71-36-3 = 871-58-9 反应条件:1.1 Reagents: Potassium Hydroxide; Rt; 30 Min,Rt 标题:Synthesis Of Iron Sulfide Thin Films And Powders From New Xanthate Precursors 作者:Almanqur,Laila; Et Al 参考文献:Journal Of Crystal Growth 日期:2019 卷标:522 页码:175-182]
专利号:US-4357465-A 优先权日:1975-12-09 标 题 :3',4'-Diedeoxykanamycin B derivatives 发明人:UMEZAWA HAMAO; UMEZAWA SUMIO; SEKI SHIGEO; FUKATSU SHUNZO; YASUDA SHUNTARO 权利人:MICROBIAL CHEM RES FOUND 摘要:New routes are provided for the synthesis of 3',4'-dideoxykanamycin B which is effective in inhibiting kanamycin-resistant organisms from kanamycin B through new intermediate, of which a fundamental process comprises a new reaction of a 3',4'-epoxy derivative of amino- and hydroxyl-protected kanamycin B with a xanthate to form a corresponding 3',4'-dideoxy-3'-eno derivative followed by removal of the amino- and hydroxyl-protecting groups thereof and by hydrogenation of the resulting 3',4'-dideoxy-3'-eno-kanamycin B. A 3',4'-episulfide derivative corresponding to the 3',4'-epoxy derivative which is formed as second product in the reaction of 3',4'-epoxy derivative with xanthate is also used as intermediate for the preparation of 3',4'-dideoxykanamycin B.
专利号:US-4195170-A 优先权日:1975-12-09 标 题:3',4'-Episulfido kanamycin B compounds 发明人:FUKATSU SHUNZO; SEKI SHIGEO; UMEZAWA HAMAO; UMEZAWA SUMIO; YASUDA SHUNTARO 权利人:MICROBIAL CHEM RES FOUND 摘要:New routes are provided for the synthesis of 3',4'-dideoxykanamycin B which is effective in inhibiting kanamycin-resistant organisms from kanamycin B through new intermediate, of which a fundamental process comprises a new reaction of a 3',4'-epoxy derivative of amino- and hydroxyl-protected kanamycin B with a xanthate to form a corresponding 3',4'-dideoxy-3'-eno derivative followed by removal of the amino- and hydroxyl-protecting groups thereof and by hydrogenation of the resulting 3',4'-dideoxy-3'-eno-kanamycin B. A 3',4'-episulfide derivative corresponding to the 3',4'-epoxy derivative which is formed as second product in the reaction of 3',4'-epoxy derivative with xanthate is also used as intermediate for the preparation of 3',4'-dideoxykanamycin B.
专利号:CN-107698475-A 优先权日:2017-08-18 标 题:A kind of synthesis technique of liquid xanthate under solvent-free condition
专利号:CN-112403684-A 优先权日:2020-11-25 标题:A kind of synthesis method of xanthogen-quaternary ammonium salt ionic liquid and its application
专利号:CN-110229284-B 优先权日:2019-07-15 标 题 :Synthesis method of polyaryletherketone grafted polyvinylpyrrolidone
专利号:CN-117247350-A 优先权日:2023-09-04 标题:Synthesis method of quinoline-2-xanthate
参考标题:Copper-Catalyzed Synthesis Of Thiazol-2-Yl Ethers From Oxime Acetates And Xanthates Under Redox-Neutral Conditions 作者:Zhongzhi Zhu,Xiaodong Tang,Jinghe Cen,Jianxiao Li,Wanqing Wu,Huanfeng Jiang 摘要:Acetates And Xanthates For The Synthesis Of Thiazol-2-Yl Ethers With Remarkable Regioselectivity Has Been Developed. Various Oxime Acetates, Whether Derived From Aryl Ketones Or Alkyl Ketones, Or Natural Product Cores Are Suitable For This Conversion. Unique Dihydrothiazoles Were Also Obtained When Both Reaction Sites Were Methine. Mechanistic Studies Indicated That Imino Copper(III) Intermediates Were Involved
合成参考文献
摘要:Aitken, R. A., Science of Synthesis Knowledge Updates, (2018) 3, 314. 摘要:Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982, -(102), 1982