氯置于fe-B Alloy体系中,化学反应生成三氯化硼 参考文献:Mazzetti; Carli,De,Atti Della Accademia Nazionale Dei Lincei,Classe Di Scienze Fisiche,Matematiche E Naturali,Rendiconti,1922,Vol. 31 Ii,# 5,P. 119 标题:Mazzetti; Carli,De,Atti Della Accademia Nazionale Dei Lincei,Classe Di Scienze Fisiche,Matematiche E Naturali,Rendiconti,1922,Vol. 31 Ii,# 5,P. 119
专利信息
专利号:US-7615169-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
专利号:US-10053406-B2 优先权日:2015-10-23 标题 :Synthesis of honokiol 发明人:JARACZ STANISLAV; KOZLOWSKI MARISA; EUN LEE YOUNG; KIM SUN MIN 权利人:COLGATE PALMOLIVE CO; UNIV PENNSYLVANIA 摘要:Disclosed herein are improved methods for the synthesis of honokiol, as well as methods for the synthesis of 3,3′-di-tert-butyl-5,5′-dimethyl-[1,1′-biphenyl]-2,4′-diol, 3′,5-dimethyl-[1,1′-biphenyl]-2,4′-diol, and 2,4′-dimethoxy-3′,5-dimethyl-1,1′-biphenyl, 3,3′,5,5′-tetra-tert-butyl-[1,1′-biphenyl]-2,4′-diol, and certain tetrasubstituted bisphenols, and uses therefor.
专利号:US-2006287520-A1 优先权日:2005-05-16 标 题 :Synthesis of salinosporamide A and analogues thereof 发明人:DANISHEFSKY SAMUEL J; ENDO ATSUSHI 权利人:DANISHEFSKY SAMUEL J; ENDO ATSUSHI 摘要:A novel synthesis of salinosporamide A is provided. Salinospoamide A as well as structurally related natural products, omuralide and lactacystin, have been shown to be proteasome inhibitors. Therefore, these compounds as well as analogues of these natural products may be useful in the treatment of proliferative diseases such as cancer, autoimmune diseases, diabetic retinopathy, etc. The invention provides for the synthesis of salinosporamide A as well as analogs thereof using a convenient point for derivatization of the bicyclic core. Pharmaceutical compositions and method of using the inventive compounds are also provided.
专利号:WO-2023036838-A1 优先权日:2021-09-07 标题:Process for preparing starting compounds intended for the synthesis of an ammine metal borohydride 发明人:HAJIYEV PARVIZ; NGUYEN HUYNH DUC 权利人:COMMISSARIAT ENERGIE ATOMIQUE 摘要:Process for preparing a metal hydride of formula AxMHx+m and a borane compound BH3, starting from a product of formula AxM(BNH)x+m, wherein: A is an alkali metal, M is a metal different from an alkali metal, 0 ≤ x ≤10, in particular 0 ≤ x ≤ 2 m>0, the process comprising: aT) reacting the metal hydride of formula AxM(BNH)x+m with ammonia such as obtain an ammoniated product of formula AxM(NH2)x+m and a hydrogenated boron nitride compound BNH, a' 2) the hydrogenation of the ammoniated product of formula AxM(NH2)x+m such as to obtain an metal hydride of formula AxMHx+m, the process further comprising the separation of the hydrogenated boron nitride compound BNH from the ammoniated product of formula AxM(NH2)x+m before step a' 2) or from the metal hydride of formula AxMHx+m after step a' 2), and b) the synthesis of the borane compound BH3, from the hydrogenated boron nitride compound BNH, the synthesis comprising: - a digestion reaction of the boron nitride compound BNH in a gaseous atmosphere containing, even consisting in, an anhydrous hydrogen halide acid gas comprising at least one halogen element Y, such as to produce a boron halide BY3, Y being preferably chlorine Cl, - a hydrodehalogenation of the boron halide, in a hydrogen gas atmosphere to obtain the borane compound BH3.
专利号:WO-2023036831-A1 优先权日:2021-09-07 标 题:Process for preparing starting compounds intended for the synthesis of an ammine metal borohydride 发明人:HAJIYEV PARVIZ; NGUYEN HUYNH DUC 权利人:COMMISSARIAT ENERGIE ATOMIQUE 摘要:Process for preparing a metal hydride of formula AxMHx+m and a borane compound BH3, starting from a product of formula AxM(BNH)x+m, wherein: A is an alkali metal, M is a metal different from an alkali metal, 0 ≤ x ≤10, in particular 0 ≤ x ≤ 2 m>0, the process comprising: a) contacting the product of formula AxM(BNH)x+m with a catalyst comprising a transition metal in solution in an aprotic polar solvent, such as to separate the metal hydride of formula AxMHx+m and a hydrogenated boron nitride compound BNH, b) the synthesis of the borane compound BH3, from the hydrogenated boron nitride compound BNH, the synthesis comprising: - a digestion reaction of the boron nitride compound BNH in a gaseous atmosphere containing, even consisting in, an anhydrous hydrogen halide acid gas comprising at least one halogen element Y, such as to produce a boron halide BY3, Y being preferably chlorine Cl, - a hydrodehalogenation of the boron halide, in a hydrogen gas atmosphere to obtain the borane compound BH3.
专利号:US-7927516-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
摘要:Merino, P., Science of Synthesis, (2010) 45, 14. 摘要:Fringuelli, F.; Piermatti, O.; Pizzo, F.; Vaccaro, L., Science of Synthesis, (2010) 47, 682. 摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 210. 摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 157. 摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 212.