CAS: 87546-18-7; Flumiclorac-Pentyl

• 英文名称Flumiclorac-Pentyl
• 中文名称氟烯草酸
• 其它别名Resource
• CAS编号87546-18-7
• MFCD编号:MFCD04112759
• FDA UNII编号:67CZ8IH915
• 分子式:C21H23ClFNO5
• 分子量:423.86
• 产品CID: 1883310
• 产品分类化学农药原药 → 除草剂 → 其他除草剂

• 相似结构搜索
• 产品信息参考;
• InChIKey: IRECWLYBCAZIJM-UHFFFAOYSA-N
• 1S/C21H23ClFNO5/c1-2-3-6-9-28-19(25)12-29-18-11-17(16(23)10-15(18)22)24-20(26)13-7-4-5-8-14(13)21(24)27/h10-11H,2-9,12H2,1H3…
• 计算化学: 氢键受体数6.0氢键供体数0.0可旋转键数9.0

物理性质

• 熔点90-91 °C
• 沸点558 °C at 760 mmHg
• 闪点291.3 °C
• 密度1.34g/cm3
• pKa:-2.32±0.20(预测)
• PSA:72.91
• LogP:4.4001
• 折射率1.575
• 蒸汽压1.74E-12 mmHg at 25 °C
• 溶解性0.000189 mg/mL at 25 °C
• 敏感性水中半衰期为6min (pH=9)、19h(pH=7)、42d (pH=5)。
• 外观形态氟咪草酯戊酯
• 储存条件0-6°C
• 产品应用利收(87546-18-7)的用途:1.它是一种原卟啉原氧化酶抑制剂.2.药剂被敏感杂草叶面吸收后,迅速作用于植株组织,引起原卟啉积累,使细胞膜脂质过氧化作用增强,从而导致敏感杂草的细胞结构和细胞功能,不可逆损害.3. 氟胺草酯 可用于玉米作物.推荐用量为45～67.5g(有效成分)/ha,也有推荐40～100g(有效成分)/ha.4.本剂为苗后除草剂,用于防除大豆田一年生阔叶杂草如藜,卷耳,豚草,苋属杂草,黄花稔,斑地锦,曼陀螺,苘麻等.
• 性质描述利收(87546-18-7)的性状:纯品为白色粉状固体.蒸气压(25°C)为l.0×10-5Pa,相对密度(20°C)为1.33,熔点为88.9～90.1°C.分配系数(20°C)为4.99,25°C时溶解度为甲醇47.8g/L,正辛醇16.0g/L,丙酮590/L,正己烷3.28g/L,水0.189mg/L.水中半衰期为6min(pH=9),19h(pH=7),42d(pH-5).毒性:本品对兔眼睛和皮肤有中度刺激作用.无致突变性,无致畸作用.鹌鹑经口LD50＞2250mg/kg,鹌鹑和野鸭LC50＞5620mg/L.对大鼠经口LD50＞3.6g(0.86EC)/kg,兔经皮LD50为2.0g(0.86EC)/kg,大鼠吸人LC50为5.51mg(0.86EC)/L.虹鳟鱼LC50为l.lmg/L,大翻车鱼为13～21mg/L(96h).

MSDS等安全信息

• UN编号UN 3077

上下游产品

合成工艺路线路线简述

• 123012-99-7 = 87546-18-7
  反应条件:1.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; 6 H,Reflux
  标题:Synthesis Of Novel Herbicide Flumiclorac-Pentyl
  作者:Lu,Yang; Et Al
  参考文献:Nongyao Kexue Yu Guanli 日期:2009 卷标:30(6) 页码:33-35]
  
  100004-30-6 = 87546-18-7
  反应条件:1.1 Reagents: Sulfuryl Chloride
  标题:3-Amino-4-Fluorophenol
  参考文献:Japan]
  
  = 87546-18-7
  反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol; Rt -> 0 °C; 5 - 6 H; 0.9 Mpa; 1 Mpa,50 °C2.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; 6 H,Reflux
  标题:Synthesis Of Novel Herbicide Flumiclorac-Pintyl
  作者:Lu,Yang; Et Al
  参考文献:Huagong Jishu Yu Kaifa 日期:2009 卷标:38(6) 页码:14-16]
  
