CAS: 79-97-0; 4,4'-(Propane-2,2-Diyl)Bis(2-Methylphenol)

该化合物是一种与二酚A(BPA)结构相关的化学化合物,由中央碳桥连接的两个酚组组成,主要用于生产高性能聚合物,树脂和涂料,热稳定性和化学抗药性至关重要,与一些传统双酚相比,BPC具有更强的耐久性和机械强度,适合要求工业用途,其分子结构允许根据特定配方的性能进行量身定制的修改,以优化其性能.BPC虽然比BPA少讨论,但在需要强健物质特性的合适应用中仍然具有相关性.由于化学反应性和潜在的环境考虑,适当的处理和监管合规至关重要.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号95-48-7 邻甲酚 | CAS号67-64-1 丙酮 | CAS号108-22-5 醋酸异丙烯酯 | CAS号463-49-0 丙二烯 | CAS号7647-01-0 盐酸 | CAS号576-55-6 3,4,5,6-四溴邻甲酚 | CAS号67081-42-9 4,5,6-tribromo-... | CAS号861372-32-9 2-bromo-6-methy... | CAS号583-59-5 2-甲基环己醇 | CAS号1740-97-2 4-异丙基-2-甲基苯酚 | CAS号95-48-7 邻甲酚 | CAS号62268-99-9 4-[2-(4-hydroxy... | CAS号6339-35-1 2-(dimethylamin...

合成工艺路线路线简述

  • 合成目标产物 2,2-Bis(4-Hydroxy-3-Methylphenyl)Propane 主要起始原料 O-Cresol And Acetone
  • (文献来源)合成步骤主要原料 O-Cresol 和 Acetone
邻甲酚置于硫酸,甲苯,十二硫醇体系中,化学反应 1.0H,反应生成 4,4'-(1-甲基亚乙基)双(2-甲基苯酚)
参考文献:ビスフェノールの製造方法,及び,ポリカーボネート樹脂の製造方法
标题:ビスフェノールの製造方法,及び,ポリカーボネート樹脂の製造方法
摘要:在反应生成双酚类化合物的反应中,从芳香族醇和酮或醛反应生成双酚类化合物的反应中,缩短反应生成双酚类化合物的反应时间,改善反应生成双酚类化合物的选择性,并获得具有非常好色调的双酚类化合物的制备方法.将含有芳香族醇的有机相和含有硫酸的水相在油水分离的状态下,使芳香族醇反应生成芳香族醇磺酸,得到含有芳香族醇磺酸的反应反应生成液的步骤(1),将含有芳香族醇磺酸的反应反应生成液与酮或醛混合,在芳香族醇磺酸存在下,从芳香族醇和酮或醛反应生成双酚类化合物的步骤(2),包括制备双酚类化合物的方法.[选择图]无

海关参考信息

专利信息


专利号:US-2009043069-A1
优先权日:2007-08-06
标 题 :Activated esters for synthesis of sulfonated telechelic polycarbonates
发明人:BRUNELLE DANIEL J; COLONNA MARTINO; FIORINI MAURIZIO; BERTI CORRADO; BINASSI ENRICO
权利人:GEN ELECTRIC
摘要:A process of making a sulfonated telechelic polycarbonate is described. A dihydroxy compound, a carbonate ester, and an activated ester of a sulfobenzoic acid salt are reacted together. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.

专利号:US-6545187-B1
优先权日:2001-09-19
标 题 :Production of low-particulate bisphenol and use thereof in the manufacturing of polycarbonate
发明人:KISSINGER GAYLORD MICHAEL; CHEN FANG CHRISTINE; BLUBAUGH JAMES CRISTOPHER; NANCE DARLENE HOPE; STOKES EDWARD BRITTAIN; ORDONEZ JUAN RODRIGUEZ; QUINTANA JOSE M
权利人:GEN ELECTRIC
摘要:Low-particulate dihydric aromatic compounds such as bisphenol-A that can be used in the synthesis of low-particulate polycarbonates are prepared by introducing into a desorber column containing a non-aggregate packing material an adduct of bisphenol and phenol and optionally a stripping gas. The column is maintained at an operating temperature that is sufficiently high and an operating pressure that is sufficiently low such that the adduct is distilled. The stream of phenol and the stripping gas is recovered from the top of the column. A second stream containing bisphenol that is substantially free of added particulate matter is recovered from the bottom of the column. This purified stream of bisphenol-A can further be used in a method of producing optical-grade polycarbonate.

