CAS: 118-74-1; Hexachlorobenzene

该化合物是一种氯化芳香化合物,其特点是附于苯环的六氯原子,其特点是六氯原子,它看起来像是白色晶状固体,水中熔点高,溶解度低,但可溶解于有机溶剂中,众所周知六氯苯在环境中具有稳定性和持久性,导致活生物体中的生物累积性;它历来被用作农药,杀真菌剂,并用于生产其他化学品,尽管许多国家已限制或禁止使用,因其毒理效应,六氯苯被归类为可能的人类致癌物,可造成各种健康问题,包括肝脏损伤和内分泌干扰,其环境影响重大,因为它可能持续在土壤和沉积物中,导致长期的生态后果;监测与补救工作对于减少其在受污染场地的存在至关重要.

结构式图片

欧盟法规

《欧盟PIC法规》统一分类与标签ECHA物质食品接触材料-禁用CMR物质OtherC&L通报REACH预注册废弃物危险特性清单欧盟《事先知情同意法规》附件五"欧盟管控危险化学品"ECHA物质工作场所安全标识要求化妆品禁用物质清单欧盟《水框架指令》附件X

上下游产品

tetrachloromethane 2-Benzoylbenzoic acid phthalic anhydride benzophenoneN-pentachlorophenyl-hexanediyldiamineN-pentachlorophenyl-hexanediyldiamine N,N'-bis-pentachlorophenyl-hexanediyldiamineN,N'-bis-pentachlorophenyl-hexanediyldiamine 1,2,4,5-tetrachloro-3,6-bis-pentylsulfanyl-benzene Pentachlorophenol

合成工艺路线路线简述

  • 合成目标产物 Hexachlorobenzene 主要起始原料 2-Dichloromethylene-1,2,3,3,5,5-Hexachlorocyclopent-1-Ene
  • (文献来源)合成步骤主要原料 2-Dichloromethylene-1,2,3,3,5,5-Hexachlorocyclopent-1-Ene
四氯乙烯 反应生成六氯苯
参考文献:Molera; Ariza,Anales De La Real Sociedad Espanola De Fisica Y Quimica,Serie B: Quimica,1958,Vol. 54,P. 389,390
标题:Molera; Ariza,Anales De La Real Sociedad Espanola De Fisica Y Quimica,Serie B: Quimica,1958,Vol. 54,P. 389,390

海关参考信息

专利信息


专利号:US-3887441-A
优先权日:1971-12-29
标 题 :Electro-chemical synthesis of organonickel compounds
发明人:HUGHES WILLIAM B; FAHEY DARRYL R
权利人:PHILLIPS PETROLEUM CO
摘要:A process for the synthesis of organonickel derivatives by electrochemical reduction of a nickel(II) complex followed by addition of a haloorganic compound which yields a different nickel(II) complex. The complexes have utility as catalysts for olefin dimerization.

专利号:US-5030777-A
优先权日:1989-10-31
标 题 :Synthesis of 3,5-dichloroalkylbenzene and recovery of 1,3-dichlorobenzene
发明人:GEORGE JACOB; DESAI KANTI B; PERESS JIMMY
权利人:STANDARD CHLORINE OF DELAWARE
摘要:A process for synthesizing 3,5-dichloroalkylbenzene and recovering 1,3-dichlorobenzene from a starting mixture of 1,3- and 1,4-dichlorobenzenes. The process includes the sequential steps of selectively alkylating the 1,3-dichlorobenzene in the starting mixture; isomerizing a portion of the 2,4-dichloroalkylbenzene produced to 3,5-dichloroalkylbenzene; separating the 1,4-dichlorobenzene from the isomeric mixture of dichlorocumenes; and selectively transalkylating the dichlorocumenes to yield alkylbenzene, 3,5-dichloroalkylbenzene and 1,3-dichlorobenzene. By selectively alkylating only a portion of the 1,3-dichlorobenzene, the reaction products are obtained in good yield and substantially free of undesirable by-products.

专利号:US-9580323-B2
优先权日:2013-05-31
标题 :Method of producing graphene and other carbon materials
发明人:MUKASYAN ALEXANDER; MANUKYAN KHACHATUR
权利人:MUKASYAN ALEXANDER; MANUKYAN KHACHATUR; UNIV NOTRE DAME DU LAC
摘要:The invention provides methods for the combustion synthesis (CS) of graphene by a novel exothermic self-sustained reaction between a refractory ceramic compound and a carbon-containing polymer under an inert gas atmosphere. The synthesis of graphene was confirmed by both transmission electron microscopy and Raman spectroscopy. The graphene produced has very low (<1 wt. %) oxygen content. Fluorocarbon gases released due to decomposition of the carbon-containing polymer in the combustion wave can reduce the ceramic to a gas and mesoporous carbon particles and graphene layers. The method does not require an external energy source because it occurs in a self-sustained synergetic manner after ignition. The methods are flexible in terms of tuning the synthesis conditions for desired products, and the method can be scaled to provide kilogram quantities.

