2-溴-4,6-二硝基苯胺 反应生成2-氰基-4-硝基-6-溴苯胺 参考文献:Water-Insoluble Azo Dyestuffs Which Are Derivatives Of 标题:Water-Insoluble Azo Dyestuffs Which Are Derivatives Of 摘要:与以下化学式对应的不溶于水的偶氮染料:##str1## 其中x代表卤素,氰基,硝基,烷基,多氟烷基,多氟烷氧基,烷基磺酰基,磺胺基或被一个或两个烷基取代的磺胺基;Y和z相同或不同,代表氢,卤素,氰基,硝基,烷基,烷氧基,多氟烷基,多氟烷氧基,烷基磺酰基,磺胺基或被一个或两个烷基取代的磺胺基;R代表氢,卤素,氰基,硝基,烷基,烷氧基,多氟烷基,多氟烷氧基,烷基磺酰基,磺胺基或被一个或两个烷基取代的磺胺基;M等于0或1;核a可能被一个或多个氯原子或烷基,烷氧基或酰氨基取代.这些染料可用于染色合成或人造纤维,特别是涤纶纤维.
专利号:US-4257942-A 优先权日:1977-10-06 标题:New water-insoluble azo dyes 发明人:DEFEO FRANCESCO; CIPOLLI ROBERTO 权利人:ACNA 摘要:The present invention relates to the synthesis of new dyes having the following general formula: wherein: D is the residue of a diazotizable component of the carbocyclic or heterocyclic series X is an ethylene group, optionally substituted by halogen-methyl, alkyl C1-C4, aryl, aralkyl or CH2OCO(HN)nR (wherein R and n have the meanings hereinafter defined); R is alkyl C1-C8 optionally substituted by halogen, CN,COOH; aryl optionally substituted by one or more atoms of halogen, alkyl C1-C4, alkoxyl C1-C4; alkoxyl C1-C4; alkoxyl C1-C8; Aryloxy; aralkoxy; cycloalkoxy; aralkyl; naphthyl optionally substituted by halogen; alkenyl C2-C8, optionally substituted by halogen, CN, COOH; R1 and R2, either like or unlike each other, may be alkyl C1-C4 optionally substituted by halogen or CN groups; aralkyl; R3 is H; halogen, alkyl C1-C4; alkoxyl C1-C4, optionally substituted. n is 0 or 1.
专利号:WO-2024074814-A9 优先权日:2022-10-04 标题 :Composition comprising a functionalised dye and a diallylamine comonomer and use thereof 发明人:CANNON PAUL; DONLEY ADAM; LAWRENCE ANTHONY; WRIGHT GAVIN; TURNER CARL; ROBERTS PHILIP 权利人:SUBLINO LTD; COLOUR SYNTHESIS SOLUTIONS LTD 摘要:The present teachings relate to a composition comprising a functionalised dye and a diallylamine comonomer, and the use of such compositions in methods of colouring a substrate. The present teachings provide improved bonding of a dye to a substrate, and preferably allow colouring to be conducted entirely in the presence of an aqueous solvent.
专利号:US-4136033-A 优先权日:1969-11-07 标 题:6-hydroxypyridone-2 compounds having a cationic group in the 3-position 发明人:STEINEMANN WILLY 权利人:SANDOZ LTD 摘要:Compounds of the formula ##STR1## wherein K.sup.⊕ is a cationic group, preferably heterocyclic, n R is hydrogen or an organic radical, preferably alkyl, phenyl or acyl, n R 1 is hydrogen, hydrocarbyl, substituted hydrocarbyl, heterocyclyl, substituted heterocyclyl, amino or substituted amino, and n A.sup.⊖ is an anion, n Are useful as intermediates in the synthesis of azo dyes of the formula ##STR2## wherein D is an aromatic carbocyclic or heterocyclic diazo component radical, and n K.sup.⊕, r, r 1 and A.sup.⊖ are as defined above.
专利号:CN-104341319-A 优先权日:2014-10-08 标题 :A kind of synthesis technique of 2-cyano-4-nitro-6-bromoaniline
专利号:CN-1314343-A 优先权日:2001-03-30 标题 :Synthesis method and application of 2-cyano-4-nitro-6-bromoaniline
专利号:CN-114213281-B 优先权日:2021-12-31 标 题 :Synthesis method of 2-cyano-4-nitroaniline
[参考文献]: P David Josephy, Et Al. Potent Mutagenicity In The Ames Test Of 2-Cyano-4-Nitroaniline And 2,6-Dicyano-4-Nitroaniline, Components Of Disperse Dyes. Environ Mol Mutagen. 2016 Jan;57(1):10-6.
合成参考文献
参考文献:10.1007/s12221-024-00488-6 摘要:Ding L, Zhang H, Chen L, Wang Z, Pei L, Yang Q, Wang J. Improved Dyeing Performance of Blue Disperse Dyes with N-Acetoxyethyl Groups in D5 Non-aqueous Media System. Fibers Polym. 2024 Feb 23;25(3):1005–14. doi: 10.1007/s12221-024-00488-6.