CAS: 34683-73-3; 1-Chloro-6-Iodohexane

相似化合物

60274-60-4 10297-05-9 2163-00-0

上下游产品

1,6-dichlorohexane 1-Chlorohexane 1,6-hexanediol 4-methylbenzenesulfonic acid 6-chlorohexyl ester 8-chloro-°Ct-1-yne 1-chloro-7-hexadecyne 7-hexadecynyl iodide 1-chloro-7-heptadecyne

6-氯-1-己醇置于咪唑,碘,三苯基膦体系中,用 二氯甲烷 用作溶剂,以70%的收率获得1-氯-6-碘己烷
参考文献:使用 Sbu2Mg 在甲苯中进行自由基 I/mg 交换反应制备伯二烷基镁和仲二烷基镁
标题:使用 Sbu2Mg 在甲苯中进行自由基 I/mg 交换反应制备伯二烷基镁和仲二烷基镁
摘要:伯二烷基镁试剂和仲二烷基镁试剂是通过s Bu 2 Mg 与烷基碘反应在甲苯中制备的(25-40 °C,1-4 小时).观测到仲环己基碘的立体会聚 I/mg 交换导致猝灭反应后产生具有高对映选择性和非对映选择性的产物,包括同羟醛产物.机制研究证实了这些交换的根本途径.
Doi:10.1002/anie.202116625

专利信息

专利号:US-4026911-A
优先权日:1976-02-23
标 题:Process for the preparation of ketoalkynoic acids and use of the process in an improved synthesis of 2-(substituted)-cyclo-pentane-1,3,4-triones
发明人：REVERMAN LAWRENCE FRANCIS
权利人:MILES LAB
摘要:Reaction of a 2-methyl-2-(alkenyl)-1,3-dioxolane with an α,ω-dihalogenoalkane to obtain a 2-methyl-2-(ω-chloroalkynyl)-dioxolane, conversion of the latter to a corresponding nitrile, and hydrolysis of the nitrile to form a ketoalkynoic acid is a novel process for preparing the acid. n Use of the process in the synthesis of 2-(substituted)-cyclopentane-1,3,4-triones improves that synthesis.

专利号:US-7915276-B2
优先权日:2006-02-14
标题 :Berberrubine derivatives having antifungal activities
发明人：KIM SUNG UK; PARK KI DUK; MOON JAE SUN; KANG TAE HOON; KIM YOUNG KOOK
权利人:KOREA RES INST OF BIOSCIENCE
摘要:The present invention relates to a berberrubine derivative having superior antifungal activity, more particularly to a berberrubine derivative having activity against chitin synthase, which participates in the synthesis of chitin and is essential in the growth of fungi, and having a potent antifungal activity against human pathogenic fungi.

专利号:WO-2025136842-A1
优先权日:2023-12-19
标题 :Process for preparing n-aminoalkylated tryptophan compounds
发明人：CO SARAH S; DALBY STEPHEN M; JOHNSON KEYWAN ALEXANDER; KLAPARS ARTIS; KUETHE JEFFREY T; PETERS BYRON KENNEDY; SIROTA ERIC; WRIGHT TIMOTHY JAMES; XIAO KAIJIONG
权利人:MERCK SHARP & DOHME LLC
摘要:The present invention relates to processes useful in the synthesis of aminohexyl compounds, such as a compound of Formula I or a salt, hydrate and/or solvate thereof, as well as methods for the preparing a compound of Formula I and intermediates used to make a compound of Formula I. The present invention presents a novel method for the selective alkylation of tryptophan analogues, eliminating the need for protecting groups and advancing the field of tryptophan analogue synthesis.

专利号:DE-2707128-A1
优先权日:1976-02-23
标 题:PROCESS FOR THE PREPARATION OF KETOALKYNIC ACIDS AND APPLICATION OF THE PROCESS TO AN IMPROVED SYNTHESIS OF 2- (SUBSTITUTE) -CYCLOPENTANE-1,3,4-TRIONEN

专利号:CN-116621696-A
优先权日:2023-05-30
标题:A kind of synthesis method of pear borer worm sex pheromone

专利号:CN-111333576-B
优先权日:2018-12-18
标题 :A class of highly stable wash-free Halo-tag probes and their synthesis and biological applications