  84478-72-8 = 87546-18-7 [标题:Reaction Conditions
  标题:Tetrahydrophthalimide Compounds And Their Use
  参考文献:European Patent Organization]
  
  = 87546-18-7
  反应条件:1.1 Reagents: Sulfuric Acid Solvents: Dichloromethane; 50 °C1.2 Reagents: Fuming Nitric Acid; 1 H,50 °C; 50 °C -> 75 °C; 3 H,75 °C2.1 Catalysts: Palladium,Carbon Solvents: Toluene; 5 H,1 Mpa,Rt3.1 Reagents: Acetic Acid Catalysts: Piperidine Solvents: Toluene; 5 H,Reflux
  标题:Study On New Synthesis Process Of Flumiclorac-Pentyl
  作者:Tu,Mei-Ling; Et Al
  参考文献:Zhejiang Gongye Daxue Xuebao 日期:2009 卷标:37(2) 页码:152-155]
  
  84478-75-1 + 5411-55-2 = 87546-18-7
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 30 Min,45 °C1.2 Ph 9,45 °C; 6 - 7 H,Ph 9,45 °C; 45 °C -> 10 °C2.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol; Rt -> 0 °C; 5 - 6 H; 0.9 Mpa; 1 Mpa,50 °C3.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; 6 H,Reflux
  标题:Synthesis Of Novel Herbicide Flumiclorac-Pintyl
  作者:Lu,Yang; Et Al
  参考文献:Huagong Jishu Yu Kaifa 日期:2009 卷标:38(6) 页码:14-16]
  
  84478-75-1 + 5411-55-2 = 87546-18-7
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 20 Min,40 - 45 °C1.2 1 H,40 - 45 °C; 6 H,40 - 45 °C; 45 °C -> 20 °C2.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol; 0.9 Mpa; 5 H,0.9 - 1.1 Mpa,50 - 55 °C3.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; Rt -> Reflux; 6 H,Reflux
  标题:Synthesis Of 2-[2-Chloro-4-Fluoro-5-(1,3,4,5,6,7-Hexahydro-1,3-Dioxo-2H-Isoindol-2-Yl)Phenoxy]Acetic Acid Pentyl Ester (Flumiclorac-Pentyl)
  作者:Zhang,Liyong; Et Al
  参考文献:Nongyao 日期:2007 卷标:46(5) 页码:307-309]
  
  153471-75-1 = 87546-18-7
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water2.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide3.1 Reagents: Acetic Acid,Iron Solvents: Water4.1 Reagents: Propionic Acid,Piperidine Solvents: Toluene
  标题:Synthesis Of Herbicide Flumiclorac-Pentyl
  作者:Wu,Hao; Et Al
  参考文献:Nongyao 日期:2000 卷标:39(11)]
  
  371-41-5 = 87546-18-7
  反应条件:1.1 Reagents: Chlorine Solvents: 1,2-Dichloroethane; 6 - 8 °C2.1 Reagents: Sodium Hydroxide Catalysts: Tetrabutylammonium Bromide Solvents: 1,2-Dichloroethane,Water; 6 - 80 °C2.2 Reagents: Triphosgene Solvents: 1,2-Dichloroethane; 6 - 80 °C2.3 Reagents: Sulfuric Acid,Fuming Nitric Acid Solvents: Water; 4 - 5 H,80 °C2.4 Reagents: Hydrochloric Acid Solvents: Ethanol,Water; 4 H,Reflux; Reflux -> 10 °C3.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 30 Min,45 °C3.2 Ph 9,45 °C; 6 - 7 H,Ph 9,45 °C; 45 °C -> 10 °C4.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol; 0.9 Mpa; 5 - 6 H,1 Mpa,50 °C5.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; 6 H,Reflux
  标题:Synthesis Of Novel Herbicide Flumiclorac-Pentyl
  作者:Lu,Yang; Et Al
  参考文献:Nongyao Kexue Yu Guanli 日期:2009 卷标:30(6) 页码:33-35]
  
  123012-99-7 = 87546-18-7
  反应条件:1.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; 6 H,Reflux
  标题:Synthesis Of Novel Herbicide Flumiclorac-Pintyl
  作者:Lu,Yang; Et Al
  参考文献:Huagong Jishu Yu Kaifa 日期:2009 卷标:38(6) 页码:14-16]
  
