CAS: 701-64-4; Phenylphosphoric Acid

该化合物是一种有机磷化合物,其特征是其磷酸功能组,与苯氧基混合物相连.这种结构具有独特的化学特性,包括强压和热稳定性,使其在腐蚀抑制,阻燃和金属表面处理等应用中有用. 它与金属离子的反作用使得工业水系统能够有效进行规模抑制,而它与聚合物的兼容性则提高了物质性能.该化合物的水文解析稳定性和低挥发性进一步有助于它适应高温和水生环境. 苯氧磷酸因其在工业化学中的多功能而受到重视,特别是在需要持久和高效的磷基功能的地方.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号770-12-7 二氯化磷酸苯酯 | CAS号108-95-2 苯酚 | CAS号409324-67-0 bis(4-bromobenz... | CAS号139-02-6 苯酚钠 | CAS号77930-00-8 ethylN-methyl-N... | CAS号79760-89-7 N-methyl-N-(phe... | CAS号793-12-4 (4-nitrophenyl)... | CAS号7664-38-2 磷酸 | CAS号330-13-2 磷酸单-(4-硝基-苯酚)酯 | CAS号902-04-5 2'-脱氧-5'-鸟苷酸 | CAS号838-85-7 磷酸二苯酯 | CAS号7664-38-2 磷酸 | CAS号10113-28-7 TRIS(PHENYL,MET... | CAS号2510-86-3 Phosphoric acid... | CAS号45951-59-5 amino(phenoxy)p... | CAS号46207-73-2 ethyl phenyl hy... | CAS号46355-07-1 磷酸异丙基苯酯 | CAS号46438-39-5 磷酸一丁基单苯酯

合成工艺路线路线简述

    苯基膦酸二乙酯置于盐酸体系中,化学反应 12.0H,以62%的收率获得产物磷酸单苯酯
    参考文献: Materials For Organic Electroluminescent Devices[fr] Matériaux Pour Dispositifs électroluminescents Organiques
    标题: Materials For Organic Electroluminescent Devices[fr] Matériaux Pour Dispositifs électroluminescents Organiques
    摘要:本发明涉及适用于电子设备,特别是有机电致发光器件的化合物的公式(1),以及包含这些化合物的电子设备.

    海关参考信息

    专利信息


    专利号:US-2004152905-A1
    优先权日:2003-01-31
    标题:Universal building blocks and support media for synthesis of oligonucleotides and their analogs
    发明人:GUZAEV ANDREI P; MANOHARAN MUTHIAH
    摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and chemically modified oligonucleotide analogs, are provided. In addition, methods for functionalization of a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.

    专利号:US-2004242897-A1
    优先权日:2002-07-31
    标题 :Universal support media for synthesis of oligomeric compounds
    发明人:GUZAEV ANDREI P; MANOHARAN MUTHIAH
    摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and oligonucleotide mimetics, are provided. In addition, methods for functionalizing a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.

    专利号:US-5756770-A
    优先权日:1987-12-31
    标题:Synthesis of stable, water-soluble chemiluminescent 1,2-dioxetanes and intermediates therefor
    发明人:BRONSTEIN IRENA Y; EDWARDS BROOKS
    权利人:TROPIX INC
    摘要:A novel synthesis of 1,2-dioxetane phosphate alkali metal salts and novel intermediates employed in this synthesis are disclosed. A hydroxyaryl enol ether alkali metal salt having the formula: ##STR1## wherein T can be an unsubstituted or substituted adamant-2'-ylidene group, R 3 can be a methyl group, Y can be a phenyl group and M + can be a sodium cation, is reacted with a phosphorohalidate to give the corresponding enol ether ethylene phosphate, which is then reacted with an alkali metal cyanide to give the corresponding enol ether cyanoethyl phosphate diester alkali metal salt intermediate. Singlet oxygen addition to this enol ether cyanoethyl phosphate diester alkali metal salt intermediate to give the corresponding 1,2-dioxetane cyanoethyl phosphate diester alkali metal salt, followed by β-elimination of the cyanoethyl group using an alkali metal hydroxide or the like, gives the corresponding 1,2-dioxetane phosphate alkali metal salt.

