专利号:US-7767425-B2 优先权日:2001-11-16 标 题:Enzymatic synthesis of sugar acrylates 发明人:BOECKH DIETER; HAUER BERNHARD; HAERING DIETMAR 权利人:BASF AG 摘要:A process is described for the enzymatic synthesis of sugar acrylates, and a process is described for preparing polymeric sugar acrylates, the polymers obtainable by this process and their use for preparing, for example, cosmetics, drugs, laundry detergents, thickeners, protecting colloids, superabsorbents and textile sizes.
专利号:US-10023677-B2 优先权日:2014-12-16 标 题 :Method for controlling the synthesis of a block copolymer containing at least one nonpolar block and at least one polar block and use of said block copolymer in applications of nanolithography by direct self-assembly 发明人:NAVARRO CHRISTOPHE; NICOLET CELIA; CHEVALIER XAVIER 权利人:ARKEMA FRANCE 摘要:A method for controlling the synthesis of a block copolymer containing at least two blocks, with at least one nonpolar block and at least one polar block, said method making it possible in particular to control the ratio between the blocks and the molecular weight of each of the blocks, said copolymer being a block copolymer intended to be used as a mask in a method of nanolithography by direct self-assembly (DSA), said control being achieved by semicontinuous anionic polymerization in an aprotic nonpolar medium.
专利号:US-7906596-B2 优先权日:2005-04-22 标 题:Processes for enzymatic synthesis of poly(oxyalkylene)acrylamides 发明人:HAERING DIETMAR; HAUER BERNHARD; BECKER STEFAN 权利人:BASF SE 摘要:Processes for enzymatic synthesis comprising: (a) providing an aliphatic poly(oxyalkylene)amine; and (b) reacting the aliphatic poly(oxyalkylene)amine with a reactant selected from the group consisting of acrylic acid compounds and alkyl esters thereof, in the presence of a hydrolase in bulk or in a liquid reaction medium comprising an organic solvent to for a poly(oxyalkylene)acrylamide.
专利号:US-2008274074-A1 优先权日:2005-11-24 标题:Method for Controlled Free Radical Polymerization or Copolymerization of Methacrylic and/or Methacrylate Monomers or Exclusively Methacrylic and/or Methacrylate Copolymers 发明人:COUTURIER JEAN-LUC; GUILLANEUF YOHANN; BERTIN DENIS; GIGMES DIDIOR 权利人:ARKEMA FRANCE 摘要:The invention relates to a method for the polymerization of one or more methacrylate and/or methacrylic monomers, for the synthesis of methacrylate or methacrylic polymers or of exclusively methacrylic and/or methacrylate copolymers, comprising a step of bringing said monomer(s) into contact with one at least of the compounds of formula (I) and (II) below: n n n n n n n n n n in which:n R 1 and R 2 may represent a phenyl group, R 3 and R 4 may together form an â•?N-phenyl group, Z represents a group of formula —CR 8 R 9 R 10 , in which R 8 and R 9 may represent methyl groups and R 10 may represent a —COO-phenyl group.
专利号:US-8299139-B1 优先权日:2009-09-08 标 题:Process and reactor for synthesis of ultra-high molecular weight acrylic polymers 发明人:TARANEKAR PRASAD; SCHUMAN AUSTIN L; BANERJIE ASIS 权利人:TARANEKAR PRASAD; SCHUMAN AUSTIN L; BANERJIE ASIS; OVATION POLYMER TECHNOLOGY AND ENGINEERED MATERIALS INC 摘要:This invention relates to a process for producing high molecular weight (HMW) and ultra-high molecular weight (UHMW) acrylic polymers having unique polymer tacticity and exhibiting enhanced thermal and mechanical properties. This process comprises polymerizing ethylenically unsaturated monomer in the presence of a free radical initiator that results in a “living-like polymerâ€? utilizing a multi-step approach. In conducting the process of this invention the “living-like polymerâ€? is further dissolved in a liquid carrier, wherein the said liquid carrier is a reactive diluent that can be reacted subsequently by an addition polymerization process to create a block- or multi-block, copolymer or homopolymer. This process can be progressively repeated with the same or various different reactive diluents to generate desired architecture and molecular weight polymer(s) which can be used in further processing procedures to be manufactured directly into finished articles.
专利号:US-9296014-B2 优先权日:2013-07-25 标 题:Process for controlling the period characterizing the morphology obtained from a blend of block copolymers and of co(polymers) of one of the blocks 发明人:NAVARRO CHRISTOPHE; CHEVALIER XAVIER; NICOLET CELIA 权利人:ARKEMA FRANCE 摘要:The present invention relates to a process for controlling the period characterizing the morphology obtained from a blend of block copolymers and of (co)polymers of one of the blocks on a surface employing a particular way of carrying out the synthesis of the blend of block copolymers and of (co)polymers of one of the blocks.
[参考文献]: Anthony J D'Angelo, Et Al. Deciphering Physical Versus Chemical Contributions To The Ionic Conductivity Of Functionalized Poly(Methacrylate)-Based Ionogel Electrolytes. J Phys Chem B. 2015 Nov 25;119(47):14959-69. [参考文献]: Antonios M Douvas, Et Al. 157-Nm Laser Ablation Of Polymeric Layers For Fabrication Of Biomolecule Microarrays. Anal Bioanal Chem. 2005 Mar;381(5):1027-32. [参考文献]: Arda Yurtsever, Et Al. Cec With New Monolithic Stationary Phase Based On A Fluorinated Monomer, Trifluoroethyl Methacrylate. Electrophoresis. 2009 Feb;30(4):589-98. [参考文献]: Y Yokoyama, Et Al. [参考文献]: Tokyo Ika Shika Daigaku Iyo Kizai Kenkyusho Hokoku. 1984:18:1-9. [参考文献]: Yoshinori Kadoma, Et Al. Kinetic Polymerization Behavior Of Fluorinated Monomers For Dental Use. Dent Mater J. 2010 Oct;29(5):602-8.
合成参考文献
参考文献:10.1016/j.jcis.2004.02.067 摘要:Inoue Y, Watanabe J, Ishihara K. Dynamic motion of phosphorylcholine groups at the surface of poly(2-methacryloyloxyethyl phosphorylcholine-random-2,2,2-trifluoroethyl methacrylate). J Colloid Interface Sci. 2004 Jun 15;274(2):465–71. doi: 10.1016/j.jcis.2004.02.067. 参考文献:10.1021/la800171h 摘要:Chen R, Zhu S, Maclaughlin S. Grafting acrylic polymers from flat nickel and copper surfaces by surface-initiated atom transfer radical polymerization. Langmuir. 2008 Jun 01;24(13):6889–96. doi: 10.1021/la800171h.