专利号:US-2009326281-A1 优先权日:2008-06-30 标题:Catalytic system and process for direct synthesis of dimethyl ether from synthesis gas 发明人:APPEL LUCIA GORENSTIN; DE FARIAS ANDREA MARIA DUARTE; ESTEVES ANGELA MARIA LAVOGADE; FRAGA MARCO ANDRE; RAMOS BARBOSA FLAVIA DE SOUZA; BORGES LUIZ EDUARDO PIZZARO; MONTEIRO JOSE LUIZ FONTES; HUERTAS FLORES JHONNY OSWALDO; DA SILVA MARIA ISABEL PAIS; SOUSA AGUIAR EDUARDO FALABELLA 权利人:PETROLEO BRASILEIRO SA; INT INST NAC DE TECNOLOGIA 摘要:A mixed-bed catalytic system and its activation for direct synthesis of dimethyl ether from synthesis gas are described, comprising a catalyst for methanol synthesis and the zeolite ferrierite in its acid form as the methanol dehydrating component, the two being mixed physically in the form of powder of defined granulometry or as pellets. Another object of the present invention is a process for production of the acid form of the zeolite ferrierite. Another object of the present invention is a process for direct synthesis of dimethyl ether from a synthesis gas, using the catalytic system of the present invention.
专利号:US-9393555-B2 优先权日:2012-02-15 标题:Catalytically active body for the synthesis of dimethyl ether from synthesis gas 发明人:SCHÄFER ALEXANDER; VON FEHREN THORSTEN; MADON ROSTAM 权利人:BASF SE 摘要:The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a defined particle size distribution. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for preparation of dimethyl ether from synthesis gas.
专利号:US-9289755-B2 优先权日:2012-12-07 标题 :Synthesis of ZSM-5 crystals with improved morphology 发明人:LAI WENYIH FRANK; ROLLMAN NICHOLAS S 权利人:LAI WENYIH FRANK; ROLLMAN NICHOLAS S; EXXONMOBIL RES & ENG CO 摘要:Methods are provided for synthesizing crystals having a ZSM-5 framework structure from synthesis mixtures suitable for synthesis of ZSM-12 framework structure crystals in the absence of seed crystals with a ZSM-5 framework structure, such as in the absence of any seed crystals. For synthesis mixtures with a sufficiently high XO 2 :Y 2 O 3 ratio, seeding a synthesis mixture with ZSM-5 seed crystals can result in production of pure phase ZSM-5 crystals with a new morphology. The morphology can include rod-like primary crystallites with a length of about 0.5 μm or less that are organized/aggregated into larger secondary crystal structures. The aggregation of the primary crystallites into a secondary crystal structure can allow for an unexpectedly large mesoporous surface area for the ZSM-5 crystals.
专利号:US-2016008797-A1 优先权日:2014-06-04 标 题:Method for the synthesis of porous inorganic material, catalytic cracking of petroleum hydrocarbons and preparation of catalyst thereof 发明人:CHEN LETIAN; CHEN JIANZHONG 权利人:ZHANJIANG GIANT SUCCESS INVEST CO LTD 摘要:A method for synthesis of porous inorganic materials, preparation of a catalyst and catalytic cracking of petroleum hydrocarbons thereof includes processes for synthesis of porous inorganic materials and preparation of the catalytic cracking catalyst and catalytic cracking of petroleum hydrocarbons. The synthesis process is advantaged in low cost in raw materials; the porous inorganic material has various pore structures; and transitional metal used overcomes the defects of the catalytic properties. The porous inorganic material serving as the main active ingredient and containing crystalline aluminum silicate zeolite structures provides surface acidity required by the catalytic reaction. The surface acidity is flexibly adjusted. The hierarchical pore profile improves the accessibility of the active center of the zeolite structure and favors the reaction efficiency and benefits of the petroleum hydrocarbon cracking, and reduces the negative effects caused by diffusion limit. The catalyst containing the porous inorganic material has low manufacturing cost and better properties.
专利号:US-7527712-B2 优先权日:2002-07-23 标 题 :Method for the continuous purification by distillation of the solvent methanol, used in the synthesis of propylene oxide 发明人:BASSLER PETER; GOEBBEL HANS-GEORG; TELES JOAQUIM HENRIQUE; RUDOLF PETER 权利人:BASF AG 摘要:Process for the continuously operated purification by distillation of the methanol used as solvent in the synthesis of propylene oxide by reaction of a hydroperoxide with propylene, with the methoxypropanols being separated off simultaneously, wherein the solvent mixture obtained in the synthesis is separated in a dividing wall column into a low-boiling fraction including methanol, an intermediate-boiling fraction containing the methoxypropanols as azeotrope with water and a high-boiling fraction including water and propylene glycol.
专利号:US-10865116-B2 优先权日:2017-03-24 标 题:Process for the synthesis of IZM-2 zeolite in the presence of a template, 1,6-bis(methylpiperidinium)hexane dihydroxide 发明人:MARTINEZ FRANCO RAQUEL; BATS NICOLAS 权利人:IFP ENERGIES NOW 摘要:A novel process is described for the preparation of a microporous crystalline solid, known as IZM-2 microporous solid or IZM-2 zeolite. This novel process consists of carrying out the synthesis of IZM-2 zeolite by conversion/transformation of a zeolite with structure type FAU in a fluorinated medium under hydrothermal conditions. In particular, said novel process consists of carrying out the synthesis of an IZM-2 zeolite in a fluorinated medium starting from a zeolite with structure type FAU used as the source of silicon and aluminium and a specific organic molecule or template comprising two quaternary ammonium functions, namely 1,6-bis(methylpiperidinium)hexane dihydroxide.
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合成参考文献
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