CAS: 90-17-5; 2,2,2-Trichloro-1-Phenylethyl Acetate

该化合物是有机化合物,其特点是芳香结构和三氯甲基组的出现,该化合物一般是一种无色的,有独特气味的淡黄色液体,以水中的溶解性相对较低闻名,但在乙醇和乙醇等有机溶剂中可溶解;三氯甲基组的存在有助于其再活性,使其成为有机合成中的有用中间体,并成为生产各种化学化合物的潜在构件;此外,该化合物还展示了在芳香和香味化学领域可能感兴趣的特性;然而,由于氯原子的存在,必须谨慎地处理该物质,因为它可能对环境和健康造成危害;在与该化合物合作时,应采取适当的安全措施,包括使用个人防护设备和遵守相关条例.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号108-24-7 乙酸酐 | CAS号2000-43-3 2,2,2-三氯-1-苯基乙醇 | CAS号67-66-3 氯仿 | CAS号581-55-5 苯亚甲基双乙酸盐 | CAS号100-52-7 苯甲醛 | CAS号64-19-7 冰醋酸 | CAS号75-87-6 三氯乙醛 | CAS号71-43-2 苯 | CAS号75-36-5 乙酰氯 | CAS号536-74-3 苯乙炔

合成工艺路线路线简述

  • 合成目标产物 2,2,2-Trichloro-1-Phenylethyl Acetate 主要起始原料 Acetic Acid And 2,2,2-Trichloro-1-Phenylethanol
  • 2000-43-3 = 90-17-5
    反应条件:1.1 Reagents: 4-(Dimethylamino)Pyridine Solvents: Pyridine; 0 °C; 3 H,Rt
    标题:Copper(I)-Promoted Dechlorinative Surzur-Tanner Rearrangement Of 2,2,2-Trichloroethyl Carboxylates
    作者:Ram,Ram N.; Meher,Nabin Kumar
    参考文献:Organic Letters 日期:2003 卷标:5(2) 页码:145-147]

    2000-43-3 = 90-17-5
    反应条件:1.1 Catalysts: Tetrabutylammonium Bromide,Sulfuric Acid Solvents: Water; 2 H,100 °C
    标题:Preparation Of Crystal Rose By Bi-Catalysts Method
    作者:Zhao,Hui-Shuang
    参考文献:Tianjin Huagong 日期:2008 卷标:22(3) 页码:48-50]

    2000-43-3 = 90-17-5
    反应条件:1.1 Catalysts: Tetrabutylammonium Bromide,Sulfuric Acid Solvents: Water; 2 H,90 °C
    标题:Preparation Of Crystal Rose By Bi-Catalysts Method
    作者:Zhao,Yi-Hong; Zhao,Hui-Shuang
    参考文献:Jiangsu Huagong 日期:2007 卷标:35(6) 页码:29-31]

    581-55-5 = 90-17-5
    反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: Tetrabutylammonium Hexafluorophosphate Solvents: Chloroform,Benzene,Toluene; 6 H,20 °C
    标题:Recoverable Phase-Transfer Catalysts With Fluorinated Anions: Generation And Reactions Of Dichlorocarbene And Ccl3 Anion In The Heterogeneous System Koh(S)/cHCL3/nbu4Npf6
    作者:Kryshtal,Galina V.; Zhdankina,Galina M.; Zlotin,Sergei G.
    参考文献:European Journal Of Organic Chemistry 日期:2008 卷标:(10) 页码:1777-1782]

    2000-43-3 = 90-17-5
    反应条件:1.1 Reagents: Pyridine Catalysts: P-Toluenesulfonic Acid Solvents: Dichloromethane
    标题:Fumigant Antitermitic Activity Of Plant Essential Oils And Components From Ajowan (Trachyspermum Ammi),Allspice (Pimenta Dioica),Caraway (Carum Carvi),Dill (Anethum Graveolens),Geranium (Pelargonium Graveolens),And Litsea (Litsea Cubeba) Oils Against Japanese Termite (Reticulitermes Speratus Kolbe)
    作者:Seo,Seon-Mi; Kim,Junheon; Lee,Sang-Gil; Shin,Chang-Hoon; Shin,Sang-Chul; Et Al
    参考文献:Journal Of Agricultural And Food Chemistry 日期:2009 卷标:57(15) 页码:6596-6602]

    2000-43-3 = 90-17-5
    反应条件:1.1 Catalysts: Sulfuric Acid Solvents: Water
    标题:Improved Technology For Production Of Rosacetol
    作者:Zheng,Gengxiu; Wang,Qiusen; Zhang,Chuanjing
    参考文献:Huaxue Shijie 日期:1994 卷标:35(3) 页码:132-4]

    2000-43-3 = 90-17-5 [标题:Reaction Conditions
    标题:Preparation Of α-(Trichloromethyl)Benzyl Acetate For Perfumes
    参考文献:Poland]

