CAS: 819-19-2; Di-T-Butylphosphine

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CAS号13716-10-4 二叔丁基氯化膦 | CAS号684-19-5 二叔丁基氧化磷 | CAS号7439-96-5 锰 | CAS号39106-95-1 Di-tert-butylph... | CAS号105-53-3 丙二酸二乙酯 | CAS号128363-76-8 硼烷二(叔丁基)膦配合物 | CAS号141-97-9 乙酰乙酸乙酯 | CAS号111857-32-0 ditert-butyl(cy... | CAS号150111-89-0 1,4-双(二叔丁基膦)丁烷 | CAS号149184-57-6 ditert-butylpho... | CAS号27286-19-7 benzyl(ditert-b... | CAS号224311-51-7 2-(二叔丁基膦)联苯 | CAS号6002-40-0 二叔丁基甲基磷 | CAS号1055888-89-5 3-(二叔丁基磷基)丙烷-1-磺酸 | CAS号13716-10-4 二叔丁基氯化膦 | CAS号128363-76-8 硼烷二(叔丁基)膦配合物 | CAS号121115-33-1 1,3-双(二叔丁基膦)丙烷

Lithium Di-Tert-Butylphosphide置于氢气体系中,用 氘代苯 作为反应溶剂,50.0 °C,405.33 Kpa 条件下,反应 20.0H,反应生成 二-叔丁基膦
参考文献:可逆活化h2的碱金属物种
标题:可逆活化h2的碱金属物种
摘要:显示了mp(t Bu)2(m = Li,Na,K),Kh和kn(sime 3)2可逆地激活hd.在mp(t Bu)2的情况下,这会导致同位素加扰,并在c 6 D 6中形成h 2,D 2,H(d)p(t Bu)2和mh(d).在甲苯中,Kp(吨丁基)2分发生反应用h 2,但也导致了同位素加扰到溶剂甲苯的甲基.dft计算表明,这些系统会影响h 2 通过与路易斯酸性碱金属和碱性磷,碳负离子或氢化物中心的协同相互作用来激活,从而模拟沮丧的路易斯对(flp)行为.
DOI:10.1002/anie.201806849

专利信息

专利号:US-2022298136-A1
优先权日:2019-08-21
标题 :Process for synthesis of pyrazolidinone compounds
发明人：MATHUR SUCHET SARAN; JAIN NANDKUMAR JANARDAN; MORE MAHENDRA MAHIPAT
权利人:GHARDA CHEMICALS LTD
摘要:A process for the synthesis of pyrazolidinone, particularly alkyl 2-(3-chloropyridin-2-yl)-5-oxo-pyrazolidine-3-carboxylate (pyrazolidinone) compound, is provided. The process is simple, economical, and produces alkyl 2-(3-chloropyridin-2-yl)-5-oxo-pyrazolidine-3-carboxylate with a comparatively high yields.

专利号:US-8309716-B2
优先权日:2005-07-29
标题 :Pyrrolo[2,3-d]pyrimidine derivatives: their intermediates and synthesis
发明人：RUGGERI SALLY GUT; HAWKINS JOEL M; MAKOWSKI TERESA M; RUTHERFORD JENNIFER L; URBAN FRANK J
权利人:RUGGERI SALLY GUT; HAWKINS JOEL M; MAKOWSKI TERESA M; RUTHERFORD JENNIFER L; URBAN FRANK J; PFIZER
摘要:This invention relates to methods and intermediates useful for the synthesis of pyrrolo[2,3-d]pyrimidine compounds. Specifically novel synthetic methods and intermediates for the synthesis of 3-{(3R,4R)-4-methyl-(7H-pyrrolo[2,3-d]pyrimidin-4-yl)-amino}-piperidin-1-yl)-3-oxo-propionitrile and its corresponding citrate salt are disclosed.

专利号:WO-2024061900-A1
优先权日:2022-09-20
标题 :Quantum dot shell synthesis
发明人：WALRAVENS WILLEM; NAKONECHNYI IGOR; MACINTYRE BROWN ALASDAIR ANGUS; PRATO MODESTINO RAFAEL ALBERTO; GRIGEL VALERIIA
权利人:QUSTOMDOT BV
摘要:The invention relates to the synthesis of core/shell/shell quantum dots, particularly to a novel shell synthesis method.

专利号:US-2024101516-A1
优先权日:2021-01-20
标 题:Synthesis of polyfluorinated aryl and heteroaryl carboxamides
发明人：KADUSKAR RAHUL; BORATE KAILASKUMAR; ADHAV SUYOG; THIRUNAVUKKARASU SARAVANAN; SHINDE HARISH; GOETZ ROLAND
权利人:BASF SE
摘要:The presently claimed invention relates to a process for the preparation of mono-, di-, tri-, fluoro arylamide or hetroarylamide.

专利号:WO-2025137396-A1
优先权日:2023-12-20
标题 :Synthesis of bromodomain inhibitors
发明人：PLAMONDON LOUIS; PATEL JATIN; WANG YI; SUN CUIXIANG
权利人:CONSTELLATION PHARMACEUTICALS INC
摘要:Provided herein are processes which are useful for the preparation of small molecule bromodomain inhibitors.

专利号:US-12291489-B2
优先权日:2016-07-01
标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition
发明人：BISWAS PRATIM; RALIYA RAMESH
权利人:BISWAS PRATIM; RALIYA RAMESH; WASHINGTON UNIVERSITY ST LOUIS
摘要:The present disclosure is related to the development of improved fertilizer for precision and sustainable agriculture. A method was developed wherein efficient NPK nanocomposite for plant nutrition was synthesized in a single step using aerosol science and technology concepts. Further a formulation was prepared by addition of ZnO, TiO 2 and other nanoparticles to the NPK nanocomposite. Also, an aerosol based foliar application technique was developed for the precise delivery of nanoparticles to the plants.