CAS: 112-06-1; Heptyl Acetate

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111-70-6 638-59-5 112-14-1

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2-壬酮置于baeyer-Villiger Monooxygenases 5体系中,用 乙醇 用作溶剂,化学反应 24.0H,反应生成乙酸庚酯
参考文献:基因组挖掘揭示了具有(生物)合成潜力的新型细菌 I 型 Baeyer-Villiger 单加氧酶
标题:基因组挖掘揭示了具有(生物)合成潜力的新型细菌 I 型 Baeyer-Villiger 单加氧酶
摘要:摘要 Baeyer-Villiger 单加氧酶 (Bvmos) 是一种氧化还原酶,以非常选择性的方式催化酮的氧化.通过基因组挖掘,我们在重氮慢生根瘤菌 Usda 110 中检测到了七个推定的 I 型 Bvmo.当我们建立它们之间以及与其他 I 型 Bvmo 的系统发育关系时,我们发现它们属于系统发育树的不同进化枝.因此,我们决定克隆并异源表达其中的五个.其中三个,每个来自不同的系统发育组,作为可溶性蛋白质获得,使我们能够继续进行它们的生物催化评估和酶学表征.至于底物范围和选择性,我们观测到三种 Bvmo 之间的互补行为.
Doi:10.1016/j.Mcat.2020.110875

专利信息

专利号:US-2023002312-A1
优先权日:2019-11-20
标题:A continuous flow process for the synthesis of hydroxamic acid
发明人：PIMPALE MILIND JAGANNATH; KINI PRASHANT VASANT
权利人:UPL LTD
摘要:The present invention relates to a process for the synthesis of hydroxamic acids by continuous flow process wherein said process comprising reacting alkyl ester with hydroxyl amine salt in presence of base in a microreactor system and continuously producing hydroxamic acid.

专利号:US-8653238-B2
优先权日:2006-02-27
标题:Compositions and methods for transport of molecules with enhanced release properties across biological barriers
发明人：WENDER PAUL A; GOUN ELENA A; JONES LISA R
权利人:WENDER PAUL A; GOUN ELENA A; JONES LISA R; UNIV LELAND STANFORD JUNIOR
摘要:Conjugates of a cargo molecule with a transporter molecule are disclosed, where the cargo molecule and the transporter molecule are linked covalently by a releasable linker. The cargo of the conjugate can be a biologically active agent or a reporter molecule. The transporter modulates the transport of the cargo across a biological barrier (e.g., a cell membrane) compared to the transport of the unconjugated cargo. Releasable linkers suitable for rapid and facile conjugation to various types of cargo and transporters are also disclosed, along with methods for using the linkers in the synthesis of conjugates.

专利号:US-2005209355-A1
优先权日:2004-03-22
标 题:[Novel Reactions and the Products of Such Reactions]
发明人：ROITMAN LIPA L
权利人:ROITMAN LIPA L
摘要:A process for the synthesis of novel compounds is described comprising reacting tetrachloroethylene with substances containing active methylene group in the presence of free radical initiators. Also, a process for grafting tetrachloroethylene is described comprising reacting these compounds with polymers containing active methylene group in the presence of free radical initiators. Furthermore, a method of conducting such reactions to high conversion is described, comprising conducting the reactions in the reflux condensate. The present invention provides a novel and high yield route for heretofore unobtainable materials.

专利号:US-5210222-A
优先权日:1991-01-21
标题 :Process for the production of malonic acid anhydride
发明人：O'MURCHU COLM
权利人:LONZA AG
摘要:A process, which is harmless with respect to safety, for the production of malonic acid anhydride. For this purpose, diketene is ozonized in the presence of a suitable carbonyl compound. Malonic acid anhydride is a highly reactive intermediate product for the synthesis of numerous active ingredients for, e.g., pharmaceutical agents, pesticides or dyes.

专利号:US-6531625-B2
优先权日:2000-09-08
标题 :Cinnamic esters
发明人：KUHN WALTER; BRAUN GERHARD; KLEIN STEPHAN
权利人:HAARMANN & REIMBER GMBH
摘要:In a novel process for the synthesis of cinnamic esters or substituted cinnamic esters, carboxylic esters are reacted, by condensation, with benzaldehyde or substituted benzaldehydes, respectively, in the presence of a solid with basic properties.

专利号:US-4818796-A
优先权日:1987-05-13
标 题:Polymers prepared by polymerizing alpha, beta-ethylenically unsaturated acids and epoxy compounds
发明人：DAS SURYYA K; PORTER JR SAMUEL; TYGER WAYNE H
权利人:PPG INDUSTRIES INC
摘要:Hydroxyl-containing polymers prepared by reaction of a polymerizable alpha, beta-ethylenically unsaturated carboxylic acid and an epoxy compound containing greater than 5 carbon atoms are disclosed. The polymer is prepared by free radical organic solution polymerization techniques. Synthesis of the polymers by this technique assures multiple hydroxyl functionality in all polymer chains thereby providing good cure response. The polymers are useful as binders in high solids coating compositions. When used with appropriate curing agents, the resultant coatings have good hardness, high gloss and distinctness of image, have good solvent and humidity resistance and are very resistant to acid etching. n Preferred reactants are: n (a) an alpha, beta ethylenically unsaturated carboxylic acid and n (b) a glycidyl ester of the formula ##STR1## where R=a tertiary aliphatic hydrocarbon group of 4 to 26 carbon atoms.