CAS: 13782-33-7; Trans-Diammine Dichloropalladium

该化合物是钚与化学配方[Pd(NH3)2Cl2]的协调化合物,具有平方平面几何学,典型的为(II)复合体,其中离子由两个氨(NG3)和两个氯化(Cl)相协调,该化合物经常用于各种用途,包括催化和有机合成的前体,具有过渡性金属复合体的特性,如可变氧化状态和参与红氧化反应的能力.氨离心体的存在有助于其溶解于极地溶剂,而氯化离心剂可以影响其再活性.此外,据了解,离心在交叉反应中的作用是众所周知的,在有机化学领域很有价值.在处理该化合物时,应当采取安全防范措施,因为及其复合体可以是有毒的,应当按照适当的实验室安全议定书加以管理.

英文名称Trans-Diammine Dichloropalladium
中文名称二氯二氨钯
其它别名Diamminedichloropalladium; Azane; Dichloropalladium; Palladium, Diamminedichloro-, (Sp-4-1)- (9Ci); Palladium(Ii) Diammine Dichloride; Trans-Dichlorodiammine Palladium(Ii); Diammine Dichloropalladium; Tra
CAS编号13782-33-7
MFCD编号:MFCD00011621
EINECS号:237-437-3
分子式:Cl2H6N2Pd
分子量:211.39
产品CID: 587132
产品分类无机化工 → 无机盐

相似结构搜索
产品信息参考;;
InChIKey: WIEZTXFTOIBIOC-UHFFFAOYSA-L
InChI=1S/2ClH.2H3N.Pd/h2*1H;2*1H3;/q;;;;+2/p-2…
计算化学: 氢键受体数2.0氢键供体数2.0可旋转键数0.0

物理性质

密度2.5
PSA:6.48
LogP:2.0268
敏感性遵照规定使用和储存则不会分解。
外观形态黄色粉末
储存条件在惰性气体(氮气或氩气)下 2-8°C
产品应用二氯二氨络钯(CAS:13782-33-7)主要用于测定一氧化碳和电镀钯等.
性质描述二氯二氨络钯(CAS:13782-33-7)密度为2.5 g/mL (25 °C),密闭储存于阴凉干燥的地方.

MSDS等安全信息

GHS象形图
GHS符号GHS06;
注释: Skull and crossbones
危险类别急性毒性类别3(吸入)
急性毒性类别3(经皮)
急性毒性类别3(经口)
特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
急性毒性类别4(经口)
严重眼损伤类别1
皮肤致敏类别1
水生慢性毒性类别4
警示词Danger(危险)
危险描述H331 |吸入会中毒.
H311 |皮肤接触会中毒.
H301 |吞咽会中毒.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
H302 |吞咽有害.
H318 |造成严重眼损伤.
H317 |可能引起皮肤过敏反应.
H413 |可能对水生生物造成长期有害影响.
防范说明P264-P280-P305+P351+P338-P337+P313P-P261-P271-P304+P340-P311-P321-P403+P233-P405-P501-P264-P280-P302+P352-P321-P332+P313-P362-P264-P270-P301+P310-P321-P330-P405-P501-P280-P302+P352-P312-P322-P361-P363-P405-P501
UN编号2811
危险品标志T
安全声明22-26-36/37/39-45
危险类别码23/24/25-36/37/38
WGK Germany3.0

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号42724-78-7 dichloropalladi... | CAS号7647-01-0 盐酸 | CAS号7664-41-7 氨 | CAS号7440-05-3 钯

合成工艺路线路线简述

专利信息

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优先权日:2008-02-27
标题 :Synthesis of poly-(P-aryleneethynylene)s in neat water under aerobic conditions
发明人：KANG YOUN K; DERIA PRAVAS; THERIEN MICHAEL J
权利人:KANG YOUN K; DERIA PRAVAS; THERIEN MICHAEL J; UNIV PENNSYLVANIA
摘要:Provided are ethyne synthons comprising boron and related methods. Also provided are related water-soluble arylethynylene polymers capable of being synthesized in neat water under aerobic conditions.

专利号:US-7071314-B2
优先权日:2001-05-30
标题:Arylation method for the functionalization of O-allyl erythromycin derivatives
发明人：ZHANG WEIJANG; HSU MARGARET CHI-PING; HAIGHT ANTHONY R; PETERSON MATTHEW JOHN; NARAYANAN BIKSHANDARKOIL A
权利人:ABBOTT LAB
摘要:An efficient arylation technique for use in the synthesis of erythromycin derivatives, involving a modified Heck reaction which employs less than six mole percent of palladium catalyst and no phosphine is disclosed. With this modified Heck reaction, an O-alkenylaryl macrolide can be obtained in a much shorter reaction time than under conventional Heck reaction conditions. The modified Heck reaction can be utilized in a method for phosphine-free arylation of an O-allylic erythromycin derivative, in a method for preparing an O-alkenylaryl erythromycin A derivative, or in a method for preparing a 2â€², 4â€³-hydroxyl protected 6-O-alkenylaryl erythromycin A derivative.

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优先权日:2007-03-30
标题 :Method for the synthesis of cubic metal nanoparticles in the presence of two reducers

专利号:US-2011257356-A1
优先权日:2008-02-27
标题:Synthesis of Poly-(P-Aryleneethynylene)s in Neat Water Under Aerobic Conditions

专利号:CN-115155550-A
优先权日:2022-07-29
标题:A catalyst for acetone one-step synthesis of MIBK and co-production of DIBK and its preparation method and application

专利号:EP-1951460-A1
优先权日:2005-11-14
标题 :Method for the synthesis of a catalyst based on anisotropic metal nanoparticles, in the presence of a reducing agent