专利号:WO-2025066562-A1 优先权日:2023-09-27 标 题 :Sugar backbone polymer and synthesis method 发明人:CHEN GUOSONG; Xue Cece; RAO ZIKUN 权利人:UNIV FUDAN 摘要:A polymer material, specifically a sugar backbone polymer and a synthesis method. A new type of sugar backbone polymer is prepared using a condensation and polymerization method. An addition reaction of alcohol-olefin is introduced into the synthesis of the sugar backbone polymer, to form a new functional primary sugar chain alternating polymer having alternating sugar and aliphatic units. It overcomes shortcomings of existing artificial chemical synthesis methods such as difficulty in controlling the stereoselectivity of the product, low molecular weight, cumbersome monomer preparation and few types. The molecular weight of the prepared polymer can reach 71,067 g/mol, and monomer preparation is simple.
专利号:US-5189184-A 优先权日:1990-08-30 标题:2-(3'-butenyl)-3,4-dihydro-2h-pyrans, their synthesis and use 发明人:SCHAEFER DIETMAR; WEIER ANDREAS; WEITEMEYER CHRISTIAN; WEWERS DIETMAR 权利人:GOLDSCHMIDT AG TH 摘要:2-(3'-butenyl)-3,4-dihydro-2H-pyrans of the general formula wherein R is a hydrogen group or an alkyl group with 1 to 6 carbon atoms. Methods for the synthesis of these compounds and their use as reactive modifiers or diluents for cationically curable monomers or polymers.
专利号:US-5073643-A 优先权日:1990-08-30 标 题 :High yield synthesis of hydroxyl-containing cationic photoinitiators 发明人:CRIVELLO JAMES V 权利人:POLYSET CORP 摘要:Synthesis use of a new class of diaryliodonium salt photo and thermal polymerization initiators in which the aryl groups are substituted with alkoxy group bearing hydroxy groups. Good to excellent yields are obtained of diaryliodonium salts in which the aryl groups are substituted with long chain alkoxy groups, which alkoxy groups also possess at least one hydroxyl moiety attached at the 2-position of an alkoxy group. The resultant salts have enhanced solubility when compared with their lower molecular weight counterparts. The hydroxyl groups serve as chain transfer agents; and, in cross linking UV-induced cationic polymerizations, the hydroxyl groups effect marked accelertion on polymerization rates. The salts also have excellent compatability with nonpolar monomers such as epoxidized oil and poly(1,2-butadience oxide) and provide further benefits when they are used along with copper cocatalysts in thermally curable polymer systems. In the latter form of cases, the secondary hydroxyl group serves as a reducing agent for the copper (II) complex.
专利号:US-4980430-A 优先权日:1989-10-20 标题:Epoxy vinyl ethers and synthesis of an epoxy vinyl ether from a hydroxylated vinyl ether and a diepoxide 发明人:LIU KOU-CHANG; VARA FULVIO J; DOUGHERTY JAMES A 权利人:GAF CHEMICALS CORP 摘要:This invention relates to epoxy vinyl ethers having the formula: ##STR1## where R is a polyvalent linear, branched or cyclic hydrocarbon radical having from 2 to 20 carbon atoms, optionally substituted with alkyleneoxy; A is branched or linear C 1 to C 4 alkylene; B is halogen or lower alkyl; m has a value of from 0 to 4; n has a value of from 0 to 20; p has a value of from 1 to 5; and T is ##STR2## when p is one, and is ##STR3## or a mixture of ##STR4## and ##STR5## when p is greater than one.
专利号:US-7728088-B2 优先权日:2002-08-06 标题 :Synthesis of statistical microgels by means of controlled radical polymerisation 发明人:DESTARAC MATHIAS; BAVOUZET BRUNO; TATON DANIEL 权利人:RHODIA OPERATIONS 摘要:The invention relates to a method of preparing statistical microgels. The inventive method comprises a step involving the radical polymerisation of a composition containing: at least one monoethylenically-unsaturated monomer, at least one multiethylenically-unsaturated monomer, a free radical source and a control agent. The invention also relates to first generation microgels thus prepared and all the compounds resulting from said microgels (next-generation microgels).
专利号:US-6384216-B1 优先权日:2000-08-09 标 题 :Purification of alkenyl compounds 发明人:LORENZ RUDOLF ERICH; BOETTCHER ARND; PINKOS ROLF 权利人:BASF AG 摘要:A process for purifying alkenyl compounds having a divalent or trivalent heteroatom in the alpha-position relative to the double bond by distillation comprises carrying out at least two distillations in which the purified alkenyl compounds are obtained from the gas phase by condensation, where the time between the first distillation after the synthesis of the alkenyl compounds and at least one further distillation is at least one day and the purified alkenyl compounds have an APHA color number of <30.
参考标题:Purification Of Alkenyl Compounds 摘要:A Process For Purifying Alkenyl Compounds Having A Divalent Or Trivalent Heteroatom In The &agr;-Position Relative To The Double Bond By Distillation Comprises Carrying Out At Least Two Distillations In Which The Purified Alkenyl Compounds Are Obtained From The Gas Phase By Condensation, Where The Time Between The First Distillation After The Synthesis Of The Alkenyl Compounds And At Least One Further Distillation Is At Least One Day And The Purified Alkenyl Compounds Have An Apha Color Number Of <30.
合成参考文献
摘要:Acute Toxicity Data. Journal of the American College of Toxicology, Part B., 1(34), 1990