专利号:US-4404363-A
优先权日:1981-05-02
标题 :Separation of diphasic mixtures containing aromatic polyesters
发明人:FREITAG DIETER; SERINI VOLKER; GOOSSENS JOHN; BOTTENBRUCH LUDWIG; HUCKS UWE
权利人:BAYER AG
摘要:Diphasic mixtures obtained from the synthesis of aromatic polyesters by the diphasic interface process may be separated into an aqueous phase and an organic phase by the addition of selected compounds.

专利号:US-8394912-B2
优先权日:2009-12-22
标 题 :Process and apparatus for the preparation of polycarbonate
发明人:DOEBERT FRANK; STREMMEL ANDREAS; BIEDRON CHRISTOPH; LAUE STEPHAN; RECHNER JOHANN; HAGEN TORSTEN; BRUYNSEELS FRANK; QUAEYHAEGENS FRANK; DECLOEDT JOHAN; VAN DORST PAUL; ARNDT UWE; EYNDE JOHAN VANDEN; TRACHT URSULA; KOENIG THOMAS; LIESENFELDER ULRICH
权利人:DOEBERT FRANK; STREMMEL ANDREAS; BIEDRON CHRISTOPH; LAUE STEPHAN; RECHNER JOHANN; HAGEN TORSTEN; BRUYNSEELS FRANK; QUAEYHAEGENS FRANK; DECLOEDT JOHAN; VAN DORST PAUL; ARNDT UWE; EYNDE JOHAN VANDEN; TRACHT URSULA; KOENIG THOMAS; LIESENFELDER ULRICH; BAYER MATERIALSCIENCE AG
摘要:The invention relates to a process for the pretreatment of material surfaces in order to minimize the interaction between polycarbonate and metal and, in the processing and synthesis of polycarbonate, to obtain a high-quality polymer which in particular does not become discolored and is free of insoluble constituents.

专利号:WO-2023038267-A1
优先权日:2021-09-13
标 题 :Monomer composition for synthesis of recycled plastic, method for preparing same, and recycled plastic and molded product using same

专利号:US-8309655-B2
优先权日:2009-12-22
标题 :Methods for the preparation of a poly(arylene ether) polysiloxane multiblock copolymer, multiblock copolymers produced thereby, and associated compositions and articles
发明人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT
权利人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT; SABIC INNOVATIVE PLASTICS IP
摘要:A poly(arylene ether)-polysiloxane multiblock copolymer is prepared by the reaction of a hydroxy-diterminated poly(arylene ether), a hydroxyaryl-diterminated polysiloxane, and an aromatic diacid chloride. This synthesis overcomes disadvantages of known syntheses of poly(arylene ether)-polysiloxane block copolymers. The poly(arylene ether)-polysiloxane multiblock copolymer is useful for improving the melt processability of poly(arylene ether) compositions.
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主要参考文献

参考标题:Redox‐neutral Coupling Between Two C(Sp 3 )−h Bonds Enabled By 1,4‐palladium Shift For The Synthesis Of Fused Heterocycles
作者:Ronan Rocaboy,Ioannis Anastasiou,Olivier Baudoin |发布日期:2019.10.7
摘要:Secondary C-H Bonds, Which Are Adjacent To An Oxygen Or Nitrogen Atom On One Side, And Benzylic Or Adjacent To A Carbonyl Group On The Other Side. A Variety Of Valuable Fused Heterocycles Were Obtained From Easily Accessible Ortho-Bromophenol And Aniline Precursors. The Second C-H Bond Cleavage Was Successfully Replaced With Carbonyl Insertion To Generate Other Types Of C(Sp3 )-C(Sp3 ) Bonds.

合成参考文献


摘要:US EPA; Estimation Program Interface (EPI) Suite. Ver. 4.10. Jan, 2011. Available from, as of Nov 5, 2012:
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
摘要:SPARC; pKa/property server. Ver 4.6., Oct, 2011. Available from, as of Nov 5, 2012:
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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