CAS: 1631-84-1; Phenyldichlorosilane

该化合物是一种有机硅化合物,其特点是存在一种苯环,以二氯硅类组替代.该化合物一般呈现无色的黄色,因存在硅-氯的债券而闻名其反应性.二氯硅类组可以参与各种化学反应,使其在合成有机化学和材料科学中有用.该化合物经常被用作硅聚合物和其他含硅材料合成的前体.该化合物一般在标准条件下稳定,但在有湿气,释放盐酸和形成硅醇化合物的情况下可水解.在处理(二氯硅)苯时,应采取安全防范措施,因为它可能会对皮肤,眼睛和呼吸系统产生刺激.建议在冷却,干燥的湿气区进行适当储存,以保持其稳定性和再活性.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号694-53-1 苯硅烷 | CAS号10025-78-2 三氯氢硅 | CAS号98-13-5 苯基三氯硅烷 | CAS号108-90-7 氯苯 | CAS号1631-83-0 二苯基氯硅烷 | CAS号80-10-4 二苯基二氯硅烷 | CAS号71-43-2 苯 | CAS号4109-96-0 二氯硅烷 | CAS号7446-70-0 氯化铝 | CAS号7637-07-2 三氟化硼 | CAS号1077-57-2 3-(dichlorophen... | CAS号140903-06-6 ditert-butyl-ch... | CAS号18106-32-6 2-chloroethyl(3... | CAS号18030-58-5 5,5-dichloroben... | CAS号268561-25-7 tert-butyl-chlo... | CAS号27991-58-8 trimethyl-[phen... | CAS号3401-26-1 dichloro-(3-chl... | CAS号98-13-5 苯基三氯硅烷 | CAS号80-10-4 二苯基二氯硅烷

合成工艺路线路线简述

    三氯硅烷置于c6H5Mgbr体系中,用 Not Given 用作溶剂,以26%的收率获得苯基二氯硅烷
    参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Si: Mvol.C,58,Page 165-167
    标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Si: Mvol.C,58,Page 165-167

    海关参考信息

    专利信息


    专利号:US-2013165350-A1
    优先权日:2011-12-22
    标 题:Surface linkers for array synthesis
    发明人:KUIMELIS ROBERT; MCGALL GLENN; PAO DEXTER; CHEN ZIHUI; AXELROD TREVOR
    权利人:KUIMELIS ROBERT; MCGALL GLENN; PAO DEXTER; CHEN ZIHUI; AXELROD TREVOR; AFFYMETRIX INC
    摘要:The present invention provide several methods of derivatizing a surface of a support with one or more linkers thus providing a suitable platform for synthesis of a polymer array, particular a nucleic acid array. Some methods derivatize a surface with a self-assembled monolayer (SAM) of a linker. The SAM confers advantages of hydrolytic stability, broad compatibility with synthesis and detection chemistries, and reduced emergence of latent functional groups during polymer array synthesis. Substrates can also be derivatized with multi-layers of SAMs providing greater hydrolytic stability. Substrates can also be derivatized by synthesizing a linker in situ on the substrate by atom transfer radical polymerization of functional and functional monomers. Appropriate selection of monomers reduces emergence of latent functional groups in subsequent array synthesis.

    专利号:CN-107216242-A
    优先权日:2017-07-07
    标题 :A method for the synthesis of aromatic aldehydes, aromatic ketones and aromatic esters by iron-catalyzed oxidation of alkyl aromatic compounds

    专利号:US-2626268-A
    优先权日:1948-12-11
    标 题 :Synthesis of aliphatic silanes
    发明人:JOHN BARRY ARTHUR; DE PREE LEE; EUGENE HOOK DONALD
    权利人:DOW CHEMICAL CO

    专利号:CN-110256327-A
    优先权日:2019-06-20
    标题:A kind of method that iron catalyzes the synthesis of 2-indolinone compound of oxidized indole compound

    专利号:CN-100402475-C
    优先权日:2006-05-16
    标题:Method for direct chlorination synthesis of chlorohydrocarbon adopting chlorosilane carbonyl compound

    专利号:US-5808162-A
    优先权日:1995-07-21
    标题:Chiral unsymmetric diphosphine compound and transition metal complex containing the same as ligand
    发明人:SAYO NOBORU; ZHANG XIAOYONG; OMOTO TATSUYA; YOKOZAWA TOHRU; YAMASAKI TETSURO; KUMOBAYASHI HIDENORI
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:A novel chiral unsymmetric diphosphine compound of formula (I): ##STR1## wherein Ar 1 and Ar 2 , which are different from each other, each represent a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, a pyridyl group, a quinolyl group, an isoquinolyl group, a furfuryl group, a benzofurfuryl group, a thienyl group, or a benzothienyl group, and a transition metal complex containing the diphosphine compound as a ligand. The complex catalyzes various asymmetric synthesis reactions, e.g., asymmetric hydrogenation or asymmetric hydrosilylation, exhibiting excellent performance in selectivity, conversion and catalytic activity, to provide a product of desired absolute configuration at high optical purity and in high yield.
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    合成参考文献


    摘要:Michael, J. P.; de Koning, C. B., Science of Synthesis, (2002) 4, 955.
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