacobs,R. B.,Journal Of The Chemical Society,1937,Vol. 5,P. 945-953

    专利信息


    专利号:US-2008032964-A1
    优先权日:2006-04-10
    标题:Process for the synthesis of azetidinone
    发明人:KANSAL VINOD K; AHMAD SUHAIL; MARIAPPAN SHANMUGAVEL; TYAGI BHUPENDRA; PERLMAN NURIT; LE PAIH JACQUES; ZANOTTI-GEROSA ANTONIO
    权利人:KANSAL VINOD K; AHMAD SUHAIL; MARIAPPAN SHANMUGAVEL; TYAGI BHUPENDRA; PERLMAN NURIT; LE PAIH JACQUES; ZANOTTI-GEROSA ANTONIO
    摘要:Provided are intermediates useful for the synthesis of hydroxyl-alkyl substituted azetidinones, processes of their preparation, and processes for the synthesis of certain hydroxyl-alkyl substituted azetidinones. Also provided are processes for the synthesis of 1-(4-fluorophenyl)-3(R)-[3-(4-fluorophenyl)-3(S)-hydroxypropyl]-4(S)-(4-hydroxyphenyl)-2-azetidinone, or ezetimibe.

    专利号:US-4399069-A
    优先权日:1980-10-12
    标题:Process for an enantioselective synthesis of optically active 14-oxo-E-homo-eburnane derivatives
    发明人:SZANTAY CSABA; SZABO LAJOS; KALAUS GYORGY; SAPI JANOS; KREIDL JANOS; FARKAS NEE KIRJAK MARIA; NEMES ANDRAS; CIBULA LASZLO
    权利人:RICHTER GEDEON VEGYESZET
    摘要:The invention relates to a new enantioselective synthesis for the preparation of optically active 14-oxo-E-homo-eburnane derivatives of the formula (Ia) ##STR1## wherein R 1 is alkyl having from 1 to 4 carbon atom. In the synthesis optically active 6-alkoxycarbonylhexahydroindoloquinolizinium salts are employed as starting materials, which contain a center of chirality at the site of attachment of the carboxyl group. This center of chirality preserves the optical activity of the optically active tryptophan ester from which this compound has been prepared until a new center of chirality is formed in the molecule in a configuration corresponding to the desired end product. The carboxyl group, which is not needed in the end product and only serves to preserving the optical activity can then be eliminated. n Compounds of the formula (Ia) are known in the art and may be used in the synthesis of (+)-vincamine and (+)-apovincaminic acid ethylester.

    专利号:US-4598160-A
    优先权日:1983-07-15
    标题 :Intermediate phenolic compounds for the catalytic synthesis of chromans
    发明人:TRUESDALE LARRY K
    权利人:HOFFMANN LA ROCHE
    摘要:A catalytic synthesis of chromans in racemic or optically active forms, including intermediates thereto; the synthesis employs an asymmetric palladium (II) catalyzed oxidative cyclization of a 2-homoallylphenol and provides intermediates useful in making chromans, especially vitamin E in racemic or optically active forms.

    专利号:US-8334381-B2
    优先权日:2006-11-16
    标题 :Process for the preparation of intermediates useful in the synthesis of imatinib
    发明人:FALCHI ALESSANDRO; GRENDELE ENNIO; MOTTERLE RICCARDO; STIVANELLO MARIANO
    权利人:FALCHI ALESSANDRO; GRENDELE ENNIO; MOTTERLE RICCARDO; STIVANELLO MARIANO; ITALIANA SINT SPA
    摘要:It is the object of the present invention a process for the preparation of 4-methyl-N3-[4-(3-pyridinyl)-2-pyrimidinyl]-1,3-benzenediamine and analogues thereof, intermediates useful for the synthesis of Imatinib, or 4-[(4-methyl-1-piperazinyl)methyl]-N-[4-methyl-3-[[4-(3-pyridinyl)-2-pyrimidinyl]amino]phenyl]benzamide.

    专利号:US-8420848-B2
    优先权日:2009-01-09
    标题:Process for the synthesis of beta glycerol phosphate
    发明人:KULKARNI YASHWANT
    权利人:KULKARNI YASHWANT; SIGMA ALDRICH CO LLC
    摘要:The present invention provides methods for the preparation of beta glycerol phosphate and its salts. In particular, the invention provides efficient methods for the synthesis of beta glycerol phosphate of high purity.

    专利号:US-2025197431-A1
    优先权日:2023-12-15
    标 题:Methods and systems for forming a layer comprising silicon and composition and synthesis of silicon precursor
    发明人:ROMERO PATRICIO EDUARDO; VERVUURT RENÉ HENRICUS JOZEF; DEZELAH CHARLES; PORE VILJAMI J
    权利人:ASM IP HOLDING BV
    摘要:Disclosed are methods and systems for forming a silicon-containing layer on a substrate. Further disclosed are composition and synthesis of silicon-containing precursor. The methods for forming a silicon-containing layer comprise executing a plurality of deposition cycles. A deposition cycle comprises a first precursor pulse that comprises exposing the substrate to a first precursor. The first precursor comprises a molecule comprising a P—Si bond. A deposition cycle further comprises a plasma pulse that comprises exposing the substrate to a plasma treatment. The plasma treatment comprises generating a plasma.
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    合成参考文献


    摘要:Sainsbury, M., Science of Synthesis Knowledge Updates, (2010) 1, 226.
    摘要:Tymoshenko, D. O., Science of Synthesis Knowledge Updates, (2012) 3, 410.
    摘要:Demchuk, O. M.; Stankevič, M.; Pietrusiewicz, K. M., Science of Synthesis Knowledge Updates, (2015) 1, 327.
    摘要:Dembitsky, V. M.; Vil’, V. A., Science of Synthesis Knowledge Updates, (2019) 3, 363.
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