CAS: 625-88-7; 2,5-Diiodothiophene

上下游产品

CAS号188290-36-0 Thiophene(SIV) | CAS号3437-95-4 2-碘噻吩 | CAS号86134-26-1 2,5-双(三甲基锡烷基)噻吩 | CAS号146434-35-7 2,5-bis(trimeth... | CAS号73178-21-9 5-Iodo-2-(pheny... | CAS号74-88-4 碘甲烷 | CAS号7664-41-7 氨 | CAS号1066-26-8 乙炔化钠,二甲苯溶液 | CAS号857360-63-5 5-iodo-[2]thien... | CAS号7553-56-2 碘 | CAS号4282-31-9 噻吩-2,5-二羧酸 | CAS号527-72-0 2-噻吩甲酸 | CAS号1081-34-1 alpha-三联噻吩 | CAS号492-97-7 2,2'-双噻吩 | CAS号5632-29-1 α-四联噻吩 | CAS号19259-10-0 2,3,5-三碘噻吩 | CAS号19259-11-1 四碘噻吩 | CAS号3437-95-4 2-碘噻吩 | CAS号30955-94-3 2-乙酰基-5-碘噻吩 | CAS号2866-43-5 荧光增白剂EBF

噻吩置于碘,高碘酸体系中,用 乙醇 作为反应溶剂,化学反应 0.17H,以64%的收率获得产物2,5-二碘噻吩
参考文献:一些芳烃和杂芳烃的微波加速和常规加热碘化反应的比较,使用邻碘酸作为氧化剂†
标题:一些芳烃和杂芳烃的微波加速和常规加热碘化反应的比较,使用邻碘酸作为氧化剂†
摘要:报道了使用二碘和原高碘酸作为氧化剂在微波辐射或常规加热下氧化碘化一些活化芳烃和杂芳烃的一种快速而简单的方法.反应在回流冷凝器下在热的 95% 乙醇中进行.对于微波辅助反应,反应时间总是显着缩短,但产率与常规方法几乎相同.
DOI:10.3390/10020401

专利信息

专利号:US-2013059412-A1
优先权日:2010-05-04
标 题 :In-situ polymerization in bulk heterojunction organic devices
发明人：ADE HARALD W; SEOK JAEWOOK
权利人:ADE HARALD W; SEOK JAEWOOK; UNIV NORTH CAROLINA STATE
摘要:Fabrication of bulk heterojunction organic devices are disclosed that utilize in-situ polymerization of an active component of the device or an in-situ polymerization of an additive that controls the device morphology. According to an aspect, a method for the synthesis of a BHJ photovoltaic film may comprise preparing a homogeneous solution comprising 2,5-dibromothiophene and/or 2,5-diiodothiophene, P3HT and PCBM. The method may also comprise preparing a thin film of the homogeneous solution on the solid surface of a material or an assembly capable of acting as an anode. Oxygen may be excluded from the environment where the thin film will be exposed to photopolymerization by placing the thin film and anode assembly in an inert-gas environment. The method also comprises exposing the liquid film to UV light for a sufficient duration of time and at a sufficient temperature to cause photopolymerization to occur.

专利号:US-4093622-A
优先权日:1975-05-19
标题 :Pyridine esters of cyclopropane-carboxylic acid
发明人：HENRICK CLIVE A; STAAL GERARDUS B
权利人:ZOECON CORP
摘要:Heterocyclic organic esters and thioesters characterized by the presence of one or two cyclopropane moieties, synthesis thereof, and compositions thereof for the control of mites and ticks.

专利号:IT-9047979-A1
优先权日:1990-05-18
标 题 :PROCEDURE FOR THE SYNTHESIS OF ALPHA-TERTIOFENE.

专利号:PL-212466-B1
优先权日:2007-12-10
标 题:Synthesis of arylene vinyl polymers

专利号:RU-2440355-C2
优先权日:2006-04-03
标 题:Method for synthesis of organoelement compounds