CAS: 7738-94-5; Chromic Acid

该化合物是一种强大的氧化剂和强酸,主要用于各种工业用途,包括金属加工,电镀和有机合成中的试剂,通常被作为一种深红到褐色溶液,具有高度腐蚀性和毒性.铬酸以其氧化有机化合物的能力而著称,并经常用于制备铬盐.化合物在水中溶解,形成一种高酸溶液,可释放有毒铬离子,对健康和环境构成重大风险.由于其致癌性质,对其使用和处置实行严格监管.安全防范,包括使用个人防护设备和适当的通风,在处理铬酸时至关重要.其化学行为受到pH和其他物质的存在影响,使其在化学过程中成为多用途但危险的试剂.

结构式图片

MSDS等安全信息

欧盟法规

ECHA物质ECHA物质欧盟授权物质清单C&L通报REACH预注册欧盟候选物质清单

上下游产品

sulfuric acid water chromium(VI) oxide dichromic acidchromium bromine chromate(VI) ion ozone

合成工艺路线路线简述

    专利信息


    专利号:US-4288608-A
    优先权日:1978-06-01
    标题:Synthesis of anthracyclines
    发明人:JOHNSON FRANCIS; KIM KYOUNG S
    权利人:RESEARCH CORP
    摘要:There is provided a novel method of synthesizing certain heterocyclic quinones. In particular there is provided a novel and regiospecific synthesis of 9-acetyl-6,11-dihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,12-quinone (7,9-dideoxydaunomycinone) which is known intermediate in the synthesis of daunomycinone. There is also provided a method of preparing analogs of 7,9-dideoxydaunomycinone which thus provide for the preparation of known and desired analogs of daunomycinone. Daunomycinone is a known compound which is an intermediate in the preparation of the clinically accepted naturally-occurring antitumor antibiotics daunomycin and its derivitive adriamycin.

    专利号:US-5451691-A
    优先权日:1992-05-07
    标题 :Synthesis of cosmetic ingredients
    发明人:CRAWFORD DUNCAN J; RAWLINGS ANTHONY V; SCOTT IAN R
    权利人:ARDEN ELIZABETH CO
    摘要:A method of synthesis of ω-hydroxy fatty acid containing ceramides having the general structure (1). ##STR1## where A represents CH 2 or --CHâ•?CH--Y represents a residue of a C 14 to C 22 fatty acid having the structure (2) ##STR2## where Z is --OH or an epoxy oxygen n x is an integer of from 12 to 20 n y is an integer of from 20 to 40 n z is 0 or an integer of from 1 to 4 n a is an integer of from 8 to 50 n b is an integer of from 10 to 100 n and n is an integer of from 7 to 27.

    专利号:US-3962291-A
    优先权日:1974-09-05
    标 题:Total synthesis of 11-alkyl steroids
    发明人:GARLAND ROBERT B; PAPPO RAPHAEL
    权利人:SEARLE & CO
    摘要:A novel total synthesis of 11-alkyl steroids, utilizing readily available and inexpensive raw materials, is described. The resulting products are useful and novel pharmacological agents possessing, for example, selective hormonal properties.

    专利号:EP-0034338-B1
    优先权日:1980-02-14
    标题:Catalyst for the synthesis of alcohol mixtures containing methanol and higher alcohols
    摘要:1. Catalyst for the synthesis of alcohol mixtures containing methanol and higer alcohols one the basis of starting catalysts containing copper oxide, zinc oxide and, optionally, aluminium oxide, obtainable either by (a) producing from soluble salts of copper, zinc and, optionally, aluminium (principal constituents) by joint precipitation with promoter compounds in an alkaline medium a precipitate which is calcined after removal of the impurity ions ; or by (b) impregnating a mixture of the oxides of copper, zinc, and, optionally, aluminium, with solutions of the promoter compounds and calcining the resultant product ; wherein the promoter compounds represent compounds of chromium, cerium, lanthanum, manganese, thorium or of combinations of these elements, and wherein at any desired stage of production alkali compounds are added.

    专利号:US-4489206-A
    优先权日:1983-05-13
    标 题:Synthesis of (+)-4-demethoxydaunomycinone
    发明人:CAVA MICHAEL P; DOMINGUEZ DOMINGO
    权利人:ADRIA LAB INC
    摘要:It has been found that stereospecific R(-)-4-demethoxy-7-deoxydaunomycinone can be synthesized from the known compound 4-demethoxy-7,9-dideoxydaunomycinone. R(-)-4-Demethoxy-7-deoxy-daunomycinone is an intermediate in the synthesis of (+)-4-demethoxydaunomycinone, the aglycone of the nonnaturally occurring and antitumor active (-)7(S)9(S)-4-demethoxydaunorubicin.

    专利号:US-5384335-A
    优先权日:1991-03-26
    标 题:Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite
    发明人:TIERNEY JOHN W; WENDER IRVING; PALEKAR VISHWESH M
    权利人:UNIV PITTSBURGH
    摘要:The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100°-160° C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H 2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.
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    📌 第三方产品分析报告

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    合成参考文献


    参考文献:10.1007/bf01898700
    摘要:Kuromizu K, Izumiya N. Synthesis of tyrocidine B. Cellular and Molecular Life Sciences. 1970 Jun;26(6):587–8. doi: 10.1007/bf01898700.
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