专利号:US-2016073631-A1
优先权日:2013-03-04
标 题 :Process for the preparation of dihydropyrrole derivatives
发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).

专利号:US-10933400-B1
优先权日:2020-08-24
标 题 :Synthesis of 3D-porous Sr(II)/Ir(III) layered hydroxide balls composed of hexagonal sheets for water purification
发明人:ELSAYED Waleed Elsayed Mahmoud; AL-GHAMDI AHMED ABDULLAH SALEM; AL-TURKI YUSUF ABDULAZIZ
权利人:UNIV KING ABDULAZIZ
摘要:Three dimensional (3D), porous, Sr(II)/Ir(III) layered double hydroxide materials with a spherical/balls like shape, are composed of nanohexagonal sheets intercalated with 1-(1-hydroxy-4-methyl-2-phenylazo)-2-naphthol-4-sulfonic acid have a number of uses including removing undesirable organic compounds and materials from polluted water. This removal can be accomplished without disturbing the pH of the water, and with high absorption capacity (2000 mg of pollutants/1 mg of LDH). The spherical/ball like materials are easily cleaned and are amenable to being reused several times.

专利号:US-12295961-B2
优先权日:2009-12-31
标 题:Modulation of solubility, stability, absorption, metabolism, and pharmacokinetic profile of lipophilic drugs by sterols
发明人:DHINGRA OM
权利人:MARIUS PHARMACEUTICALS INC
摘要:A formulation for drug delivery, providing enhanced modulation of solubility, stability, absorption, metabolism, and/or pharmacokinetic profile of a lipophilic therapeutic agent by formulation with sterols and/or sterol esters, resulting in higher bioavailability of a therapeutic agent administered to a subject in need of such therapeutic agent. The formulation contains a therapeutic agent and a sterol or sterol ester, and can, optionally, further contain a solubilizer and/or an enhancing agent. Also described are pharmaceutical compositions containing the formulations and methods of making and methods of using the formulations and pharmaceutical compositions. Formulations of the disclosure can be constituted to minimize the synthesis of dihydrotestosterone when the therapeutic agent includes testosterone or testosterone esters.
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合成参考文献


参考文献:10.1016/j.chemosphere.2010.01.026
摘要:Bustnes JO, Moe B, Herzke D, Hanssen SA, Nordstad T, Sagerup K, Gabrielsen GW, Borgå K. Strongly increasing blood concentrations of lipid-soluble organochlorines in high arctic common eiders during incubation fast. Chemosphere. 2010 Apr;79(3):320–5. doi: 10.1016/j.chemosphere.2010.01.026.
参考文献:10.1186/1476-069x-10-65
摘要:Hayley S, Mangano E, Crowe G, Li N, Bowers WJ. An in vivo animal study assessing long-term changes in hypothalamic cytokines following perinatal exposure to a chemical mixture based on Arctic maternal body burden. Environmental Health. 2011 Jul 11;10(1):65. doi: 10.1186/1476-069x-10-65.
参考文献:10.1007/s11356-011-0561-x
摘要:Turgut C, Atatanir L, Mazmanci B, Mazmanci MA, Henkelmann B, Schramm K. The occurrence and environmental effect of persistent organic pollutants (POPs) in Taurus Mountains soils. Environmental Science and Pollution Research. 2011 Jul 13;19(2):325–34. doi: 10.1007/s11356-011-0561-x.
参考文献:10.1007/s00128-011-0353-5
摘要:Cantu-Soto EU, Meza-Montenegro MM, Valenzuela-Quintanar AI, Félix-Fuentes A, Grajeda-Cota P, Balderas-Cortes JJ, Osorio-Rosas CL, Acuña-García G, Aguilar-Apodaca MG. Residues of Organochlorine Pesticides in Soils from the Southern Sonora, Mexico. Bulletin of Environmental Contamination and Toxicology. 2011 Jul 15;87(5):556. doi: 10.1007/s00128-011-0353-5.
参考文献:10.1007/s00244-011-9696-5
摘要:Hisamichi Y, Haraguchi K, Endo T. Levels of Mercury and Organohalogen Compounds in Pacific Bluefin Tuna (Thunnus orientalis) Cultured in Different Regions of Japan. Archives of Environmental Contamination and Toxicology. 2011 Jul 16;62(2):296–305. doi: 10.1007/s00244-011-9696-5.
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