2,4-二硝基苯甲酸置于三氯溴甲烷,三氯异氰尿酸,溴体系中,化学反应 18.0H,以91%的收率获得产物1-溴-2,4-二硝基苯 参考文献: Process For The Preparation Of Organic Halides[fr] Procédé De Préparation D'Halogénures Organiques 标题: Process For The Preparation Of Organic Halides[fr] Procédé De Préparation D'Halogénures Organiques 摘要:本发明提供了一种卤代羧酸脱羧化工艺,用于从相应的羧酸制备有机氯化物,有机溴化物及其混合物,所述工艺使用从三氯异氰酸(tcca),二氯异氰酸(dcca)或其组合中选取的氯化试剂和溴化试剂.
专利信息
专利号:WO-2004096766-A1 优先权日:2003-04-29 标题 :A method of indole synthesis 发明人:BANWELL MARTIN GERHARDT; LUPTON DAVID WILLIAM 权利人:UNIV AUSTRALIAN; BANWELL MARTIN GERHARDT; LUPTON DAVID WILLIAM 摘要:The present invention relates to methods for the synthesis of indoles. In particular, the invention relates to the coupling of an a-haloenone or a-haloenal with an ortho-halonitroarene to form an ortho-(enone)nitroarene or ortho-(enal)nitroarene. Reductive cyclization of an ortho-(enone)nitroarene or ortho-(enal)nitroarene affords access to indole compounds.
专利号:US-8754111-B2 优先权日:2011-01-26 标 题 :Method and substances for preparation of N-substituted pyridinium compounds 发明人:GEBAUER PETER; HEINDL DIETER; HORN CARINA 权利人:ROCHE DIAGNOSTICS OPERATIONS 摘要:A method for the synthesis of N-substituted 3-acylated pyridinium compounds by reacting a pentamethine precursor with a primary amine.
专利号:US-8895747-B2 优先权日:2009-07-27 标 题 :Method and substances for preparation of N-substituted pyridinium compounds 发明人:HEINDL DIETER; MAERZ HERIBERT; SCHMIDT AXEL 权利人:HEINDL DIETER; MAERZ HERIBERT; SCHMIDT AXEL; ROCHE DIAGNOSTICS OPERATIONS 摘要:Methods for the synthesis of N-substituted pyridinium compounds by using an N-heteroaryl substituted pyridinium salt (Zincke salt) and reacting it with a nucleophilic amine are provided. Novel purine-substituted pyridyl compounds, which may be useful reagents in the above reaction, are also disclosed.
专利号:US-9085535-B2 优先权日:2009-07-27 标 题 :Method and substances for the preparation of N-substituted pyridinium compounds 发明人:HEINDL DIETER; GEBAUER PETER 权利人:HEINDL DIETER; GEBAUER PETER; ROCHE DIAGNOSTICS OPERATIONS 摘要:Methods for the synthesis of N-substituted carboxylated pyridinium compounds by reaction of a pentamethine precursor with a primary amine are provided. In this reaction an N-substituted alkoxycarbonyl pyridinium heterocycle is formed.
专利号:WO-2006117556-A2 优先权日:2005-05-04 标题:Materials and methods for the photodirected synthesis of oligonucleotide arrays
专利号:CN-116283823-B 优先权日:2023-03-17 标题 :Synthesis method and application of dehydroabietyl B-cyclobenzothiazole-aniline and diphenylamine compound