CAS: 15418-29-8; Copper(I) Tetra(Acetonitrile) Tetrafluoroborate

该化合物是一个协调化合物,其特点是在+1氧化状态下铜,与四种丙烯酸(CHCN)离子体相协调.该复合体的特点是亮蓝色,这是铜(I)复合物的典型特征.四氟乙酸盐(BF)离离子是一种对应物,有助于化合物在极地溶剂中的稳定性和溶性.乙硝酸盐作为离子存在,并且增加了有机溶剂中化合物的溶解性,使其在各种合成应用中有用.该化合物经常用于有机合成和催化,特别是在涉及电子转移过程的反应中.其协调环境是四氟化物,因为铜中心周围有四颗丙烯离子.此外,该化合物对空气和湿度敏感,需要在惰性条件下谨慎地处理和储存,以防止氧化或水解.总体而言,四氟基(乙酰)聚物(I).四氟丙酸酯是协调化学和催解过程中的一种有价值的再生剂.

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copper acetonitrile4[Cu(6-(4-diethylmethylphosphonatephenyl)-2,2'-bipyridine)(bis(diphenylphosphino)ethane monoxide)]BF4

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    专利信息


    专利号:US-2016317682-A1
    优先权日:2015-04-30
    标题:PREPARATION OF Ag18F AND ITS USE IN THE SYNTHESIS OF PET RADIOTRACERS
    发明人:SCOTT PETER J H; BROOKS ALLEN F; ICHIISHI NAOKO; SANFORD MELANIE S
    权利人:UNIV MICHIGAN REGENTS; THE REGENTS OFTHE UNIV OF MICHIGAN
    摘要:Copper-catalyzed radiofluorination of aryl iodides using Ag 18 F, methods of preparing Ag 18 F, and compounds obtained by copper-catalyzed radiofluorination of aryl iodides using Ag 18 F are disclosed. Diagnostic and therapeutic methods involving such compounds also are disclosed.

    专利号:US-2024360125-A9
    优先权日:2021-02-22
    标 题 :2-substituted bicyclo[1.1.1]pentanes
    发明人:MACMILLAN DAVID W; GARRY OLIVIA L; LIANG YUFAN; HEILMANN MICHAEL
    权利人:UNIV PRINCETON
    摘要:Provided herein are 2-substituted bicyclo[1.1.1]pentane (BCP) compounds, as well as methods of making the 2-substituted BCP compounds and methods of derivatizing the 2-substituted BCP compounds, particularly at the 2-position. The 2-substituted BCP compounds described herein are useful building blocks in the synthesis of a variety of products, including pharmaceuticals, polymers, liquid crystals, monolayers and supramolecular structures.

    专利号:CN-120041848-A
    优先权日:2025-02-18
    标 题 :Method for electrochemically synthesizing chiral beta-ester nitrile and application of chiral beta-ester nitrile in synthesis of baclofen and rolipram

    专利号:CN-117623998-A
    优先权日:2023-12-05
    标 题:Application of perfluorocarbon sulfur-based silver reagent in synthesis of aryl perfluoroethyl sulfide

    专利号:US-5346995-A
    优先权日:1991-11-25
    标题:Preparation of copper 2-alkoxyisobutylisonitrile complexes and 99m Tc labelling of 2-alkoxyisobutylisonitrile
    发明人:TE-WEI LEE; GANN TING; CHANG-SHINN SU; SHYH-YI CHYI
    权利人:INST NUCLEAR ENERGY RES
    摘要:A new method for synthesizing 2-alkoxyisobutylisonitrile is provided in which isobutylene is used as the starting material. The haloalkoxylation of isobutylene in alcohol medium gives 2-alkoxyisobutylhalide which is then converted to 2-alkoxyisobutylamine. In the basic condition, the reaction of 2-alkoxyisobutylamine with chloroform produces 2-alkoxyisobutylisonitrile. The synthesis process contains three steps by which a higher yield is achieved. 2-Alkoxyisobutylisonitrile is labelled with technetium-99m by exchange labelling of stable tetrakis(2-alkoxyisobutylisonitrile)copper(I) complex. Tetrakis(2-alkoxyisobutylisonitrile)copper(I) complex can be prepared by the exchange of acetonitrile molecules in tetrakis(acetonitrile)copper(I) complex with isonitrile ligands.

    专利号:CN-114369248-B
    优先权日:2020-10-15
    标题 :A kind of chiral silicon-containing polyester and its synthesis method
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    合成参考文献


    摘要:López-Carrillo, V.; Echavarren, A. M., Science of Synthesis Knowledge Updates, (2011) 2, 49.
    摘要:Zhang, L., Science of Synthesis Knowledge Updates, (2011) 2, 84.
    摘要:Nahm Garrett, M.; Johnson, J. S., Science of Synthesis Knowledge Updates, (2012) 2, 15.
    摘要:Oishi, M.; Takikawa, H., Science of Synthesis Knowledge Updates, (2010) 4, 97.
    摘要:Hou, X.-L.; Peng, X.-S.; Yeung, K.-S.; Wong, H. N. C., Science of Synthesis Knowledge Updates, (2011) 2, 295.
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