CAS: 20846-91-7; (2S,2'S)-2,2'-(Ethane-1,2-Diylbis(Azanediyl))Disuccinic Acid

该化合物是一种具有氨酸和乙二酰胺结构的手动铬化剂,其主要优点包括金属离子协调具有高度选择性,因为其具有立体特性(S, S) , 使其在非对称合成和催化中具有价值. 化合物的双功能设计加强了其对二价和三价金属离子的结合性, 有助于分析和工业应用. 其水溶性和生物降解性进一步支持其在环境敏感工艺中的使用. 硬性乙烷-1,2-二基能能确保复杂的形成稳定,而丙酸基质则为衍生或进一步功能化提供了多种再活动.

英文名称(2S,2'S)-2,2'-(Ethane-1,2-Diylbis(Azanediyl))Disuccinic Acid
中文名称(2S,2'S)-2,2'-(乙烷-1,2-二基双(氮二基))二琥珀酸
IUPAC名称(2S,2'S)-2,2'-(ethane-1,2-diylbis(azanediyl))disuccinic acid
其它别名Edds; Trisodium Ethylenediamine Disuccinate; N,N'-Ethylenediamine Disuccinic Acid; (2S,2'S)-2,2'-(Ethane-1,2-Diylbis(Azanediyl))Disuccinic Acid; L-Aspartic Acid, N,N'-1,2-Ethanediylbis-; (S,S)-Ethylenediamine-N,N'-Disuccinic Acid; (2~{s})-
CAS编号20846-91-7
MFCD编号:MFCD00510741
EINECS号:682-220-2
分子式:C10H16N2O8
分子量:292.24
产品CID: 1060612
产品分类有机原料→分子砌块→脂肪链类化合物

相似结构搜索
产品信息参考;
InChIKey: VKZRWSNIWNFCIQ-WDSKDSINSA-N
InChI=1S/C10H16N2O8/c13-7(14)3-5(9(17)18)11-1-2-12-6(10(19)20)4-8(15)16/h5-6,11-12H,1-4H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)/t5-,6-/m0/s1…
计算化学: 氢键受体数6.0氢键供体数6.0可旋转键数11.0

相似化合物

89198-07-2 153352-57-9 5464-30-2

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H302-H315-H319-H332-H335
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

合成工艺路线路线简述

(4S,4'S)-1,2-Ethylenediamino-N,N'-Bis((5S)-5-(D-Menthyloxy)Butyrolactone)置于重铬酸吡啶体系中,用水,N,N-二甲基甲酰胺用作溶剂,化学反应 24.0H,反应生成N,N'-乙二胺二琥珀酸
参考文献:Asymmetric Synthesis Of New Chiral Europium N,N'-Disuccinate Complexes: Shift Reagents For Aqueous Solutions And Application In The Enantiomeric Excess Determination Of Amino Acids
标题:Asymmetric Synthesis Of New Chiral Europium N,N'-Disuccinate Complexes: Shift Reagents For Aqueous Solutions And Application In The Enantiomeric Excess Determination Of Amino Acids
摘要:The Synthesis Of New Chiral N,N'-Disuccinate Ligands (R,R)-8,(R,R)-9,And (S,S)-10 From (5R)-Or (Ss)-(Menthyloxy)-2(5H)-Furanone Is Described. These Ligands,After Complexation With Eucl3.6H(2)O,Are Highly Suitable As Chiral Shift Reagents For The Enantiomeric Excess Determination Of Amino Acids And Alpha-Alkylated Amino Acids In Aqueous Solutions. Resolution Experiments Using Various Amino Acids And Their Derivatives And A Study Of The Ph Dependency Of The Induced Diastereomeric Shift Differences Are Included.
Doi:10.1021/jo00103A044