    2000-43-3 = 90-17-5
    反应条件:1.1 Reagents: Pyridine
    标题:Reductive Addition Of Polyhalomethanes And Their Related Compounds To Aldehydes And 1,2-Elimination Of The Coupling Products In A Palladium/aluminum Bimetal Redox System
    作者:Tanaka,Hideo; Yamashita,Shiro; Yamanoue,Motoi; Torii,Sigeru
    参考文献:Journal Of Organic Chemistry 日期:1989 卷标:54(2) 页码:444-50
2,2,2-三氯-1-苯基乙醇置于硫酸,乙酸酐体系中,化学反应生成 乙酸-α-(三氯甲基)苄酯
参考文献:Ettel; Weichet,Collection Of Czechoslovak Chemical Communications,1950,Vol. 15,P. 520,523
标题:Ettel; Weichet,Collection Of Czechoslovak Chemical Communications,1950,Vol. 15,P. 520,523

海关参考信息

专利信息


专利号:WO-2018192923-A1
优先权日:2017-04-18
标题 :Alpha alkylation of aldehyde with a polycyclic olefin
发明人:QUINTAINE JULIE; MACMILLAN DAVID W C
权利人:FIRMENICH & CIE
摘要:The present invention relates to the field of organic synthesis and more specifically to the alpha alkylation of an aldehyde with a polycyclic olefin followed by a ring opening step in order to provide compound of formula (I) in the form of any one of its stereoisomers or a mixture thereof and wherein R represents a hydrogen atom or C 1-8 linear alkyl group; R 1 , R 2 , R 3 and R 4 represent, when taken separately, independently of each other, a hydrogen atom or a C 1-2 linear alkyl group or a C 3-4 linear or branched alkyl group; or R 2 and R 3 , when taken together, represent a C 4-10 linear, branched or cyclic alkanediyl group and n is 1 or 2.

专利号:US-12076423-B2
优先权日:2015-12-23
标题 :Spiculisporic acid-based composition
发明人:AGNAOU REDA; MARION CATHERINE
权利人:OREAL
摘要:Composition in the form of an oil-in-water emulsion that includes at least 1% of an oil phase, and an aqueous phase. The composition includes 0.1 to 15 wt % spiculisporic acid relative to the total weight of the composition, at least one base selected from amino acids and alkanolamines in an amount suitable for forming at least a monosalt of spiculisporic acid, less than 3% glycol(s) and/or polyol(s) relative to the total weight of the composition, at least one UV filter and/or an additive selected from volatile aromatic materials such as essential oils and fragrance substances, fillers, dyeing materials such as pigments, mother-of-pearl or particles with a metallic sheen, moisturizers, anti-wrinkle or anti-age agents, peeling agents, antioxidants, active ingredients stimulating the synthesis of epidermal and/or dermal macromolecules, dermo-relaxing agents, depigmentation agents, deodorant agents and mixtures thereof.

专利号:US-2025034074-A1
优先权日:2021-11-25
标题:Process for preparing a cyclic diene
发明人:JACOBY DENIS; CHAPPUIS SIMONE; KELLER FABRICE
权利人:FIRMENICH & CIE
摘要:The present invention relates to the field of organic synthesis and more specifically it concerns a process for preparing compound of formula (I) comprising the reaction of a compound of the formula (II) with a base having a boiling point superior to the boiling point of the compound of formula (I). Moreover, the compound of formula (I) and the compound of formula (II) are also part of the invention.

专利号:US-2024327367-A1
优先权日:2021-07-30
标 题 :Process for preparing a oxacylohexane or oxacylopentane derivative
发明人:DAPSENS PIERRE-YVES; VILCOQ LEA
权利人:FIRMENICH & CIE
摘要:The present invention relates to the field of organic synthesis and, more specifically, it concerns a process for the preparation of a cycloether of formula (I) comprising the cyclisation of compound of formula (II) performed in the presence of heterogenous acidic catalyst.

专利号:WO-2023057548-A1
优先权日:2021-10-07
标题:Ccr6 receptor modulators
发明人:AISSAOUI HAMED; ALLEMANN OLIVER; CAROFF EVA; MEYER EMMANUEL; RICHARD-BILDSTEIN SYLVIA
权利人:IDORSIA PHARMACEUTICALS LTD
摘要:The present invention relates to compounds of Formula (I), their synthesis and use as CCR6 receptor modulators for the prevention or treatment of e.g. inflammatory/autoimmune diseases/disorders and cancer.

专利号:US-4762819-A
优先权日:1983-02-05
标题 :2,6-exo configured tricyclo-5.2.1.02,6 decane derivatives with functional side chains at C-8/C-9 and their utilization thereof as perfumes
发明人:BRUNKE ERNST-JOACHIM
权利人:DRAGOCO GERBERDING CO GMBH
摘要:The invention relates to 2,6-exo-configured tricyclo-5.2.1.02,6 decane derivatives that correspond to general formula A wherein A Ra = Rb = Rc = Rd = HRa, Rb, Rc = H, CH3 (2 x H, 1 x CH3), Rd = CH3 R1, R2: H, C1-C5Alkyl Ra, Rb, Rc, Rd are hydrogen or Rd is a methyl group and Ra, Rb, Rc are hydrogen or methyl groups, one of the substituents being a methyl group and both the others being hydrogen, the broken line represents a C-C double bond optionally at (-3) or (-4), the wavy line represents geometric isomers, R1 and R2 are hydrogen, or lower alkyl groups with a total of 1-6 carbon atoms, and X represents a carbonyl or hydroxyl function, as well as a process for their synthesis and their use as scents.
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合成参考文献


摘要:Food and Cosmetics Toxicology., 13(919), 1975
摘要:Kostikov, R. R., Science of Synthesis, (2006) 24, 93.
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