CAS: 613-69-4; 2-Ethoxybenzaldehyde

上下游产品

CAS号71672-75-8 邻乙氧基苯甲醇 | CAS号90-02-8 水杨醛 | CAS号74-96-4 溴乙烷 | CAS号938-73-8 2-乙氧基苯甲酰胺 | CAS号50-00-0 甲醛 | CAS号103-73-1 苯乙醚 | CAS号89-95-2 邻甲基苄醇 | CAS号69471-15-4 2-(4-hydroxy-2,... | CAS号75-03-6 碘乙烷 | CAS号4265-25-2 2-甲基苯并呋喃 | CAS号938-73-8 2-乙氧基苯甲酰胺 | CAS号94-71-3 邻乙氧基苯酚 | CAS号19508-22-6 4-[(2-ethoxyphe... | CAS号611-20-1 水杨腈 | CAS号90-02-8 水杨醛 | CAS号79636-94-5 5-溴-2-乙氧基苯甲醛 | CAS号69038-81-9 2-乙氧基肉桂酸 | CAS号6609-57-0 邻乙氧基苯腈 | CAS号71672-75-8 邻乙氧基苯甲醇

2-乙氧基苯甲酰胺置于lithium-Tris(Diethylamino)Hydridoaluminate体系中,用 四氢呋喃 作为反应溶剂,化学反应 12.0H,以83%的收率获得产物2-乙氧基苯甲醛
参考文献:用双或三(二烷基氨基)氢化铝锂进行选择性还原.三,三(二乙氨基)氢化铝锂将伯酰胺还原为醛
标题:用双或三(二烷基氨基)氢化铝锂进行选择性还原.三,三(二乙氨基)氢化铝锂将伯酰胺还原为醛
摘要:在室温下,Thf中的三(二乙基氨基)氢化锂铝可将脂肪族和芳香族伯酰胺很容易地还原为相应的醛,产率为50-90%.
DOI:10.1016/0040-4039(91)80439-D

专利信息

专利号:US-5861532-A
优先权日:1997-03-04
标 题:Solid-phase synthesis of N-alkyl amides
发明人：BROWN EDWARD G; NUSS JOHN M
权利人:CHIRON CORP
摘要:Methods for solid phase synthesis of N-alkyl amides comprise reductive amination of carbonyl compounds using a reducing agent and an amine-containing linker bound to a solid support. The methods afford high yields of linker-bound, monoalkylated amines, and subsequent coupling with acid derivatives provide derivatized N-substituted amides in excellent yields after cleavage from the solid-phase. Compositions useful in solid phase synthesis are also described.

专利号:US-5783577-A
优先权日:1995-09-15
标题 :Synthesis of quinazolinone libraries and derivatives thereof
发明人：HOUGHTEN RICHARD A; OSTRESH JOHN M
权利人:TREGA BIOSCIENCES INC
摘要:The present invention provides synthetic combinatorial libraries of organic compounds based on the quinazolinone ring.

专利号:US-5175302-A
优先权日:1987-07-13
标 题 :Nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4837327-A
优先权日:1987-07-13
标 题 :Process for nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to alkehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4999429-A
优先权日:1989-01-09
标 题 :Process for the preparation of α,α,β-1-trifluoro-1-olefinic derivatives
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:EP-3515880-B1
优先权日:2017-03-17
标题:Methods and compositions for synthesis of encoded libraries
发明人：LI JIN; MORGAN BARRY A; Wan jinqiao; DOU DENGFENG; LIU GUANSAI; CHANG YONG; CHEN QIUXIA; WANG XING; XU YANSHAN; HU DONGYAN; LIU JIAN; CHENG XUEMIN
权利人:HITGEN INC