CAS: 1746-81-2; 3-(4-Chlorophenyl)-1-Methoxy-1-Methylurea

该化合物是一种选择性除草剂,主要用于农业控制某些大叶杂草和草,属于尿素衍生物的化学类,其特点是系统化行动,允许植物根和叶吸收. 单linuron功能,抑制光合作用,具体影响氯板的电子运输链,最终干扰植物生产能源的能力.这种化合物通常用于土豆和胡萝卜等作物,有助于管理杂草人口,而不会严重伤害所希望的植物. 就物理特性而言,莫诺林龙一般是一种白晶状的固体,水和有机溶剂中具有中等溶性.必须谨慎地处理这种物质,因为它可能对环境造成风险,对非目标生物的潜在毒性.监管措施往往规范其使用,以尽量减少生态影响,使用者应当遵守安全准则和应用议定书,以确保负责任的使用.

结构式图片

欧盟法规

《欧盟PIC法规》统一分类与标签"欧盟管控危险化学品"ECHA物质ECHA物质工作场所安全标识要求OtherC&L通报欧盟生物杀灭剂法规欧盟《生物杀灭剂法规》REACH预注册废弃物危险特性清单

上下游产品

1-(p-chlorophenyl)-3-methoxyurea dimethyl sulfate N-(4-chlorophenyl)-N'-hydroxyurea N,O-dimethylhydroxylamine*hydr°Chloridemethylamine

合成工艺路线路线简述

  • 合成目标产物 Monolinuron 主要起始原料 N,O-Dimethylhydroxylamine Hydrochloride And 4-Chlorophenyl Isocyanate
  • (文献来源)合成步骤主要原料 N,O-Dimethylhydroxylamine Hydrochloride 和 4-Chlorophenyl Isocyanate
对氯苯异氰酸酯置于sodium Hydroxide体系中,用 甲醇 用作溶剂,化学反应生成绿谷隆
参考文献:Scherer,O. Et Al.,Angewandte Chemie,1963,Vol. 75,P. 851-854
标题:Scherer,O. Et Al.,Angewandte Chemie,1963,Vol. 75,P. 851-854

海关参考信息

专利信息


专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

专利号:US-11919928-B2
优先权日:2016-03-16
标题 :Method for producing dihydrotentoxin
发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
权利人:KUMIAI CHEMICAL INDUSTRY CO
摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

专利号:ES-2717283-T3
优先权日:2012-07-24
标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids
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✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: D Giraud, Et Al. Determination Of Traces Of Pesticides In Water By Solid-Phase Extraction And Liquid Chromatography-Ionspray Mass Spectrometry. J Chromatogr A. 1997 Aug 8;777(1):115-25.
[参考文献]: Georgia Gatidou, Et Al. Investigation Of Photodegradation And Hydrolysis Of Selected Substituted Urea And Organophosphate Pesticides In Water. Environ Sci Pollut Res Int. 2011 Jul;18(6):949-57.
[参考文献]: H Maier-Bode, Et Al. Linuron And Monolinuron. Residue Rev. 1981:77:1-364.
[参考文献]: M Bahadir, Et Al. A Comparative Study On Pesticide Formulations For Application In Running Waters. Ecotoxicol Environ Saf. 1985 Oct;10(2):197-201.
[参考文献]: M L Escuderos-Morenas, Et Al. Direct Determination Of Monolinuron, Linuron And Chlorbromuron Residues In Potato Samples By Gas Chromatography With Nitrogen-Phosphorus Detection. J Chromatogr A. 2003 Sep 5;1011(1-2):143-53.

合成参考文献


摘要:World Review of Pest Control., 9(119), 1970
摘要:Hartley, D. and H. Kidd (eds.). The Agrochemicals Handbook. 2nd ed. Lechworth, Herts, England: The Royal Society of Chemistry, 1987., p. A285/OCT 83
摘要:Martin, H. and C.R. Worthing (eds.). Pesticide Manual. 4th ed. Worcestershire, England: British Crop Protection Council, 1974., p. 364
摘要:Tomlin, C.D.S. (ed.). The Pesticide Manual - World Compendium. 10th ed. Surrey, UK: The British Crop Protection Council, 1994., p. 709
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
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