  123012-99-7 = 87546-18-7
  反应条件:1.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; Rt -> Reflux; 6 H,Reflux
  标题:Synthesis Of 2-[2-Chloro-4-Fluoro-5-(1,3,4,5,6,7-Hexahydro-1,3-Dioxo-2H-Isoindol-2-Yl)Phenoxy]Acetic Acid Pentyl Ester (Flumiclorac-Pentyl)
  作者:Zhang,Liyong; Et Al
  参考文献:Nongyao 日期:2007 卷标:46(5) 页码:307-309]
  
  84478-41-1 + 52034-03-4 = 87546-18-7 [标题:Reaction Conditions
  标题:Tetrahydrophthalimide Compounds And Their Use
  参考文献:European Patent Organization]
  
  = 87546-18-7
  反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol; 0.9 Mpa; 5 - 6 H,1 Mpa,50 °C2.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; 6 H,Reflux
  标题:Synthesis Of Novel Herbicide Flumiclorac-Pentyl
  作者:Lu,Yang; Et Al
  参考文献:Nongyao Kexue Yu Guanli 日期:2009 卷标:30(6) 页码:33-35]
  
  = 87546-18-7
  反应条件:1.1 Catalysts: Palladium,Carbon Solvents: Toluene; 5 H,1 Mpa,Rt2.1 Reagents: Acetic Acid Catalysts: Piperidine Solvents: Toluene; 5 H,Reflux
  标题:Study On New Synthesis Process Of Flumiclorac-Pentyl
  作者:Tu,Mei-Ling; Et Al
  参考文献:Zhejiang Gongye Daxue Xuebao 日期:2009 卷标:37(2) 页码:152-155]
  
  84478-75-1 + 5411-55-2 = 87546-18-7
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 30 Min,45 °C1.2 Ph 9,45 °C; 6 - 7 H,Ph 9,45 °C; 45 °C -> 10 °C2.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol; 0.9 Mpa; 5 - 6 H,1 Mpa,50 °C3.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; 6 H,Reflux
  标题:Synthesis Of Novel Herbicide Flumiclorac-Pentyl
  作者:Lu,Yang; Et Al
  参考文献:Nongyao Kexue Yu Guanli 日期:2009 卷标:30(6) 页码:33-35]
  
  84478-75-1 = 87546-18-7 [标题:Reaction Conditions
  标题:Tetrahydrophthalimide Compounds And Their Use
  参考文献:European Patent Organization]
  
  5411-55-2 + 1996-41-4 = 87546-18-7
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 50 °C; 5 H,80 °C2.1 Reagents: Sulfuric Acid Solvents: Dichloromethane; 50 °C2.2 Reagents: Fuming Nitric Acid; 1 H,50 °C; 50 °C -> 75 °C; 3 H,75 °C3.1 Catalysts: Palladium,Carbon Solvents: Toluene; 5 H,1 Mpa,Rt4.1 Reagents: Acetic Acid Catalysts: Piperidine Solvents: Toluene; 5 H,Reflux
  标题:Study On New Synthesis Process Of Flumiclorac-Pentyl
  作者:Tu,Mei-Ling; Et Al
  参考文献:Zhejiang Gongye Daxue Xuebao 日期:2009 卷标:37(2) 页码:152-155]
  
  1996-41-4 = 87546-18-7
  反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Tetrabutylammonium Bromide Solvents: 1,2-Dichloroethane,Water; 6 - 80 °C1.2 Reagents: Triphosgene Solvents: 1,2-Dichloroethane; 6 - 80 °C1.3 Reagents: Sulfuric Acid,Fuming Nitric Acid Solvents: Water; 4 - 5 H,80 °C1.4 Reagents: Hydrochloric Acid Solvents: Ethanol,Water; 4 H,Reflux; Reflux -> 10 °C2.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 30 Min,45 °C2.2 Ph 9,45 °C; 6 - 7 H,Ph 9,45 °C; 45 °C -> 10 °C3.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol; 0.9 Mpa; 5 - 6 H,1 Mpa,50 °C4.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; 6 H,Reflux
  标题:Synthesis Of Novel Herbicide Flumiclorac-Pentyl
  作者:Lu,Yang; Et Al
  参考文献:Nongyao Kexue Yu Guanli 日期:2009 卷标:30(6) 页码:33-35]
  