    专利号:EP-0629195-B1
    优先权日:1992-03-05
    标 题 :Synthesis of stable, water-soluble chemiluminescent 1,2-dioxetanes and intermediates therefor
    发明人:BRONSTEIN IRENA Y; EDWARDS BROOKS
    权利人:TROPIX INC
    摘要:A novel synthesis of 1,2-dioxetane phosphate alkali metal salts and novel intermediates employed in this synthesis are disclosed. A hydroxyaryl enol ether alkali metal salt having formula (1), wherein T can be an unsubstituted or substituted adamant-2'-ylidene group, R<3> can be a methyl group, Y can be a phenyl group and M<+> can be a sodium cation, is reacted with a phosphorohalidate to give the corresponding enol ether ethylene phosphate, which is then reacted with an alkali metal cyanide to give the corresponding enol ether cyanoethyl phosphate diester alkali metal salt intermediate. Singlet oxygen addition to this enol ether cyanoethyl phosphate diester alkali metal salt intermediate to give the corresponding 1,2-dioxetane cyanoethyl phosphate diester alkali metal salt, followed by beta -elimination of the cyanoethyl group using an alkali metal hydroxide or the like, gives the corresponding 1,2-dioxetane phosphate alkali metal salt.

    专利号:WO-2004011474-A1
    优先权日:2002-07-31
    标题:Universal support media for synthesis of oligomeric compounds
    发明人:GUZAEV ANDREI P; MANOHARAN MUTHIAH; RAVIKUMAR VASULINGA T; KUMAR RAJU K
    权利人:ISIS PHARMACEUTICALS INC; GUZAEV ANDREI P; MANOHARAN MUTHIAH; RAVIKUMAR VASULINGA T; KUMAR RAJU K
    摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotide and oligonucleotide mimetics, are provided. In addition, methods for functionalizing a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.

    专利号:US-6653468-B1
    优先权日:2002-07-31
    标 题 :Universal support media for synthesis of oligomeric compounds
    发明人:GUZAEV ANDREI P; MANOHARAN MUTHIAH
    权利人:ISIS PHARMACEUTICALS INC
    摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and oligonucleotide mimetics, are provided. In addition, methods for functionalizing a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.
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    合成参考文献


    参考文献:10.3390/ijms12063770
    摘要:Shi JY, Yuan XF, Lin HR, Yang YQ, Li ZY. Differences in soil properties and bacterial communities between the rhizosphere and bulk soil and among different production areas of the medicinal plant Fritillaria thunbergii. Int J Mol Sci. 2011;12(6):3770–85.
    参考文献:10.1155/2012/137386
    摘要:Abdelwahab SI, Mohamed AH, Mohamed OY, Oall M, Taha MME, Mohan S, Noordin MI, Mustafa MR, Alkharfy KM. Erectogenic Effects ofClerodendron capitatum: Involvement of Phosphodiesterase Type-5 Inhibition. Evidence-Based Complementary and Alternative Medicine. 2012;2012():1–6. doi: 10.1155/2012/137386.
    参考文献:10.1016/j.chroma.2011.06.054
    摘要:Booker CJ, Sun S, Woolsey S, Mejia JS, Yeung KK. Removal of sample background buffering ions and myoglobin enrichment via a pH junction created by discontinuous buffers in capillary electrophoresis. J Chromatogr A. 2011 Aug 19;1218(33):5705–11. doi: 10.1016/j.chroma.2011.06.054.
    参考文献:10.1038/ismej.2011.88
    摘要:Holmes DE, Risso C, Smith JA, Lovley DR. Genome-scale analysis of anaerobic benzoate and phenol metabolism in the hyperthermophilic archaeon Ferroglobus placidus. The ISME Journal: Multidisciplinary Journal of Microbial Ecology. 2011 Jul 21;6(1):146–57. doi: 10.1038/ismej.2011.88.
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