CAS: 16004-77-6; Adamantane-1,3,5,7-Tetraamine

相似化合物

10303-95-4 768-94-5 665-66-7

上下游产品

adamantane-1,3,5,7-tetracarboxamide

1,3,5,7-Adamantanetetracarboxamide置于溴,Sodium Hydroxide体系中,用 水 用作溶剂,化学反应 1.0H,以70%的收率获得1,3,5,7-四氨基金刚烷
参考文献:用于可调电导率的基于三维四硫富瓦烯的共价有机框架
标题:用于可调电导率的基于三维四硫富瓦烯的共价有机框架
摘要:三维 (3D) 共价有机框架 (Cof) 的功能化对于扩大其应用至关重要.然而,将具有电活性能力的有机基团引入到 3D Cof 中仍然非常有限.在此,我们报告了具有非或 2 倍互穿 Pts 拓扑和可调电化学活性的 3D 四硫富瓦烯基 Cof(3D-Ttf-Cof)的第一个案例.获得的 Cof 显示出高结晶度,永久孔隙率和大比表面积(高达 3000 M2/g).此外,这些基于 Ttf 的 Cof 具有氧化还原活性,可通过碘掺杂形成有机盐,该盐具有可调节的电导率(在 120 oc 时高达 1.4 x 10-2 S Cm-1).这些结果为设计 3D 电活性 Cof 材料开辟了道路,并促进了它们在分子电子学和能量存储中的应用.
Doi:10.1021/jacs.9B06908

专利信息

专利号:US-12170372-B2
优先权日:2022-03-11
标 题 :Nitrogen-doped hollow cobaltosic oxide and preparation method and use thereof
发明人：WU XINGYU; LI CHANGDONG; Feng Maohua; RUAN DINGSHAN; LI BIN; LIU BAOYE
权利人:GUANGDONG BRUNP RECYCLING TECHNOLOGY CO LTD; HUNAN BRUNP RECYCLING TECH CO LTD; HUNAN BRUNP EV RECYCLING CO LTD
摘要:The invention belongs to the technical field of material synthesis, and discloses a nitrogen-doped hollow cobaltosic oxide and a preparation method and application thereof. A chemical formula of the nitrogen-doped hollow cobaltosic oxide is Co3O4—COF-T-D@C—N; and the COF-T-D is a covalent organic framework. Due to an open hollow structure, the nitrogen-doped hollow cobaltosic oxide of the invention has a large specific surface area, thus having a large contact area with an electrolyte, which is convenient for lithium ions to transport therein. The open hollow structure also prevents a volume effect from being generated during charging and discharging, and nitrogen is introduced for doping, so that granules can be gradually activated to increase the specific surface area and active sites, a discharge (cycle) stability of the material is improved, and a rate performance of the material is improved.