  371-41-5 = 87546-18-7
  反应条件:1.1 Reagents: Chlorine Solvents: 1,2-Dichloroethane; 6 - 8 °C1.2 Reagents: Sodium Hydroxide,Triphosgene Catalysts: Tetrabutylammonium Bromide Solvents: 1,2-Dichloroethane,Water; 6 - 8 °C1.3 Reagents: Sulfuric Acid,Fuming Nitric Acid Solvents: Water; Rt; Rt -> 80 °C; 4 - 5 H,80 °C1.4 Reagents: Hydrochloric Acid Solvents: Ethanol,Water; 4 H,Reflux; Reflux -> 10 °C2.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 30 Min,45 °C2.2 Ph 9,45 °C; 6 - 7 H,Ph 9,45 °C; 45 °C -> 10 °C3.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol; Rt -> 0 °C; 5 - 6 H; 0.9 Mpa; 1 Mpa,50 °C4.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; 6 H,Reflux
  标题:Synthesis Of Novel Herbicide Flumiclorac-Pintyl
  作者:Lu,Yang; Et Al
  参考文献:Huagong Jishu Yu Kaifa 日期:2009 卷标:38(6) 页码:14-16]
  
  371-41-5 = 87546-18-7
  反应条件:1.1 Reagents: Chlorine Solvents: 1,2-Dichloroethane; 3 - 4 H,5 - 10 °C1.2 Reagents: Sodium Hydroxide Catalysts: Tetrabutylammonium Bromide Solvents: Water; 20 - 30 °C1.3 Reagents: Phosgene Solvents: 1,2-Dichloroethane; 3 H,20 - 30 °C; 1 H,20 - 30 °C1.4 Reagents: Sulfuric Acid,Fuming Nitric Acid Solvents: Water; 1 H,40 - 60 °C; 60 °C -> 80 °C; 3 H,75 - 80 °C1.5 Reagents: Hydrochloric Acid Solvents: Ethanol,Water; 4 H,Reflux; Reflux -> 10 °C2.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 20 Min,40 - 45 °C2.2 1 H,40 - 45 °C; 6 H,40 - 45 °C; 45 °C -> 20 °C3.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol; 0.9 Mpa; 5 H,0.9 - 1.1 Mpa,50 - 55 °C4.1 Catalysts: Acetic Acid,Piperidine Solvents: Toluene; Rt -> Reflux; 6 H,Reflux
  标题:Synthesis Of 2-[2-Chloro-4-Fluoro-5-(1,3,4,5,6,7-Hexahydro-1,3-Dioxo-2H-Isoindol-2-Yl)Phenoxy]Acetic Acid Pentyl Ester (Flumiclorac-Pentyl)
  作者:Zhang,Liyong; Et Al
  参考文献:Nongyao 日期:2007 卷标:46(5) 页码:307-309]
  
  84478-89-7 = 87546-18-7 [标题:Reaction Conditions
  标题:Tetrahydrophthalimide Compounds And Their Use
  参考文献:European Patent Organization]
  
  371-41-5 = 87546-18-7
  反应条件:1.1 Reagents: Chlorine1.2 Reagents: Sodium Hydroxide Solvents: Water1.3 Reagents: Sulfuric Acid,Nitric Acid2.1 Reagents: Sodium Hydroxide Solvents: Water3.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide4.1 Reagents: Acetic Acid,Iron Solvents: Water5.1 Reagents: Propionic Acid,Piperidine Solvents: Toluene
  标题:Synthesis Of Herbicide Flumiclorac-Pentyl
  作者:Wu,Hao; Et Al
  参考文献:Nongyao 日期:2000 卷标:39(11)]
  
  84478-88-6 = 87546-18-7
  反应条件:1.1 Reagents: Sulfuric Acid,Nitric Acid2.1 -3.1 -4.1 -5.1 -
  标题:Tetrahydrophthalimide Compounds And Their Use
  参考文献:European Patent Organization

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
  2903919090-氯苯
  2905121000-正丙醇
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