专利号:US-7122694-B2 优先权日:1998-11-06 标 题 :Hydroboronation process 发明人:MARCUCCIO SEBASTIAN MARIO; RODOPOULOS MARY; WEIGOLD HELMUT 权利人:BORON MOLECULAR PTY LTD 摘要:The invention relates to processes for the synthesis of aryl or alkene borates which comprises reacting: (i) an olefinic compound having a halogen or halogen-like substituent in a vinylic substitution position, or (ii) an aromatic ring having a halogen or halogen-like substituent in a ring substitution position, with a disubstituted monohydroborane in the presence of a Group 8-11 metal catalyst. The invention also relates to the use of these borates in coupling reactions. The invention further relates to certain disubstituted monohydroboranes and aryl or alkene borates.
专利号:CN-114315885-A 优先权日:2021-12-28 标 题:A method for catalytic synthesis of methyl 3-hydroxy-4-((trimethylsilyl)ethynyl)benzoate
专利号:WO-2005047237-A1 优先权日:2003-11-06 标题 :Method for synthesising diaryl sulphide compounds in a solid phase 发明人:DIAZ PHILIPPE 权利人:GALDERMA RES & DEV; DIAZ PHILIPPE 摘要:The invention relates to a method for synthesising, in an industrialised solid phase, novel diaryl sulphide compounds of formula (I). Said invention also relates to the purity of novel industrial useful products, to chemical compounds produced by said synthesis, to pharmaceutical or dermatological compositions containing said products and to the use thereof in the pharmaceutical compositions for human medicine and for veterinary sciences or for cosmetic compositions.
参考文献:10.1007/s00044-014-1311-7 摘要:Barone M, Pistarà V, Frasca G, Noto C, Scribano M, Catalfo A, Santagati A. Synthesis, structure–activity relationships, and bioactivity evaluation of 6-bromo-quinazolinone derivatives. Medicinal Chemistry Research. 2014 Dec 13;24(6):2461–75. doi: 10.1007/s00044-014-1311-7.