专利号:US-5556924-A 优先权日:1993-11-01 标题 :Synthesis of photoreactive polymeric binders 发明人:FITZGERALD MAURICE J; KEARNEY FREDERICK R; LIANG RONG-CHANG; SCHWARZEL WILLIAM C 权利人:POLAROID CORP 摘要:A photoreactive binder that may be used to enhance photospeed in either conventional plates or on-press developable lithographic printing plates. Briefly, a polymer of m-isopropenyl- alpha , alpha -dimethylbenzyl isocyanate is derivatized for vinyl group reactivity by reacting the isocyanate groups thereof with hydroxyalkyl acrylate. The resulting photopolymeric binder provides significantly higher photospeed than the non-reactive binder currently utilized in the production of conventional printing plates. The resulting lithographic printing plate also shows better durability (as manifested by longer run-length) and is more easily developed by the microencapsulated developers utilized in the present invention. As to the preparation of the photoreactive binders, the application discloses a method of copolymerizing m-isopropenyl- alpha , alpha -dimethylbenzyl isocyanate (m-TMI) through complexation with an electron-deficient monomer such as maleic anhydride to accelerate free radical copolymerization with other monomers, and thus, provides greater monomer-to-polymer conversion. Use of the resulting product in the photoresist of a lithographic printing plate improves its adhesion to an underlying substrate.
专利号:CN-107556183-B 优先权日:2016-06-24 标题 :Synthesis method of o-diketone
参考文献:10.1246/cl.2002.1130 摘要:Kawano M, Ozawa Y, Matsubara K, Imabayashi H, Mitsumi M, Toriumi K, Ohashi Y. Synchrotron Radiation Structure Analyses of the Light-induced Radical Pair of a Hexaarylbiimidazolyl Derivative. Origin of the Spin-Multiplicity Change. 2002 Nov 01;31(11):1130–1. doi: 10.1246/cl.2002.1130.